Analysis of Thermodynamic Cycles of Heat Pumps and Magnetic Refrigerators Using Mathematical Models
Abstract
:1. Introduction
1.1. Heat Pumps
1.2. Magnetocaloric Technology
1.3. Magnetocaloric Materials
1.4. Thermodynamic Cycles of Magnetocaloric Systems
Active Magnetic Regenerator (AMR) Cycle
- A magnetization process that leads to heating the ferromagnetic material of the regenerator, which heats the carrier fluid flowing inside it.
- A regenerator cooling process with a constant applied magnetic field. The pumping system allows the passage of the regenerating fluid which, being at a lower temperature than the magnetic substance, heats up and is sent to the lateral heat exchanger taking thermal energy from the magnetic substance, which cools down.
- A demagnetization process that leads to further lowering of the regenerator temperature. The magnetic field affecting the regenerator is removed, causing a lowering of the regenerator temperature profile due to the magnetocaloric effect.
- A regenerator heating process. In the absence of an external magnetic field, the regenerator is passed through the regenerating fluid leaving the heat source exchanger which, being at a higher temperature than the extreme heat of the magnetic substance, will release energy by cooling to be sent to the cold side exchanger as the temperature profile of the regenerator increases.
2. Methodology—Mathematical Models and Experimental Comparison
2.1. The Curie-Weiss Law Applied to the Ericsson cycle
2.2. Effect of Regeneration
- From Tcold to T0, , ;
- From T0 to Thot, . .
- -
- If , the integral of Qr would be between T0 and T0 and, therefore, equal to 0;
- -
- If , the integral of Qr would be between Tcold and Thot and, therefore, it would be ;
- -
- If , the integral of Qr would be between T0 and Thot and, therefore, it would be .
2.3. Definition of the COP through Langevin’s Theory
2.4. Performance Analysis of the Brayton Cycle
- From point 1 to point 2s, an isentropic adiabatic magnetization from the H2 field to the field H1 is represented. The real process that is carried out is, however, adiabatic and irreversible and goes from 1 to 2; the material temperature rises from T1 to T2.
- From point 2 to point 3, the material, with a constant magnetic field H1, releases heat Qh to the hot source, decreasing its temperature up to T3. This temperature, assuming an ideal heat exchange, is equal to Th of the hot source.
- From point 3 to point 4, the material cools down to T4 giving QR heat to the regenerator.
- From point 4 to point 5s, the material is subjected to an isentropic adiabatic demagnetization from the H1 field to the field H2. The real process that is performed is, however, adiabatic and irreversible and ranges from 4 to 5; the material temperature drops from T4 to T5.
- From point 5 to point 6 the material, with constant magnetic field H2, absorbs heat Ql from the cold source, rising to the temperature T6. This temperature, assuming an ideal heat exchange, is equal to Tl of the cold source.
- From point 6 to point 1, the regenerator transfers the QR heat to the magnetocaloric material, making it return to the starting temperature T1.
3. Results
3.1. Ericsson Cycle Experimental Data
3.2. Ericsson Cycle Results through Curie-Weiss Theory
- When , the curve decreases for any Thot, while in the experimental graph (Figure 8), even after 294.4 K, the curves with and do not change curvature.
- The orange curve, calculated with a larger Thot, should not be higher than the blue one, calculated with a smaller Thot; this is because the COP decreases when operating with a higher temperature range.
3.3. Ericsson Cycle Results through Langevin’s Theory
- Qh, Ql, Qbc, and Qda are all positive;
- The Ericsson magnetic cycle is stable;
- The temporal characteristics of demagnetization, magnetization, the magnetocaloric effect, and heat transfer are neglected;
- Gadolinium is assumed to be an ideal magnetic material;
- Other irreversibility factors are neglected, except for imperfect regeneration;
- There is no difference in temperature, during the heat transfer, between the magnetic material and the sources.
- For the process a–b, the thermal energy supply to the environment to be heated (Th = Thot):
- For the process c–d, the absorption of thermal energy from the environment to be cooled (Tl = Tcold):
- For the process b–c, the thermal energy supply to the regenerator:
- For the process d–a, the absorption of thermal energy from the regenerator:
4. Conclusions
Author Contributions
Funding
Informed Consent Statement
Conflicts of Interest
Nomenclature
Bj (x) | Brillouin function | |
c | Specific heat capacity | J/kgK |
C | Curie costant | |
CH | Heat capacity the constant magnetic field | J/K |
g | Landé factor | |
H | Magnetic field | T |
Hext | External magnetic field | T |
JA | Quantum number of the total angular momentum | |
JO | Quantum number of the orbital moment | |
L | Work supplied to the system | J |
L(x) | Langevin function | |
m | Mass | kg |
M | Magnetization intensity | A/m |
Mm | Molar mass | g/mol |
n | Number of moles | mol |
NA | Avogadro number | |
ND | Number of magnetic moments | |
NG | Number of atoms in 1kg of gadolinium | atoms/kg |
Nm | Number of atoms or molecules | |
Ns | Quantum number of spins | |
Qcold, Ql | Cold source heat | J |
Qh | Hot source heat | J |
QH | Net heating quantity | J/K |
QL | Net cooling quantity | J/K |
Qr | Insufficient regenerative heat | J/K |
s | Specific entropy | J/kgK |
S | Entropy | J/K |
Se | Entropy of free electrons of the material | J/K |
Sm | Magnetic entropy | J/K |
Sr | Reticular entropy | J/K |
Stot | Total entropy | J/K |
T | Temperature of material | K |
T0 | Working temperature | K |
TC | Curie temperature | K |
Th, Thot, T2 | Hot source temperature | K |
Tl, Tcold | Cold source temperature | K |
W | Overall work of the system | J/K |
Greek Letters | ||
α | Regenerative degree | |
ΔTad | Adiabatic temperature change | K |
ΔSm | Isothermal entropy change | J/K |
β | Ratio of two magnetic fields | |
k | Boltzmann constant | J/K |
χ | Magnetic susceptibility | |
λ | Molecular magnetic field | |
µB | Bohr magneton | J/K |
Γ | Factor | |
µ | Spin magnetic moment | J/T |
ηc, ηe | Adiabatic irreversibility | |
τ | Ratio of temperatures of two heat reservoirs | |
Abbreviations | ||
AMR | Active Magnetic Regenerator | |
COP | Coefficient of Performance | |
GWP | Global Warming Potential | |
MCE | Magneto-Caloric Effect | |
ODP | Ozone Destruction Potential |
References
- Baglivo, C.; Bonuso, S.; Congedo, P.M. Performance Analysis of Air Cooled Heat Pump Coupled with Horizontal Air Ground Heat Exchanger in the Mediterranean Climate. Energies 2018, 11, 2704. [Google Scholar] [CrossRef] [Green Version]
- Congedo, P.M.; Lorusso, C.; Baglivo, C.; Milanese, M.; Raimondo, L. Experimental validation of horizontal air-ground heat exchangers (HAGHE) for ventilation systems. Geothermics 2019, 80, 78–85. [Google Scholar] [CrossRef]
- Baglivo, C.; D’Agostino, D.; Congedo, P.M. Design of a Ventilation System Coupled with a Horizontal Air-Ground Heat Exchanger (HAGHE) for a Residential Building in a Warm Climate. Energies 2018, 11, 2122. [Google Scholar] [CrossRef] [Green Version]
- Chaudhary, V.; Chen, X.; Ramanujan, R. Iron and manganese based magnetocaloric materials for near room temperature thermal management. Prog. Mater. Sci. 2019, 100, 64–98. [Google Scholar] [CrossRef]
- Restuccia, G. Thermally driven heat pumps in future energy systems. IEA Heat Pump Cent. Newsl. 2007, 27, 13–15. [Google Scholar]
- Moscati, M. Il Freddo ad Adsorbimento e l’Energia Solare. 2013. Available online: https://www.zerosottozero.it/2013/05/03/il-freddo-ad-adsorbimento-e-lenergia-solare/ (accessed on 4 May 2020).
- Pompa di Calore Termica a Zeolite. 2012. Available online: https://www.casaeclima.com/ar_10577__IMPIANTI-meccanici-Generatori-di-calore-Vitosorp-200-F--Viesmann-Pompa-di-calore-termica-a-zeolite.html (accessed on 4 May 2020).
- Demir, H.; Mobedi, M.; Ülkü, S. A review on adsorption heat pump: Problems and solutions. Renew. Sustain. Energy Rev. 2008, 12, 2381–2403. [Google Scholar] [CrossRef] [Green Version]
- Karaca, F.; Kincay, O.; Bolat, E.; Kıncay, O. Economic analysis and comparison of chemical heat pump systems. Appl. Therm. Eng. 2002, 22, 1789–1799. [Google Scholar] [CrossRef]
- Peruchetti, E.; Perboni, S. Un Innovativo Sistema di Accumulo Termico: Nuove Opportunità per CSP e Teleriscaldamento. 2018. Available online: http://www.lab-e.it/wp-content/uploads/2018/12/2018-12-17-Accumulo-termico.pdf (accessed on 13 May 2020).
- Fujimoto, S.; Bilgen, E.; Ogura, H. CaO/Ca(OH)2 chemical heat pump system. Energy Convers. Manag. 2002, 43, 947–960. [Google Scholar] [CrossRef]
- Padovan, G.; Produzione di Energia Elettrica ed Energia Frigorifera con il Suono. Introduzione ai Motori e Refrigeratori Termoacustici. Available online: http://www.22passi.it/downloads/Produrre%20energia%20elettrica%20e%20frigorifera%20con%20il%20suono%20rev.pdf (accessed on 6 May 2020).
- Egolf, P.W.; Introduzione alla Refrigerazione Magnetica. Centro Studi Galileo. Available online: https://www.centrogalileo.it/nuovapa/Articoli%20tecnici/Egolf/introduzione%20alla%20refrigerazione%20magnetica.htm (accessed on 13 May 2020).
- Gómez, J.R.; Garcia, R.F.; Catoira, A.D.M. Magnetocaloric effect: A review of the thermodynamic cycles in magnetic refrigeration. Renew. Sustain. Energy Rev. 2013, 17, 74–82. [Google Scholar] [CrossRef]
- Berardi, R. Che cos’è l’Effetto Magnetocalorico? Ralph DTE. 2016. Available online: https://www.ralph-dte.eu/2016/09/20/che-cose-leffetto-magnetocalorico/ (accessed on 13 May 2020).
- Loigerot, J.; Il Freddo Magnetico. Centro Studi Galileo. Available online: https://www.centrogalileo.it/nuovapa/Articoli%20tecnici/Il%20freddo%20magnetico.htm (accessed on 13 May 2020).
- Wang, J.Y.; Diguet, G.; Lin, G.X.; Chen, J.C. Performance Characteristics of a Magnetic Ericsson Refrigeration Cycle Using La(Fe0.88Si0.12)13H1 or Gd as the Working Substance. Adv. Mater. Res. 2013, 631, 322–325. [Google Scholar] [CrossRef]
- Umberto, L. General approach to obtain the magnetic refrigeretion ideal coefficient of performance. Phys. A Stat. Mech. Appl. 2008, 387, 3477–3479. [Google Scholar] [CrossRef]
- Bingfeng, Y.; Yan, Z.; Qiang, G.; Dexi, Y. Research on performance of regenerative room temperature magnetic refrigeration cycle. Int. J. Refrig. 2006, 29, 1348–1357. [Google Scholar] [CrossRef]
- Yang, Y.; Chen, J.; He, J.; Brück, E. Parametric optimum analysis of an irreversible regenerative magnetic Brayton refrigeration cycle. Phys. B Condens. Matter 2005, 364, 33–42. [Google Scholar] [CrossRef]
Gadolinium (Gd) | La (Fe0.88Si0.12)13H1 | ||
---|---|---|---|
Mass | 1 kg | Mass | 1 kg |
Qc,max at Tcold = 294.4 K | 1257 J/kg | Qc,max at Tcold = 277.3 K | 5830 J/kg |
ΔSm at Tcold = 294.4 K | 4.27551 J/kg | ΔSm at Tcold = 277.3 K | 21.02416 J/kg |
TC | 294 K | TC | 277.3 K |
ΔH | 2 T | ΔH | 2 T |
Gadolinium (Gd) | ||
---|---|---|
External electronic configuration | 4f7 5d1 6s2 | |
Quantum number of spins NS | 3.5 | |
Quantum orbital number JO | 0 | |
Quantum number of the total angular momentum JA | 3.5 | |
Landè factor g | 2 | |
Mass m | 1 | kg |
Molar mass M | 157.25 | g/mol |
Number of moles n | 6.36 | mol |
Avogadro number NA | 6.02 × 1023 | |
Number of atoms in 1kg of gadolinium Ng | 3.83 × 1024 | atoms/kg |
Bohr magneton μB | 9.27 × 10−24 | J/T |
Boltzmann constant k | 1.38 × 10−23 | J/K |
Curie constant C | 501.23 | JK/T2 |
Curie Temperature TC | 294.4 | K |
Γ | 294.40 | K |
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Baglivo, C.; Congedo, P.M.; Donno, P.A. Analysis of Thermodynamic Cycles of Heat Pumps and Magnetic Refrigerators Using Mathematical Models. Energies 2021, 14, 909. https://doi.org/10.3390/en14040909
Baglivo C, Congedo PM, Donno PA. Analysis of Thermodynamic Cycles of Heat Pumps and Magnetic Refrigerators Using Mathematical Models. Energies. 2021; 14(4):909. https://doi.org/10.3390/en14040909
Chicago/Turabian StyleBaglivo, Cristina, Paolo Maria Congedo, and Pasquale Antonio Donno. 2021. "Analysis of Thermodynamic Cycles of Heat Pumps and Magnetic Refrigerators Using Mathematical Models" Energies 14, no. 4: 909. https://doi.org/10.3390/en14040909