Upgrading Hydrothermal Carbonization (HTC) Hydrochar from Sewage Sludge
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Hydrothermal Carbonization
2.3. Organic Acids
3. Results and Discussion
3.1. Characteristics of Phosphorus Elimination in HTC Hydrochars Using Different Organic Acids
3.2. Comparison of HTC Hydrochar Properties with Different Organic Acids
3.3. Phosphorus Removal Characteristics According to the Amount of Oxalic Acid Added in the HTC Product
3.4. Comparison of Solid Fuel Properties According to the Amount of Oxalic Acid Treated in the HTC Product
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Descriptions | Sludge | HTC | HTC (Oxalic) | HTC (Citric) | HTC (Tartaric) |
---|---|---|---|---|---|
Proximate analysis (wt.%, db a) | |||||
Moisture | 1.10 | 0.11 | 0.12 | 0.14 | 0.13 |
Volatile | 69.95 | 59.81 | 70.31 | 72.06 | 67.94 |
Fixed carbon | 10.78 | 12.48 | 12.83 | 14.19 | 12.63 |
Ash | 18.17 | 27.60 | 17.34 | 13.61 | 19.30 |
Ultimate analysis (wt.%, db a) | |||||
C | 42.00 | 45.34 | 50.60 | 53.55 | 48.32 |
H | 6.20 | 6.09 | 6.40 | 6.78 | 6.82 |
O | 24.60 | 16.91 | 24.99 | 21.56 | 25.21 |
N | 7.80 | 4.73 | 3.91 | 4.65 | 4.17 |
S | 0.99 | 0.60 | 0.50 | 0.54 | 0.51 |
Calorific analysis (kcal/kg, db a) | |||||
Higher heating value | 4503 | 4960 | 5350 | 5690 | 5020 |
Ash analysis (wt.%, db a) | |||||
Phosphorous content in ash | 43.65 | 48.13 | 3.10 | 6.39 | 21.39 |
Solid yield (%) | - | 65.76 | 54.71 | 51.07 | 55.28 |
Descriptions | HTC (Oxalic, 0.1) | HTC (Oxalic, 0.5) | HTC (Oxalic, 1.0) | HTC (Oxalic, 5.0) |
---|---|---|---|---|
Proximate analysis (wt.%, db a) | ||||
Moisture | 0.11 | 0.11 | 0.11 | 0.12 |
Volatile | 60.10 | 63.01 | 64.25 | 70.31 |
Fixed carbon | 10.78 | 11.01 | 11.05 | 12.83 |
Ash | 29.01 | 25.87 | 24.59 | 17.34 |
Ultimate analysis (wt.%, db a) | ||||
C | 45.08 | 46.90 | 47.99 | 50.60 |
H | 6.00 | 6.07 | 6.12 | 6.40 |
O | 17.62 | 19.13 | 20.07 | 24.99 |
N | 4.66 | 4.59 | 3.97 | 3.91 |
S | 0.53 | 0.54 | 0.52 | 0.50 |
Calorific analysis (kcal/kg, db a) | ||||
Higher heating value | 4870 | 5130 | 5190 | 5350 |
Ash analysis (wt.%, db a) | ||||
Phosphorous content in ash | 31.08 | 24.93 | 22.63 | 3.10 |
Solid yield (%) | 64.18 | 63.95 | 62.28 | 54.71 |
Oxalic Acid Fraction (w/w, %) | 0.1 | 0.5 | 1.0 | 5.0 |
---|---|---|---|---|
Unit Cost of Oxalic Acid (US$/tonsludge) | 0.48 | 2.4 | 4.8 | 24 |
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Song, E.; Park, S.; Kim, H. Upgrading Hydrothermal Carbonization (HTC) Hydrochar from Sewage Sludge. Energies 2019, 12, 2383. https://doi.org/10.3390/en12122383
Song E, Park S, Kim H. Upgrading Hydrothermal Carbonization (HTC) Hydrochar from Sewage Sludge. Energies. 2019; 12(12):2383. https://doi.org/10.3390/en12122383
Chicago/Turabian StyleSong, Eunhye, Seyong Park, and Ho Kim. 2019. "Upgrading Hydrothermal Carbonization (HTC) Hydrochar from Sewage Sludge" Energies 12, no. 12: 2383. https://doi.org/10.3390/en12122383