The Role of N and S Doping on Photoluminescent Characteristics of Carbon Dots from Palm Bunches for Fluorimetric Sensing of Fe3+ Ion
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis and Characterization of CDs under Hydrothermal Conditions and Effect of Different Dopants on CD Properties
2.2. Effect of Different Concentrations of Nitrogen and Sulfur Passivating Agents on CD Characteristics
2.3. Study on Metal Detection by NS/CDs Using Turn-Off Fluorescent Assay
3. Materials and Methods
3.1. Hydrothermal Synthesis of Carbon Dots from EFBs and Effect of Different Dopants on CD Properties
3.2. Effect of N and S Concentrations on Enhancement of CD Photoluminescent Properties
3.3. Characterization of CDs
3.4. Study on Metal Detection by NS/CDs Using Fluorimetric Sensing
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample | QY (%) | ζ (mV) | Eg (eV) | ID/IG Ratio |
---|---|---|---|---|
CDs | 39% | −25.5 | 3.95 | 2.54 |
0.05 M NS/CDs | 24% | −35.5 | 3.89 | 3.61 |
0.10 M NS/CDs | 18% | −46.9 | 3.92 | 2.80 |
0.20 M NS/CDs | 48% | −46.5 | 3.56 | 0.73 |
0.30 M NS/CDs | 75% | −61.9 | 2.59 | 0.58 |
0.40 M NS/CDs | 114% | −33.4 | 2.53 | 0.43 |
Detection Probe | Ions Detected | Detection Limit (μM) | Linear Range (μM) | References |
---|---|---|---|---|
Graphene quantum dots (GQDs) | Fe3+ | 7.22 | 0–80 | [68] |
Nitrogen-doped carbon dots (N-CDs) | Fe3+ | 0.96 | 0–100 | [69] |
Nitrogen-doped polymer nanodots (N-PNDs) | Fe3+ | 0.10 | 0–30 | [70] |
Graphene oxide (GO) nanosheets | Fe3+ | 17.50 | 14.3–143.2 | [71] |
Fluorescent carbon nanoparticles (F-CNPs) | Fe3+ | 0.32 | 0–20 | [72] |
Phosphorus-doped carbon quantum dots (P-CQDs) | Fe3+, Fe2+ | 0.005 | 0–20 | [73] |
Nitrogen-doped carbon quantum dots (N-CQDs) | Fe3+, Hg2+ | 0.09 | 1–1945 | [5] |
Au nanoclusters | Fe3+ | 3.50 | 5–1280 | [74] |
Nitrogen-doped carbon quantum dots (NCQDs) | Fe3+ | 4.67 | 0–50 | [75] |
Nitrogen-and-sulfur-doped carbon dots (0.20 M NS/CDs) | Fe3+ | 0.10 | 5–400 | This study |
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Saengsrichan, A.; Saikate, C.; Silasana, P.; Khemthong, P.; Wanmolee, W.; Phanthasri, J.; Youngjan, S.; Posoknistakul, P.; Ratchahat, S.; Laosiripojana, N.; et al. The Role of N and S Doping on Photoluminescent Characteristics of Carbon Dots from Palm Bunches for Fluorimetric Sensing of Fe3+ Ion. Int. J. Mol. Sci. 2022, 23, 5001. https://doi.org/10.3390/ijms23095001
Saengsrichan A, Saikate C, Silasana P, Khemthong P, Wanmolee W, Phanthasri J, Youngjan S, Posoknistakul P, Ratchahat S, Laosiripojana N, et al. The Role of N and S Doping on Photoluminescent Characteristics of Carbon Dots from Palm Bunches for Fluorimetric Sensing of Fe3+ Ion. International Journal of Molecular Sciences. 2022; 23(9):5001. https://doi.org/10.3390/ijms23095001
Chicago/Turabian StyleSaengsrichan, Aphinan, Chaiwat Saikate, Peeranut Silasana, Pongtanawat Khemthong, Wanwitoo Wanmolee, Jakkapop Phanthasri, Saran Youngjan, Pattaraporn Posoknistakul, Sakhon Ratchahat, Navadol Laosiripojana, and et al. 2022. "The Role of N and S Doping on Photoluminescent Characteristics of Carbon Dots from Palm Bunches for Fluorimetric Sensing of Fe3+ Ion" International Journal of Molecular Sciences 23, no. 9: 5001. https://doi.org/10.3390/ijms23095001