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Molbank, Volume 2001, Issue 1 (March 2001) – 18 articles

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89 KiB  
Short Note
(2,2'-Bipyridine-N,N')dibutyldiisothiocyanotin
by Chun Hu, Rihong Tan, Jianping Wang, Yu Ji and Shengfu Wang
Molecules 2001, 6(3), M210; https://doi.org/10.3390/M210 - 25 Mar 2001
Abstract
Diorganotin dihalide complexes with bidentate nitrogen ligands exhibit some pharmaceutical activities such as antitumour activity, antiviral activity and anti-microbiological activity[1-3], we have synthesized some diorganotin dihalide and dipseudohalide complexes with bidentate nitrogen ligands, one of which is (2,2'-bipyridine-N,N')dibutyldiisothiocyanotin.[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
89 KiB  
Short Note
Dibutyldichloro(1,10-phenanthroline-N1,N10)tin
by Chun Hu, Rihong Tan, Jianping Wang, Yu Ji and Shengfu Wang
Molecules 2001, 6(3), M209; https://doi.org/10.3390/M209 - 25 Mar 2001
Abstract
Diorganotin dihalide complexes with bidentate nitrogen ligands exhibit some pharmaceutical activities such as antitumour activity, antiviral activity and anti-microbiological activity[1-3], we have synthesized some diorganotin dihalide complexes with bidentate nitrogen ligands, one of which is dibutyldichloro(1,10-phenanthroline-N1,N10)tin.[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
86 KiB  
Short Note
2-Methyl-5-chloromethyl-8-hydroxyquinoline
by Ke-Qing Zhao, Ping Hu, Yu-Quan Zhou and Hong-Bo Xu
Molecules 2001, 6(3), M208; https://doi.org/10.3390/M208 - 25 Mar 2001
Cited by 1
Abstract
Quinoline and its derivatives have been widely used as metal ion chelating agents, metal extracting agents, corrosive inhibitors and they often show biological activity.[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
87 KiB  
Short Note
1-(Pyridin-3-yl)-4-(triethylsilyloxy)-2-butyn-1-ol
by Vittorio E. Caprio, Michael W. Jones and Margaret A. Brimble
Molecules 2001, 6(3), M207; https://doi.org/10.3390/M207 - 25 Mar 2001
Abstract
The general part of the experimental section [1] has been presented elsewhere.[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
86 KiB  
Short Note
1-(Pyridin-3-yl)but-2-yn-1,4-diol
by Vittorio E. Caprio, Michael W. Jones and Margaret A. Brimble
Molecules 2001, 6(3), M206; https://doi.org/10.3390/M206 - 25 Mar 2001
Abstract
The general part of the experimental section [1] has been presented elsewhere.[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
15 KiB  
Short Note
4-Hydroxy-methylen-4'-methyl-2,2'-bipyridine
by Michael Kercher and Burkhard König
Molecules 2001, 6(3), M205; https://doi.org/10.3390/M205 - 25 Mar 2001
Abstract
A key intermediate in the synthesis of extended bipyridine ligands [1] is 4-hydroxymethylene-4-methyl-2,2-bipyridine (3), because the hydroxy group is readily converted into a variety of other chemical moieties, such as leaving or carbonyl groups.[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
89 KiB  
Short Note
4,5-Dimethoxy-2-(4-methylbenzoyl)-1-(4-methylphenylsulfonylamido)benzene
by Sergey K. Smirnov, Artem S. Dmitriyev and Irina V. Lodina
Molecules 2001, 6(3), M204; https://doi.org/10.3390/M204 - 25 Mar 2001
Abstract
For this synthesis, we propose a modification of the reaction procedure described in [1].[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
77 KiB  
Short Note
Methyl 3-Hydroxythieno[2,3-b]pyridine-2-carboxylate
by Gerard P. Moloney
Molecules 2001, 6(3), M203; https://doi.org/10.3390/M203 - 25 Mar 2001
Cited by 26
Abstract
As part of a research programme targeting novel molecules as potential anti-inflammatory agents we synthesised methyl 3-hydroxythieno[2,3-b]pyridine-2-carboxylate based on the reported anti-inflammatory activity of the structurally related molecule 3-isopropoxy-5-methoxy-N-(1H-1,2,3,4-tetraazol-5-yl)-1-benzothiophene-2-carboxamide [1,2].[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
89 KiB  
Short Note
Pyridine-3-carboxaldehyde O-methyloxime
by Vittorio E. Caprio, Michael W. Jones and Margaret A. Brimble
Molecules 2001, 6(3), M202; https://doi.org/10.3390/M202 - 25 Mar 2001
Cited by 1
Abstract
The general part of the experimental section [1] has been presented elsewhere.[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
97 KiB  
Short Note
1-(2-Vinyl-pyridin-3-yl)propanal O-methyloxime and 1-(6-Vinyl-pyridin-3-yl)propanal O-methyloxime
by Vittorio E. Caprio, Michael W. Jones and Margaret A. Brimble
Molecules 2001, 6(3), M201; https://doi.org/10.3390/M201 - 25 Mar 2001
Abstract
The general part of the experimental section [1] has been presented elsewhere. Boron trifluoride diethyl etherate (313 mg, 2.21 mmol) was added dropwise to a solution of oxime 1 (100 mg, 0.735 mmol) in toluene (8 mL) at -78oC under nitrogen [...] Read more.
The general part of the experimental section [1] has been presented elsewhere. Boron trifluoride diethyl etherate (313 mg, 2.21 mmol) was added dropwise to a solution of oxime 1 (100 mg, 0.735 mmol) in toluene (8 mL) at -78oC under nitrogen and the mixture stirred for 5 min.[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
88 KiB  
Short Note
tert-Butyl methoxy(2-propynyl)carbamate
by Vittorio E. Caprio, Michael W. Jones and Margaret A. Brimble
Molecules 2001, 6(3), M200; https://doi.org/10.3390/M200 - 25 Mar 2001
Cited by 1
Abstract
The general part of the experimental section [1] has been presented elsewhere.[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
94 KiB  
Short Note
N-Benzyl-3-(2-morpholine)ethoxy-5-methoxy benzofuran-2-carboxamide
by Gerard P. Moloney
Molecules 2001, 6(3), M199; https://doi.org/10.3390/M199 - 25 Mar 2001
Cited by 1
Abstract
As part of a research programme targeting novel indole-like molecules as potential cannabinoid agonists [1-4] we synthesised methyl 3-(2-(N-morpholino)ethyl-5-methoxybenzofuran-2-carboxylate.[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
90 KiB  
Short Note
N-(2-Ethylmorpholino)-3-bis-ketothiene
by Gerard P. Moloney
Molecules 2001, 6(3), M198; https://doi.org/10.3390/M198 - 25 Mar 2001
Abstract
As part of a research programme targeting novel indole-like molecules as potential cannabinoid agonists [1-4] we synthesised N-(2-ethylmorpholino)-3-bis-ketothiene.[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
91 KiB  
Short Note
1-(2-Ethylmorpholino)-5-benzyloxy-3-(1-napthoyl)pyrrolopyridine
by Gerard P. Moloney
Molecules 2001, 6(3), M197; https://doi.org/10.3390/M197 - 25 Mar 2001
Abstract
As part of a research programme targeting novel indole-like molecules as potential cannabinoid agonists [1-4] we synthesised N-(2-ethylmorpholino)-3-bis keto(1-naphthyl) oxindole.[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
92 KiB  
Short Note
N-(2-Ethylmorpholino)-3-bis-keto(1-naphthyl)oxindole
by Gerard P. Moloney
Molecules 2001, 6(3), M196; https://doi.org/10.3390/M196 - 25 Mar 2001
Abstract
As part of a research programme targeting novel indole-like molecules as potential cannabinoid agonists [1-4] we synthesised N-(2-ethylmorpholino)-3-bis-keto(1-naphthyl)oxindole.[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
92 KiB  
Short Note
5-Isopropyl-N-(1H-1,2,3,4-tetrazol-5-yl)thiobenzo-2-oxazole Acetamide
by Gerard P. Moloney
Molecules 2001, 6(3), M195; https://doi.org/10.3390/M195 - 25 Mar 2001
Abstract
As part of a research programme targeting novel molecules as potential anti-inflammatory agents we synthesised 3-Chloro-5-methoxy-1-benzo[b]thiophene-2-sulphonylamide base on the reported anti-inflammatory activity of the structurally related molecule 3-isopropoxy-5-methoxy-N-(1H-1,2,3,4-tetraazol-5-yl)-1-benzothiophene-2-carboxamide [1,2]. Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
92 KiB  
Short Note
[5-Hydroxy-1-(2-morpholinoethyl)-1H-indol-3-yl](4-methoxyphenyl)methanone
by Gerard P. Moloney
Molecules 2001, 6(3), M194; https://doi.org/10.3390/M194 - 25 Mar 2001
Abstract
As part of a research programme targeting novel indole-based molecules as potential cannabinoid agonists we synthesised [5-hydroxy-1-(2-morpholinoethyl)-1H-indol-3-yl](4-methoxyphenyl)methanone [1-4].[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
85 KiB  
Short Note
Bis(p-allylhimachalene)dichlorodipalladium
by Larbi El Firdoussi and Abdellah Karim
Molecules 2001, 6(3), M193; https://doi.org/10.3390/M193 - 25 Mar 2001
Abstract
The title organometallic compound, potentially important synthetic intermediate, was prepared regio- and stereospecifically from b-himachalene ((4aR)-3,5,5,9-Tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), essentiel component of cedrus atlantica oil [1].[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
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