Recent Advances in the Self-Assembly of Block Copolymers

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Chemistry".

Deadline for manuscript submissions: 31 October 2024 | Viewed by 982

Special Issue Editors


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Guest Editor
Faculty of Chemistry, Lomonosov Moscow State University, Moscow, Russia
Interests: controlled polymer synthesis by radical polymerization with reversible chain deactivation; synthesis and self-organization of block copolymers and gradient copolymers; synthesis of acrylonitrile copolymers as potential carbon fiber precursors and study of their properties

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Guest Editor
Faculty of Physics, Lomonosov Moscow State University, Moscow, Russia
Interests: polymers; polymer synthesis; microgels; phase separation; nanostructured materials; self-assembly; electron microscopy; scattering methods

Special Issue Information

Dear Colleagues,

This Special Issue is devoted to the study of block copolymers and their self-assembly. Modern synthetic chemistry offers the possibility to design block copolymers with required functionalities, directly embodying the “code” that drives their self-assembly in bulk or their solution into chemically distinct domains with size and periodicity in the order of 10–100 nm. A large variety of distinct periodic morphologies, including simple, complex or even hierarchical assemblies can be obtained via the proper selection of macromolecules, the length and the order of the blocks, the degree of block incompatibility, and the chain architecture. These aggregates provide an inexpensive route to generate large-area nanostructured materials with potential or practical applications in many fields. To highlight the progress on block copolymer self-assembly, the controlled synthesis of new functional block copolymers with desired molecular architecture and morphology, modern insights in the physics of the directed self-assembly, including its theory and simulations, and major applications of block copolymers in drug delivery, soft lithography, porous materials, etc., are considered in this Special Issue.

Prof. Dr. Elena V. Chernikova
Dr. Elena Yu Kozhunova
Guest Editors

Manuscript Submission Information

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Keywords

  • block copolymers
  • living polymerization
  • reversible-deactivation radical polymerization
  • polymerization-induced self-assembly
  • self-assembly
  • morphology
  • microphase separation
  • stimulus-responsive block copolymers
  • theory and simulations
  • functional nanomaterials

Published Papers (1 paper)

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Review

67 pages, 14854 KiB  
Review
Modern Trends in Polymerization-Induced Self-Assembly
by Natalia S. Serkhacheva, Nickolay I. Prokopov, Evgenii A. Lysenko, Elena Yu. Kozhunova and Elena V. Chernikova
Polymers 2024, 16(10), 1408; https://doi.org/10.3390/polym16101408 - 15 May 2024
Viewed by 638
Abstract
Polymerization-induced self-assembly (PISA) is a powerful and versatile technique for producing colloidal dispersions of block copolymer particles with desired morphologies. Currently, PISA can be carried out in various media, over a wide range of temperatures, and using different mechanisms. This method enables the [...] Read more.
Polymerization-induced self-assembly (PISA) is a powerful and versatile technique for producing colloidal dispersions of block copolymer particles with desired morphologies. Currently, PISA can be carried out in various media, over a wide range of temperatures, and using different mechanisms. This method enables the production of biodegradable objects and particles with various functionalities and stimuli sensitivity. Consequently, PISA offers a broad spectrum of potential commercial applications. The aim of this review is to provide an overview of the current state of rational synthesis of block copolymer particles with diverse morphologies using various PISA techniques and mechanisms. The discussion begins with an examination of the main thermodynamic, kinetic, and structural aspects of block copolymer micellization, followed by an exploration of the key principles of PISA in the formation of gradient and block copolymers. The review also delves into the main mechanisms of PISA implementation and the principles governing particle morphology. Finally, the potential future developments in PISA are considered. Full article
(This article belongs to the Special Issue Recent Advances in the Self-Assembly of Block Copolymers)
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