Photoprocesses in Derivatives of 1,4- and 1,3-Diazadistyryldibenzenes
Abstract
:1. Introduction
2. Results and Discussion
2.1. Absorption and Fluorescence Spectra
2.2. Kinetic Spectroscopy
2.3. Quantum Chemical Calculations
2.3.1. Model
2.3.2. Results
3. Materials and Methods
Calculation
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Compound | Experiment | Calculation | ||
---|---|---|---|---|
λmax, nm | ε, L∙mol−1∙cm−1 | λmax, nm | f | |
1 | 390 | 5.4 × 104 | 420 | 2.07 |
2 | 350 | 5.0 × 104 | 372 1 350 1 348 1 314 1 | 0.59 1 0.58 1 0.75 1 0.23 1 |
Compound | Experiment | Calculation | |||||||
---|---|---|---|---|---|---|---|---|---|
φ | λmax, nm | λ0-0, nm | λexc, nm | Δλ, nm | τfl, ps | λmax, nm | f | τr, ps | |
1 | 0.05 | 470 | 434 | 393 | 77 | 120 | 454 1 472 2 | 2.18 1.34 | 1420 2500 |
2 | 0.02 | 455 | 395 | 346 | 109 | 160 | 409 1 422 2 | 0.30 0.19 | 8350 13700 |
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Atabekyan, L.S.; Freidzon, A.Y.; Ionov, D.S.; Nuriev, V.N.; Medved’ko, A.V.; Vatsadze, S.Z.; Gromov, S.P.; Chibisov, A.K. Photoprocesses in Derivatives of 1,4- and 1,3-Diazadistyryldibenzenes. Int. J. Mol. Sci. 2022, 23, 15346. https://doi.org/10.3390/ijms232315346
Atabekyan LS, Freidzon AY, Ionov DS, Nuriev VN, Medved’ko AV, Vatsadze SZ, Gromov SP, Chibisov AK. Photoprocesses in Derivatives of 1,4- and 1,3-Diazadistyryldibenzenes. International Journal of Molecular Sciences. 2022; 23(23):15346. https://doi.org/10.3390/ijms232315346
Chicago/Turabian StyleAtabekyan, Levon S., Alexandra Y. Freidzon, Dmitry S. Ionov, Vyacheslav N. Nuriev, Alexey V. Medved’ko, Sergey Z. Vatsadze, Sergey P. Gromov, and Alexander K. Chibisov. 2022. "Photoprocesses in Derivatives of 1,4- and 1,3-Diazadistyryldibenzenes" International Journal of Molecular Sciences 23, no. 23: 15346. https://doi.org/10.3390/ijms232315346