Synthesis and Characterization of Manganese Dithiocarbamate Complexes: New Evidence of Dioxygen Activation
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis and Characterization of MnL2 (1), (L = Diethyldithiocarbamate)
2.2. Stability Studies of MnL2 (1) after Exposure to Atmospheric Dioxygen
2.3. Synthesis and Characterization of [MnL3] (3), (L = Diethyldithiocarbamate)
2.4. Synthesis and Characterization of [Mn(II)((S2CN(CH2CH2OEt)2)2] (4), L’ = bis(N-Ethoxyethyl)Dithiocarbamate and Stability Studies after Exposure to Atmospheric Dioxygen
2.5. Magnetic Susceptibility
2.6. Remarks
3. Materials and Methods
3.1. Synthesis and Characterization of MnL2 (1)
3.2. Characterization of the of MnL2O2 (2)
3.3. Synthesis and Characterization of MnL3 (3)
3.4. Synthesis and Characterization of MnL2′ (4)
3.5. Characterization of MnL2′O2 (5)
3.6. Synthesis and Characterization of MnL’3 (6)
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
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Compound | μeff ± SD |
---|---|
2 | 4.31 ± 0.03 |
3 | 4.28 ± 0.02 |
5 | 4.47 ± 0.14 |
6 | 4.17 ± 0.05 |
[Mn(III)(acac)3] | 4.62 ± 0.02 |
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Martini, P.; Boschi, A.; Marvelli, L.; Uccelli, L.; Carli, S.; Cruciani, G.; Marzola, E.; Fantinati, A.; Esposito, J.; Duatti, A. Synthesis and Characterization of Manganese Dithiocarbamate Complexes: New Evidence of Dioxygen Activation. Molecules 2021, 26, 5954. https://doi.org/10.3390/molecules26195954
Martini P, Boschi A, Marvelli L, Uccelli L, Carli S, Cruciani G, Marzola E, Fantinati A, Esposito J, Duatti A. Synthesis and Characterization of Manganese Dithiocarbamate Complexes: New Evidence of Dioxygen Activation. Molecules. 2021; 26(19):5954. https://doi.org/10.3390/molecules26195954
Chicago/Turabian StyleMartini, Petra, Alessandra Boschi, Lorenza Marvelli, Licia Uccelli, Stefano Carli, Giuseppe Cruciani, Erika Marzola, Anna Fantinati, Juan Esposito, and Adriano Duatti. 2021. "Synthesis and Characterization of Manganese Dithiocarbamate Complexes: New Evidence of Dioxygen Activation" Molecules 26, no. 19: 5954. https://doi.org/10.3390/molecules26195954