Easy Preparation of Liposome@PDA Microspheres for Fast and Highly Efficient Removal of Methylene Blue from Water
Abstract
:1. Introduction
2. Results and Discussion
2.1. Preparation and Characterization of Liposome@PDA Microspheres
2.2. Adsorption Experiments of MB Onto Liposome@PDA Microspheres
2.3. Kinetic Studies of the Adsorption Process
2.4. Adsorption Isotherms
2.5. Adsorption Thermodynamics
2.6. Adsorption Experiments in Model Effluent and Reusability
3. Materials and Methods
3.1. Reagents
3.2. Liposome@PDA Microspheres Preparation
3.3. Liposomes and Liposome@PDA Microspheres Characterization
3.4. Adsorption Experiments
3.5. Evaluation of the Specific Surface Area of the Liposome@PDA Microspheres
3.6. Adsorption Experiments in Model Effluent and Reusability of Liposome@PDA Microspheres
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Conflicts of Interest
References
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PDA-Based Adsorbents | qmax (mg g−1) | Refs. |
---|---|---|
PDA-porous silica microspheres (separation in fixed bed) | 83.8 | [5] |
Acid etching coconut shells carbon -PDA | 79.32 | [6] |
SiO2-PDA-polyacrylic acid | 150.02 | [29] |
PDA microspheres | 90.7 | [2] |
PAAM/PA/PDA hydrogel | 350.67 | [34] |
PDA-functionalized graphene–Fe3O4 magnetic composites | 365.39 | [36] |
Fe3O4@PDA-Ag hollow microspheres | 102.04 | [37] |
Fe3O4/PDA | 204.1 | [38] |
Deacetylated cellulose acetate@PDA nanofiber membrane | 88.2 | [39] |
Fe3O4/PDA-Fe3+ | 361.8 | [40] |
Liposome@PDA microspheres | 395.4 | This work |
Kinetic Model | T (K) | qe, exp (mg g−1) | qe, calc (mg g−1) | k1 (min−1) | k2 (g mg−1 min−1) | ki1/2 (g mg−1 min−0.5) | R2 |
---|---|---|---|---|---|---|---|
Pseudo-first order | 298 | 395.36 | 37.60 | 0.047 | - | - | 0.8391 |
Pseudo-second order | 298 | 395.36 | 393.70 | - | 0.0104 | - | 0.9999 |
Intraparticle diffusion | 298 | - | - | - | - | Ki1 = 33.05 Ki2 = 3.20 | R12 = 1.0000 R22 = 1.0000 |
Intraparticle diffusion | 313 | - | - | - | - | Ki1 = 72.51 Ki2 = 4.12 | R12 = 0.8483 R22 = 0.6481 |
Isotherms. | Parameters | R2 |
---|---|---|
Langmuir | q0 = 414.94 mg g−1 KL = 20.25 L mg−1 RL = 0.1220–0.0366 | 0.9772 |
Freundlich | KF = 422.93 (mg g−1) (mg L−1)n n = 4.73 | 0.5899 |
T (K) | Kα (L g−1) | ΔG° (kj mol−1) | ΔH° (kj mol−1) | ΔS° (kj mol−1 T−1) |
---|---|---|---|---|
278 | 124.56 | −11.15 | 13.37 | 87.84 |
288 | 146.32 | −11.94 | ||
298 | 158.39 | −12.55 | ||
313 | 242.89 | −14.29 |
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De Leo, V.; Maurelli, A.M.; Ingrosso, C.; Lupone, F.; Catucci, L. Easy Preparation of Liposome@PDA Microspheres for Fast and Highly Efficient Removal of Methylene Blue from Water. Int. J. Mol. Sci. 2021, 22, 11916. https://doi.org/10.3390/ijms222111916
De Leo V, Maurelli AM, Ingrosso C, Lupone F, Catucci L. Easy Preparation of Liposome@PDA Microspheres for Fast and Highly Efficient Removal of Methylene Blue from Water. International Journal of Molecular Sciences. 2021; 22(21):11916. https://doi.org/10.3390/ijms222111916
Chicago/Turabian StyleDe Leo, Vincenzo, Anna Maria Maurelli, Chiara Ingrosso, Fabio Lupone, and Lucia Catucci. 2021. "Easy Preparation of Liposome@PDA Microspheres for Fast and Highly Efficient Removal of Methylene Blue from Water" International Journal of Molecular Sciences 22, no. 21: 11916. https://doi.org/10.3390/ijms222111916