Solar doi: 10.3390/solar4020009
Authors: Kenneth M. Hughes Chris C. Phillips
We consider the restrictions on photovoltaic (PV) capacity that are caused by limitations on where panels can be sited and find quantitative evidence for the need for high efficiencies. We define 15% of the UK’s energy consumption as a “significant” contribution and, with London as an exemplar, we perform an idealised calculation that makes the most optimistic possible assumptions about the capabilities of future PV technologies and use published surveys on energy usage, dwelling type and insolation. We find that covering every UK domestic roof with the highest power conversion efficiency (PCE) solar panels currently commercially available could produce up to 9% of the UK’s energy. A 15% contribution would require PV technologies with >37% PCE, more than the theoretical Shockley–Queisser limit. Replacing the idealising assumptions with more realistic estimates increases this by 2–3 times. Alternatively, a solar farm using the currently available PCEs would require a politically challenging ~1200 km2 of new land, roughly the area of Greater London, for this 15% contribution. We conclude that PCEs must be driven higher than even the Shockley–Queisser limit for PV to play a significant part in carbon mitigation.
]]>Solar doi: 10.3390/solar4010008
Authors: Reza Nematirad Anil Pahwa Balasubramaniam Natarajan
Integrating photovoltaic (PV) systems plays a pivotal role in the global shift toward renewable energy, offering significant environmental benefits. However, the PV installation should provide financial benefits for the utilities. Considering that the utility companies often incur costs for both energy and peak demand, PV installations should aim to reduce both energy and peak demand charges. Although PV systems can reduce energy needs during the day, their effectiveness in reducing peak demand, particularly in the early morning and late evening, is limited, as PV generation is zero or negligible at those times. To address this limitation, battery storage systems are utilized for storing energy during off-peak hours and releasing it during peak times. However, finding the optimal size of PV and the accompanying battery remains a challenge. While valuable optimization models have been developed to determine the optimal size of PV–battery systems, a certain gap remains where peak demand reduction has not been sufficiently addressed in the optimization process. Recognizing this gap, this study proposes a novel statistical model to optimize PV–battery system size for peak demand reduction. The model aims to flatten 95% of daily peak demands up to a certain demand threshold, ensuring consistent energy supply and financial benefit for utility companies. A straightforward and effective search methodology is employed to determine the optimal system sizes. Additionally, the model’s effectiveness is rigorously tested through a modified Monte Carlo simulation coupled with time series clustering to generate various scenarios to assess performance under different conditions. The results indicate that the optimal PV–battery system successfully flattens 95% of daily peak demand with a selected threshold of 2000 kW, yielding a financial benefit of USD 812,648 over 20 years.
]]>Solar doi: 10.3390/solar4010007
Authors: Gurleen Kaur Antonio J. Olivares Pere Roca i Cabarrocas
Nanocrystalline silicon oxide (nc-SiOx:H) is a multipurpose material with varied applications in solar cells as a transparent front contact, intermediate reflector, back reflector layer, and even tunnel layer for passivating contacts, owing to the easy tailoring of its optical properties. In this work, we systematically investigate the influence of the gas mixture (SiH4, CO2, PH3, and H2), RF power, and process pressure on the optical, structural, and passivation properties of thin n-type nc-SiOx:H films prepared in an industrial, high-throughput, plasma-enhanced chemical vapor deposition (PECVD) reactor. We provide a detailed description of the n-type nc-SiOx:H material development using various structural and optical characterization techniques (scanning electron microscopy (SEM), energy dispersive X-ray (EDX), Raman spectroscopy, and spectroscopic ellipsometry) with a focus on the relationship between the material properties and the passivation they provide to n-type c-Si wafers characterized by their effective carrier lifetime (τeff). Furthermore, we also outline the parameters to be kept in mind while developing different n-type nc-SiOx:H layers for different solar cell applications. We report a tunable optical gap (1.8–2.3 eV) for our n-type nc-SiOx:H films as well as excellent passivation properties with a τeff of up to 4.1 ms (implied open-circuit voltage (iVoc)~715 mV) before annealing. Oxygen content plays an important role in determining the crystallinity and hence passivation quality of the deposited nanocrystalline silicon oxide films.
]]>Solar doi: 10.3390/solar4010006
Authors: Noor Alqallaf Rami Ghannam
This paper presents a comprehensive and systematic review of virtual reality (VR) as an innovative educational tool specifically for solar photovoltaic energy systems. VR technology, with its immersive and interactive capabilities, offers a unique platform for in-depth learning and practical training in the field of solar energy. The use of VR in this context not only enhances the understanding of solar photovoltaic (PV) systems but also provides a hands-on experience that is crucial for developing the necessary skills in this rapidly evolving field. Among the 6814 articles initially identified, this systematic review specifically examined 15 articles that focused on the application of VR in PV education. These selected articles demonstrate VR’s ability to accurately simulate real-world environments and scenarios related to solar energy, providing an in-depth exploration of its practical applications in this field. By offering a realistic and detailed exploration of PV systems, VR enables learners to gain a deeper understanding of harnessing, managing and using such a vast energy resource. The paper further discusses the implications of employing VR in educational settings, highlighting its potential to change the way solar energy professionals are trained, thereby contributing significantly to the acceleration of photovoltaic technology adoption and its integration into sustainable energy solutions.
]]>Solar doi: 10.3390/solar4010005
Authors: Khadija Barhmi Chris Heynen Sara Golroodbari Wilfried van Sark
Solar energy forecasting is essential for the effective integration of solar power into electricity grids and the optimal management of renewable energy resources. Distinguishing itself from the existing literature, this review study provides a nuanced contribution by centering on advancements in forecasting techniques. While preceding reviews have examined factors such as meteorological input parameters, time horizons, the preprocessing methodology, optimization, and sample size, our study uniquely delves into a diverse spectrum of time horizons, spanning ultrashort intervals (1 min to 1 h) to more extended durations (up to 24 h). This temporal diversity equips decision makers in the renewable energy sector with tools for enhanced resource allocation and refined operational planning. Our investigation highlights the prominence of Artificial Intelligence (AI) techniques, specifically focusing on Neural Networks in solar energy forecasting, and we review supervised learning, regression, ensembles, and physics-based methods. This showcases a multifaceted approach to address the intricate challenges associated with solar energy predictions. The integration of Satellite Imagery, weather predictions, and historical data further augments precision in forecasting. In assessing forecasting models, our study describes various error metrics. While the existing literature discusses the importance of metrics, our emphasis lies on the significance of standardized datasets and benchmark methods to ensure accurate evaluations and facilitate meaningful comparisons with naive forecasts. This study stands as a significant advancement in the field, fostering the development of accurate models crucial for effective renewable energy planning and emphasizing the imperative for standardization, thus addressing key gaps in the existing research landscape.
]]>Solar doi: 10.3390/solar4010004
Authors: Roberto Jakomin Stefano Rampino Giulia Spaggiari Michele Casappa Giovanna Trevisi Elena Del Canale Enos Gombia Matteo Bronzoni Kodjo Kekeli Sossoe Francesco Mezzadri Francesco Pattini
In recent years, research attention has increasingly focused on thin-film photovoltaics utilizing Sb2Se3 as an ideal absorber layer. This compound is favored due to its abundance, non-toxic nature, long-term stability, and the potential to employ various cost-effective and scalable vapor deposition (PVD) routes. On the other hand, improving passivation, surface treatment and p-type carrier concentration is essential for developing high-performance and commercially viable Sb2Se3 solar cells. In this study, Cu-doped Sb2Se3 solar devices were fabricated using two distinct PVD techniques, pulsed electron deposition (PED) and radio frequency magnetron sputtering (RFMS). Furthermore, 5%Cu:Sb2Se3 films grown via PED exhibited high open-circuit voltages (VOC) of around 400 mV but very low short-circuit current densities (JSC). Conversely, RFMS-grown Sb2Se3 films resulted in low VOC values of around 300 mV and higher JSC. To enhance the photocurrent, we employed strategies involving a thin NaF layer to introduce controlled local doping at the back interface and a bilayer p-doped region grown sequentially using PED and RFMS. The optimized Sb2Se3 bilayer solar cell achieved a maximum efficiency of 5.25%.
]]>Solar doi: 10.3390/solar4010003
Authors: Hussain Al Mahdi Paul G. Leahy Mohammad Alghoul Alan P. Morrison
With the global increase in the deployment of photovoltaic (PV) modules in recent years, the need to explore and understand their reported failure mechanisms has become crucial. Despite PV modules being considered reliable devices, failures and extreme degradations often occur. Some degradations and failures within the normal range may be minor and not cause significant harm. Others may initially be mild but can rapidly deteriorate, leading to catastrophic accidents, particularly in harsh environments. This paper conducts a state-of-the-art literature review to examine PV failures, their types, and their root causes based on the components of PV modules (from protective glass to junction box). It outlines the hazardous consequences arising from PV module failures and describes the potential damage they can bring to the PV system. The literature reveals that each component is susceptible to specific types of failure, with some components deteriorating on their own and others impacting additional PV components, leading to more severe failures. Finally, this review briefly summarises PV failure detection techniques, emphasising the significance of electrical characterisation techniques and underlining the importance of considering more electrical parameters. Most importantly, this review identifies the most prevalent degradation processes, laying the foundation for further investigation by the PV research community through modelling and experimental studies. This allows for early detection by comparing PV performance when failures or degradation occur to prevent serious progression. It is worth noting that most of the studies included in this review primarily focus on detailing failures and degradation observed in PV operations, which can be attributed to various factors, including the manufacturing process and other external influences. Hence, they provide explanations of these failure mechanisms and causes but do not extensively explore corrective actions or propose solutions based on either laboratory experiments or real-world experience. Although, within this field of study, there are corresponding studies that have designed experiments to suggest preventive measures and potential solutions, an in-depth review of those studies is beyond the scope of this paper. However, this paper, in turn, serves as a valuable resource for scholars by confining PV failures to critically evaluate available studies for preventative measures and corrective actions.
]]>Solar doi: 10.3390/solar4010002
Authors: Lisete Fernandes Pedro B. Tavares
Food waste is one of the biggest challenges we are facing nowadays. According to the Food and Agriculture Organization (FAO) of the United Nations, approximately one-third of all food produced in the world is lost at some stage between production and consumption, totaling 930 million tons of food per year. Meanwhile, 10.5% of humanity suffers from malnutrition, 26% are overweight and greenhouse gases derived from the food industry account for between 25 and 30% of total emissions (8 to 10% referring to food waste), exacerbating the current climate crisis. To address these concerns, there has been a growing inclination to seek alternatives to fossil fuels, including the adoption of solar energy across diverse sectors, including the food industry. Actions are needed in order to change these patterns. This review article aims to provide an overview of recent developments in the field of solar food dehydration and the types of dehydrators that have emerged. Extensive research and bibliographic analysis, including other review articles, have revealed a growing focus on investment in this area to develop solar dehydrators that are increasingly effective but as sustainable as possible.
]]>Solar doi: 10.3390/solar4010001
Authors: Manuel Betancourt Schwarz Mathilde Veyron Marc Clausse
Renewable energy sources, distributed generation, multi-energy carriers, distributed storage, and low-temperature district heating systems, among others, are demanding a change in the way thermal networks are conceived, understood, and operated. Governments around the world are moving to increase the renewable share in energy distribution networks through legislation like the European Directive 2012/27 in Europe, and solar energy integration into district heating systems is arising as an interesting option to reduce operation costs and carbon footprint. This conveys an important investment that adds complexity to the management of thermal networks and often delays the return on investment due to the unpredictability of renewable energy sources, like solar radiation. To this end, this paper presents an optimisation methodology to aid in the operative control of an existing solar district heating system located in the northwest of France. The modelling of the system, which includes a large-scale solar field, a biomass boiler, a gas boiler, and thermal energy storage, was previously built in Dymola. The optimisation of this network was performed using MATLAB’s genetic algorithm (GA) and running the Dymola model as functional mock-up units, FMUs, using Simulink’s FMI Kit. The results show that the methodology presented here can reduce the current operation costs and improve the use of the daily storage of the DH system by a combination of mass flow control and the implementation of a flexibility function for the end-users. The cost-per-kWh was reduced by as much as 16% in a single day, and the share of heat supplied by the solar field on this day was increased by 5.22%.
]]>Solar doi: 10.3390/solar3040036
Authors: Sharmarke Hassan Mahmoud Dhimish
Detection of cracks in solar photovoltaic (PV) modules is crucial for optimal performance and long-term reliability. The development of convolutional neural networks (CNNs) has significantly improved crack detection, offering improved accuracy and efficiency over traditional methods. This paper presents a comprehensive review and comparative analysis of CNN-based approaches for crack detection in solar PV modules. The review discusses various CNN architectures, including custom-designed networks and pre-trained models, as well as data-augmentation techniques and ensemble learning methods. Additionally, challenges related to limited dataset sizes, generalizability across different solar panels, interpretability of CNN models, and real-time detection are discussed. The review also identifies opportunities for future research, such as the need for larger and more diverse datasets, model interpretability, and optimized computational speed. Overall, this paper serves as a valuable resource for researchers and practitioners interested in using CNNs for crack detection in solar PV modules.
]]>Solar doi: 10.3390/solar3040035
Authors: Ayed Banibaqash Ziad Hunaiti Maysam Abbod
Qatar’s ambitious Vision 2030 includes a major shift towards clean energy, and residential solar PV installation can be an obvious option, given its abundant sunlight and high power for residential cooling. Despite significant solar panel farm investment, there has been limited progress in deploying solar panels on home roofs, and further research is needed to identify the potential for such an initiative and its impact on the country’s move towards clean energy. This field survey assesses the potential for residential rooftop solar panel installation across Qatar, considering space availability, currently utilized space, remaining space, shading, and roof type. It also provided indications of potential obstacles and shading that might affect panel sunlight exposure. The results showed that there is significant potential for installing solar panels on Qatari homes, which could contribute to a considerable portion of the energy consumed by households during peak usage periods, particularly in the summer months. Moreover, excess energy generated could be exported to other countries with high demand during periods of low demand in Qatar. The study’s findings complement previous research efforts and provide insights for policymakers and stakeholders to develop strategies that endorse the vision for 2030 and promote the transition towards clean energy in Qatar.
]]>Solar doi: 10.3390/solar3040034
Authors: Michael M. Santos Ana Teresa Vaz Ferreira João C. G. Lanzinha
Africa has abundant solar resources but only 2% of its current capacity is generated from renewable sources. Photovoltaics (PV) offer sustainable, decentralized electricity access to meet development needs. This review synthesizes the recent literature on PV in Africa, with a focus on Mozambique. The 10 most cited studies highlight the optimization of technical components, such as storage and bifacial modules, and challenges in integrating large-scale PV. Case studies demonstrated Mozambique’s potential for PV applications in water heating, irrigation, and rural electrification. These benefits include reduced emissions and energy access. However, barriers, such as high costs, lack of infrastructure, and training, exist. While solar cookers are insufficient, thermal systems have unrealized potential. Mozambique’s urban and rural electrification rates are 57% and 13%, respectively, despite its energy resources. Targeted policies, financing, and community engagement are essential for promoting adoption. While PV can sustainably expand electricity access, coordinated efforts must address costs, infrastructure, maintenance, and social factors for successful implementation. Mozambique has immense solar potential, but strategic planning and support are critical to unlocking these benefits. This review provides insights into optimizing PV systems and policy frameworks for a clean and inclusive energy production future in Africa, to synthesize the 10 most cited studies on photovoltaic solar energy in Africa, and to deeply reflect upon the current energy needs in Mozambique, the benefits of employing PV and solar thermal systems, and the challenges of implementing such systems within the Mozambican context.
]]>Solar doi: 10.3390/solar3040033
Authors: Nosakhare Aigbedion Francis Njoka Mathew Munji
This study combines simulations and experiments to study the heat interactions between various types of roofs and the photovoltaic (PV) modules installed on them. Specifically, the performance of PV modules on a clay roof was compared with their performance on two types of metal roofs, a Box-profile metal roof and an Orientile metal roof, which differ in shape and geometry. Additionally, this study examined the cooling potential of three common metal roof pigments, iron (iii) oxide (Fe2O3), titanium dioxide (TiO2) and basalt, on roof-installed PV modules. An unpigmented roof was also studied for comparison purposes. Model development and simulation were implemented in COMSOL Multiphysics, and the simulation results were validated and compared with field experiments. The maximum open-circuit voltages of the PV installations were found to be 21.096 V for the clay roof, 20.945 V for the Box-profile metal roof and 20.718 V for the Orientile metal roof. This study revealed that the unpigmented roof had higher solar cell temperatures compared to the pigmented models, with temperature gains ranging from 2.2 °C to 2.71 °C. Moreover, the unpigmented model displayed significantly higher surface radiosity than the pigmented models. The performance output of the modules also varied depending on the metal roof sheet shape and geometry, with the Box-profile metal roof yielding better results than the Orientile metal roof sheet. These results indicate that a specific roof pigmentation may have a small impact on a single PV module, but it can become significant in a large array of modules, especially if cooling through natural convection is hindered.
]]>Solar doi: 10.3390/solar3040032
Authors: Francisca Muriel Daniel-Durandt Arnold Johan Rix
A review of quality control for large irradiance datasets is applied as a case study for the Southern African Universities Radiometric Network (SAURAN) database. The quality control procedure is automated and applied to 24 stations from the database with a total of 848,189 hourly datapoints. From this, the individual station’s data quality is also analysed. The assessment validates the automated methodology without the need for a user-based review of the data. The SAURAN database can play a significant role in advancing solar and wind energy; however, the number of offline stations hinders this process. Data scarcity remains an obstacle to these goals, and therefore, recommendations are provided to address this. Recommendations regarding each site’s usability in time-series and discrete applications are made, which provides an overall indication of the SAURAN database’s irradiance measurement quality. Of the 24 measuring stations assessed, eight are recommended, 11 are recommended with cautious use, and five are recommended with extremely cautious use. These recommendations are based on multiple factors, such as whether a dataset has more than one full year of data or is missing minimal datapoints. Further, a study of the irradiance correlation between the stations was conducted. The results indicated groupings of different stations that showed highly correlated irradiance measurements and similar weather patterns. This is useful if a proposed renewable energy power plant, such as PV, falls within a cluster where the data from the SAURAN database can be used as a substitute if no data is available. SAURAN presents an opportunity for Southern Africa to increase its research outputs in solar and wind energy and lessen its dependency on fossil fuel-based energy production.
]]>Solar doi: 10.3390/solar3040031
Authors: Roberto Jakomin Stefano Rampino Giulia Spaggiari Francesco Pattini
Sb2Se3, as an earth-abundant and low-toxic material, has emerged as one of the most interesting absorbers for clean renewable power generation technologies. Due to its optical properties, especially bandgap and absorption coefficient, the number of papers on Sb2Se3-based solar cells has been constantly increasing in the last ten years, and its power conversion efficiency has raised from 1% in 2014 to 10.57% in 2022. In this review, different Sb2Se3 solar cells’ fabrication technologies based on physical vapor deposition are described and correlated to the texture coefficient (ribbon orientation). Moreover, recent research works of the most promising solar cell configurations with different electron-transporting layers and hole-transporting layers are analyzed with a special emphasis on photovoltaic performances. Furthermore, different Sb2Se3 doping techniques are discussed. All these aspects are considered as new strategies to overcome the Sb2Se3 solar cell’s actual limitations.
]]>Solar doi: 10.3390/solar3040030
Authors: Amedeo Ebolese Domenico Marano Carlo Copeta Agatino Bruno Vincenzo Sabatelli
The development of small-sized parabolic trough collectors (PTCs) for processing heat production at medium temperatures (100–250 °C) represents an interesting approach to increase the utilization of solar thermal technologies in industrial applications. Thus, the development of simplified models to analyze and predict their performance under different operative and climatic conditions is crucial for evaluating the application potential of this low-cost technology. In this paper, we present a numerical method that by combining three-dimensional finite element simulations (implemented with COMSOL Multiphysics software version 6.1) with a one-dimensional analysis (based on a MATLAB script) allows for the theoretical determination of the power output of a small-PTC with a nonevacuated tubular receiver operating at a medium temperature. The finite element model considers both the nonuniformity of the concentrated solar flux on the receiver tube (evaluated using Monte Carlo ray-tracing analysis) and the establishment of natural convection in the air gap between the glass envelope and absorber tube. The model calculates, for several values of direct normal irradiance (DNI) and inlet temperatures, the thermal power transferred to the heat transfer fluid (HTF) per unit length. The data are fitted using the multiple linear regression method, obtaining a function that is then used in a one-dimensional multi-nodal model to estimate the temperatures and the heat gains along the receiver tube. The outputs of the model are the outlet temperature and the total thermal power transferred to the HTF. In order to validate the developed methodology for the assessment of the heat transfer characteristics in the small-PTC with a nonevacuated receiver, an experiment at the ENEA Trisaia—Solar Thermal Collector Testing Laboratory was carried out. This work compares the theoretical data with those acquired through experimentation, obtaining a good agreement, with maximum differences of 0.2% and 3.6% for the outlet temperatures and the power outputs, respectively.
]]>Solar doi: 10.3390/solar3030029
Authors: Abid Ali Maïté Volatier Maxime Darnon
Despite abundant solar resources, Mali has remained one of the least electrified countries in the world. Besides daily life activities and the economy, the shortage of electricity has severely affected the quality of healthcare services in the country. In the absence of electrical grids, standalone photovoltaic (PV) systems could be an alternative option in Mali for the electrification of isolated community health centers. However, because standalone PV systems are highly weather-dependent, they must be properly sized according to the local weather conditions. This paper presents the optimal sizing of standalone PV systems for the electrification of community health centers in Mali. The optimization for PV systems was performed for five different locations through simulation and modeling using PVsyst, considering the autonomy of 1 to 3 days and the probability of loss of load for 1 to 5%. Furthermore, for the economic analysis, the levelized cost of electricity (LCOE), payback period and return on investment for the standalone PV systems were calculated. Through the optimization, it was found that the standalone PV systems with PV array sizes ranging from 1650 to 2400 watts, along with 606 Ah battery storage, would be suitable to supply the daily energy demand for community health centers anywhere in the country. Moreover, by only replacing the 606 Ah battery storage with 1212 Ah and 1818 Ah sizes, the PV systems would be able to help and keep the energy reserves for 2 and 3 autonomous days, respectively. Furthermore, the results show that in comparison to a LCOE of 0.94–0.98 USD/kWh for a diesel generator, the LCOE for the standalone PV system would range from 0.23 to 0.46 USD/kWh without discounted rates and from 0.33 to 0.60 USD/kWh if discounted at 6%. In addition to a lower LCOE, the saving of 46–76 tons of CO2 during the project’s lifespan, the short payback periods and high return of investment (ROI) values make standalone PV systems a suitable electrification option for Mali. Considering the total expenses, LCOE, payback period, and ROI, standalone PV systems for community health centers were found to be economically viable in all cases for Mali.
]]>Solar doi: 10.3390/solar3030028
Authors: Jaewook Chung Sreenath Sukumaran Aleksandr Hlebnikov Anna Volkova
The decarbonization of the district heating (DH) sector is receiving attention worldwide. Solar energy and heat pump technologies are widely considered in existing and new DH networks. There is a need to understand the influence of solar energy on district heating experimentally. However, only a few university laboratories are focused on district heating aspects. Further, the concept of such laboratories is not adequately disseminated in the scientific literature. The main objective of this paper is to develop a conceptual design of a solar energy laboratory with a focus on district heating systems. The proposed concept forms part of the preliminary study carried out by a research group at the Tallinn University of Technology. First, a brief literature review on solar energy laboratory development is provided. Then, the conceptual design of such a laboratory is presented, along with a case study. Regardless of project size, the main components of a district heating-based solar energy laboratory are solar collectors, thermal energy storage (TES) tanks, and a control system. The proposed laboratory is expected to serve multiple roles, such as a practical laboratory to provide interdisciplinary courses for students, a research and experimental platform for researchers, and a cradle to achieve the campus green initiative. It is roughly estimated that the thermal energy output from the proposed laboratory would meet around 25% of the heat demand of the institutional building during the summer season (May, June, July, and August). It is expected that the present study will be a reference material for the development of innovative energy laboratories in educational institutions.
]]>Solar doi: 10.3390/solar3030027
Authors: João P. Cardoso António Couto Paula A. Costa Carlos Rodrigues Jorge Facão David Loureiro Anne Wambugu Sandra Banda Izael Da Silva Teresa Simões
The challenges associated with traditional cooking methods in African countries, particularly the use of firewood and charcoal, which have negative impacts on the environment, health and human and economic development and safety, are addressed in this work. Given the high annual solar irradiation on the African continent, photovoltaic-powered electric cooking alternatives, such as electric pressure cookers (EPCs), are identified as a potential efficient, clean and affordable cooking solution. This work focuses on the potential of standalone solar electric cookers for use in rural African locations, namely, if this type of solution can satisfy cooking demand. Surveys and experimental data from several households in two different countries (Rwanda and Kenya) were collected. Specifically, the researchers performed a survey regarding cooking habits and an experimental campaign to determine real energy consumption profiles of EPCs. The main results are analyzed and discussed in this work. An assessment of the solar power capability to directly supply the EPCs’ energy demand, as determined from the experimental data, is performed. The findings indicate that, for the most commonly prepared food types, using EPCs saves considerable time in comparison with traditional cooking methods. In Rwanda, time savings range from 55% to 84%, while in Kenya, the time saved varies from 9% to 64%. Results show that, even for scenarios with high installed solar capacity, storage solutions are required to enable the PV-powered EPC system to supply more than 50% of meal demand.
]]>Solar doi: 10.3390/solar3030026
Authors: Elias Kaufhold Jan Meyer Johanna Myrzik Peter Schegner
The growth of renewables in the energy sector, e.g., in public low-voltage networks, leads to an increasing share of installed power electronic devices, e.g., inverters for photovoltaic applications. To rely on these devices, suitable analyses have to be performed. This includes studies of the device stability in the harmonic frequency range, i.e., above 50 Hz up to 2 kHz. State-of-the-art time-domain studies for harmonic stability analyses require detailed knowledge about the inverter design. Black-box studies must identify the inverter characteristics in the laboratory, which can differ depending on specific operating points, i.e., specific operating powers. This study analyzes the operating-point dependency of inverters on the critical inductance values of the network impedance, e.g., the inductances at which the inverter is expected to become unstable. Measurements are performed for three operating powers of an unknown, commercially available single-phase inverter to validate the critical inductances. Two further commercially available inverters and four simulative implementations are analyzed as well with regard to the critical inductance and the critical frequency. The results demonstrate the importance of considering a representative range of operating powers of the inverter for the small-signal stability analysis.
]]>Solar doi: 10.3390/solar3030025
Authors: Abraham Dimitri Kapim Kenfack Nicolas Matome Thantsha Mandla Msimanga
This paper presents the simulation of the novel prototype of a heterojunction perovskite solar cell (PSC) based on CSGeI2Br/CSGeI3. The device consists of two absorber layers (CSGeI2Br, CSGeI3), an electron transport layer (ETL) chosen as TiO2 and a hole transport layer (HTL) given as poly(3-hexylthiophene) (P3HT). Within the simulation, the effects of thickness, doping and defect density in each absorber layer and different back contact metal electrodes on electrical parameters (efficiency, short circuit current, open circuit voltage, and fill factor) are evaluated. In addition, the contribution of the HTL (doping density and thickness), temperature, shunt and series resistance were also checked on the same electrical parameters. The simulations are conducted in standard test conditions with the irradiation normalized as 0.1 W/cm2 using the SCAPS-1D platform. The maximum efficiency obtained within the simulation of this device was about 31.86%. For this device, the thickness of the CSGeI3 layer should be around 900 nm, while that of the CsGeI2Br should be around 100 nm to facilitate optimal absorption of the incident photons. The doping density in the absorber layer is such that in CsGeI3 should be around 1018 cm−3 and around 1016 cm−3 in the CsGeI2Brlayer. The defects densities in both layers of the perovskite materials should be around 1014 cm−3. Concerning the HTL, the thickness and the doping density of the P3HT should be around 50 nm and  1018 cm−3, respectively. In terms of the back contact electrode, the work function of the metal should be at least equal to 5 eV, corresponding to gold (Au) metal. The series resistance due to the connection of the cell to the external load should be very small, while the shunt resistance due to the leakage current in the solar cell should be high. Furthermore, the operating temperature of the new PSC should be maintained at an ambient level of around 25 °C in order to deliver high efficiency.
]]>Solar doi: 10.3390/solar3030024
Authors: Nikolaos Skandalos Vasileios Kapsalis Tao Ma Dimitris Karamanis
The necessity of affordable and durable building-integrated photovoltaics has gained widespread importance for the renewable energy transition involving electrification and decarbonization in climate-neutral cities that possess many public health co-benefits. Although the PV market is dominated by polycrystalline and monocrystalline silicon solar cells of the first generation, there is an impetus in the research lately for more sophisticated solar cell architectures with higher efficiency, longer lifetime, and less use of raw materials in an eco-design approach. To accelerate building integration of the next generation of photovoltaics and the associated climate change mitigation benefits, we propose in this work a holistic novel approach to the requirements and associated parameters for the emerging and innovative PV structures, spanning from intrinsic cell properties to panels effect in the urban environment. Within this framework, and supported by building simulation, the improvement of cells’ efficiency is revealed as an important parameter for their wider PV building and urban deployment as well as a major improvement in covering the building energy needs with minimized thermal impact in the urban environment. By analyzing the lab-reported values and the timeline of emerging and novel tandem solar cells, we propose the 30% BIPV efficiency of the eco-designed BIPV products as a central milestone to be attained before 2030 for a sustainable urban transformation.
]]>Solar doi: 10.3390/solar3030023
Authors: David Firnando Silalahi Andrew Blakers
In this paper, we analyse 40 years of maximum wind speed and wave height data to identify potential sites for solar photovoltaic (PV) systems floating on seas and oceans. Maximum hourly wave height and wind speed data were segregated into 5 distinct categories. These categorisations were then combined at the nearest wind speed and wave height grid point for each sea location, generating a comprehensive wind–wave map via a geographic information system (GIS) visualisation. We find that regions around the equator are generally calm, i.e., free from strong winds and large waves. The most favourable locations are around the Indonesian archipelago, and the Gulf of Guinea on the west coast of tropical Africa. Our analysis indicates the huge potential of floating solar PV systems in calm tropical maritime regions, capable of generating about one million terawatt-hours per year in regions that rarely experience waves larger than 6 m or winds stronger than 15 m/s. This study furthers our understanding of alternative renewable energy options, emphasising the promising potential of offshore floating solar PV systems in the global energy transition.
]]>Solar doi: 10.3390/solar3030022
Authors: Hai-Ying Liu Nikolaos Skandalos Liga Braslina Vasileios Kapsalis Dimitris Karamanis
This study focuses on achieving climate neutrality in European cities by integrating solar energy technologies and nature-based solutions. Through an examination of current practices, emerging trends, and case examples, the study explores the benefits, challenges, and prospects associated with this integration in urban contexts. A pioneering approach is presented to assess the urban heat and climate change mitigation benefits of combining building-integrated photovoltaics and nature-based solutions within the European context. The results highlight the synergistic relationship between nature-based components and solar conversion technology, identifying effective combinations for different climatic zones. In Southern Europe, strategies such as rooftop photovoltaics on cool roofs, photovoltaic shadings, green walls, and urban trees have demonstrated effectiveness in warmer regions. Conversely, mid- and high-latitude European cities have seen positive impacts through the integration of rooftop photovoltaics and photovoltaic facades with green roofs and green spaces. As solar cell conversion efficiency improves, the environmental impact of photovoltaics is expected to decrease, facilitating their integration into urban environments. The study emphasizes the importance of incorporating water bodies, cool pavements, spaces with high sky-view factors, and effective planning in urban design to maximize resilience benefits. Additionally, the study highlights the significance of prioritizing mitigation actions in low-income regions and engaging citizens in the development of social photovoltaics-positive energy houses, resilient neighbourhoods, and green spaces. By adopting these recommendations, European cities can create climate-neutral urban environments that prioritize clean energy, nature-based solutions, and the overall wellbeing of residents. The findings underscore the need for a multidisciplinary approach combining technological innovation, urban planning strategies, and policy frameworks to effectively achieve climate neutrality.
]]>Solar doi: 10.3390/solar3030021
Authors: Saman Sharbaf Kalaghichi Jan Hoß Renate Zapf-Gottwick Jürgen H. Werner
Passivated, selective contacts in silicon solar cells consist of a double layer of highly doped polycrystalline silicon (poly Si) and thin interfacial silicon dioxide (SiO2). This design concept allows for the highest efficiencies. Here, we report on a selective laser activation process, resulting in highly doped p++-type poly Si on top of the SiO2. In this double-layer structure, the p++-poly Si layer serves as a layer for transporting the generated holes from the bulk to a metal contact and, therefore, needs to be highly conductive for holes. High boron-doping of the poly Si layers is one approach to establish the desired high conductivity. In a laser activation step, a laser pulse melts the poly Si layer, and subsequent rapid cooling of the Si melt enables electrically active boron concentrations exceeding the solid solubility limit. In addition to the high conductivity, the high active boron concentration in the poly Si layer allows maskless patterning of p++-poly Si/SiO2 layers by providing an etch stop layer in the Si etchant solution, which results in a locally structured p++-poly Si/SiO2 after the etching process. The challenge in the laser activation technique is not to destroy the thin SiO2, which necessitates fine tuning of the laser process. In order to find the optimal processing window, we test laser pulse energy densities (Hp) in a broad range of 0.7 J/cm2 ≤ Hp ≤ 5 J/cm2 on poly Si layers with two different thicknesses dpoly Si,1 = 155 nm and dpoly Si,2 = 264 nm. Finally, the processing window 2.8 J/cm2≤ Hp ≤ 4 J/cm2 leads to the highest sheet conductance (Gsh) without destroying the SiO2 for both poly Si layer thicknesses. For both tested poly Si layers, the majority of the symmetric lifetime samples processed using these Hp achieve a good passivation quality with a high implied open circuit voltage (iVOC) and a low saturation current density (J0). The best sample achieves iVOC = 722 mV and J0 = 6.7 fA/cm2 per side. This low surface recombination current density, together with the accompanying measurements of the doping profiles, suggests that the SiO2 is not damaged during the laser process. We also observe that the passivation quality is independent of the tested poly Si layer thicknesses. The findings of this study show that laser-activated p++-poly Si/SiO2 are not only suitable for integration into advanced passivated contact solar cells, but also offer the possibility of maskless patterning of these stacks, substantially simplifying such solar cell production.
]]>Solar doi: 10.3390/solar3030020
Authors: Carlo Spampinato Paola La Magna Salvatore Valastro Emanuele Smecca Valentina Arena Corrado Bongiorno Giovanni Mannino Enza Fazio Carmelo Corsaro Fortunato Neri Alessandra Alberti
Perovskite solar cells have become a popular alternative to traditional silicon solar cells due to their potential to provide high-efficiency, low-cost, and lightweight solar energy harvesting solutions. However, the multilayer architecture of perovskite solar cells demands careful investigation of the interaction and interfacing between the various layers, as they play a crucial role in determining the overall performance of the cell. In this context, the present work aims at analyzing the coupling between a spongy transparent electron-transporting layer (ETL) and perovskite in a formulation CsPbI3:EuI2. The ETL used in this work is a transparent mesoporous TiO2 layer called “gig-lox” (grazing incidence angle geometry–local oxidation), which has been optimized to boost the interfacing with the perovskite for achieving a highly interconnected blend of materials. The gig-lox TiO2 ETL shows a high surface wettability with respect to the perovskite solution, especially after pre-annealing at 500 °C, and this enables the perovskite material to deeply infiltrate throughout it. The surface wettability of the gig-lox TiO2 has been estimated by contact angle measurements, while the deep infiltration of the perovskite material has been demonstrated through X-ray diffraction and transmission electron microscopy analyses. Thanks to the achieved deep infiltration, the photo-generated charge injection from the perovskite into the mesoporous oxide is enhanced with respect to the use of a planar compact oxide, as shown by the photoluminescence measurements. The mainstay of the approach resides in the ETL that is deposited by a solvent-free sputtering method and is up-scalable for high industrial throughput.
]]>Solar doi: 10.3390/solar3020019
Authors: Ghadeer Badran Mahmoud Dhimish
Photovoltaic (PV) technology plays a crucial role in the transition towards a low-carbon energy system, but the potential-induced degradation (PID) phenomenon can significantly impact the performance and lifespan of PV modules. PID occurs when a high voltage potential difference exists between the module and ground, leading to ion migration and the formation of conductive paths. This results in reduced power output and poses a challenge for PV systems. Research and development efforts have focused on the use of new materials, designs, and mitigation strategies to prevent or mitigate PID. Materials such as conductive polymers, anti-reflective coatings, and specialized coatings have been developed, along with mitigation strategies such as bypass diodes and DC-DC converters. Understanding the various factors that contribute to PID, such as temperature and humidity, is critical for the development of effective approaches to prevent and mitigate this issue. This review aims to provide an overview of the latest research and developments in the field of PID in PV modules, highlighting the materials, designs, and strategies that have been developed to address this issue. We emphasize the importance of PID research and development in the context of the global effort to combat climate change. By improving the performance and reliability of PV systems, we can increase their contribution to the transition towards a low-carbon energy system.
]]>Solar doi: 10.3390/solar3020018
Authors: Vadan Padiachy Utkal Mehta
This paper presents a new fractional-order proportional-integral, (PI)λ (FO[PI]) type structure to investigate the load frequency control (LFC) problem. In the literature, some controllers’ extensive tuning options may slow or complicate the optimization process. Due to the intricacy of the tuning, even if there are fewer tuning parameters, a robust structure can be obtained. The (PI)λ structure deviates from the standard FOPI, integer PID, or PI-PD controllers with the same or fewer tuning parameters. The efficacy of a tri-parametric fractional-order controller is examined on a two-area interconnected hybrid power system comprising a photovoltaic (PV) grid and a Reheated Thermal Generator (RTG). In order to obtain optimal performance with lower control efforts, a novel dual-performance index is developed for the LFC problem. Various analyses are also proven to perform better than other optimized controllers from the recent literature. The presented scheme is significantly robust to disturbance interruptions, non-linearities, and parameter perturbations. It is also observed that there are no stability issues due to communication time delays. It is highlighted that the improvement can be obtained without adding complex structure or controller parameters.
]]>Solar doi: 10.3390/solar3020017
Authors: Tatiana Montagni Mauricio Rodríguez Chialanza María Fernanda Cerdá
This work aimed to show the possibility of applying anthocyanins extracted from blueberries following a straightforward path as potential impregnation dyes in dye-sensitized solar cells (DSSCs), particularly in the presence of co-adsorbents, such as silver nanoparticles, as an alternative in order to profit from large amounts of discarded fruits. Following a simple procedure, anthocyanins (mainly delphinidin-3-glucoside) were obtained from blueberries (Southern Highbush type). Complete characterization was carried out in order to prove the utility of delphinidin-3-glucoside as a sensitizer in DSSCs. The analyzed anthocyanin is suitable for sensitizing because of its high molar absorptivity values within the visible region of the light spectra, the adsorption ability to a FTO/TiO2 electrode (FTO, fluorine-doped tin oxide) as confirmed by Fourier transform infrared (FTIR) as well as thermogravimetry coupled to differential scanning calorimetry (TG-DSC), a potential oxidation value near 1 V, and adequate thermal as well as light stabilities. Moreover, the cell’s conversion efficiency is improved in the presence of silver nanoparticles, reaching 0.24% (nearly a 25% increase). The sum of all these characteristics points to the application of delphinidin-3-glucoside as a sensitizer in DSSCs, offering a technological use with potential interest for countries where agricultural production offers an abundant origin of extraction.
]]>Solar doi: 10.3390/solar3020016
Authors: Ilaria Marotta Thibault Péan Francesco Guarino Sonia Longo Maurizio Cellura Jaume Salom
The paper presents the analysis of energy retrofitting, integration of renewable energy and activation of energy flexibility in a cluster of buildings in the surroundings of a port on the Mediterranean Sea in Southern Italy, with the aim of checking the potential for it to achieve the status of positive energy district (PED). The objective of this study is to improve the contemporaneity between local energy generation and energy demand and reduce CO2eq emissions by considering signals that reflect the environmental variability of the electricity grid, through flexibility solutions applied to the HVAC system. The proposed scenarios are based on the dynamic simulation of the district and analyze the effect of actions that activate the energy flexibility of buildings through advanced control strategies of the air conditioning system. The results show that the joint action of energy efficiency strategies, integration of solar energy and energy flexibility improves the environmental sustainability of the district and the balance of energy flows. Specifically, the activation of energy flexibility contributes to a 10% reduction in operational CO2eq emissions and increases in self-consumption of energy per year. The operational emissions of the district vary from the base value of 33.37 tons CO2eq/y to 19.52 tons CO2eq/y in the scenario based on the integration of solar energy systems and energy efficiency measures, and to 17.39 tons CO2eq/y when also the demand-side energy flexibility is activated.
]]>Solar doi: 10.3390/solar3020015
Authors: Donatella Spadaro Jessica Barichello Ilaria Citro Giuseppe Calogero
The use of traditional Dye-sensitized solar cells (DSSCs) is limited due to the use of toxic and non-environmentally safe solvents. In this review, water is proposed as a viable alternative to developing green chemistry and sustainable materials for DSSCs. However, water-based DSSCs (WBDSSCs) require improvement in their photovoltaic parameters. The detachment of dye molecules from the semiconductor and the poor solubility of iodine in water are the primary reasons for their low efficiency. This review analyzes the best results achieved by 100% aqueous electrolytes containing synthetic, organic, and natural dyes to identify the best conditions to overcome these limitations. Developing a suitable photoanode/electrolyte interface and finding a compromise in the choice of dye are the main research goals in the coming years. WBDSSCs can contribute significantly to producing clean energy using sustainable and environmentally friendly materials. Furthermore, here we report the state of the art of the emerging technology of underwater dye-sensitized solar cells, which are a promising technology for generating renewable energy in aquatic environments. Recent advancements in material science and device engineering have shown promising results in enhancing their efficiency and durability. Further research and development can make these devices a viable alternative for sustainable energy generation in a wide range of underwater applications.
]]>Solar doi: 10.3390/solar3020014
Authors: Peter Scholz Dieter Weise Linda Schmidt Martin Dembski Alexander Stahr Martin Dix Florin Duminica Sebastien Le Craz Jiri Koziorek
This paper provides an overview of the development of a 3D formed and metal-based facade element that combines a custom design and solar thermal functionality. To achieve this, a novel simplified solar thermal collector structure was developed using formed sheet metal half-shells with an integrated channel structure on the inside and a special absorber coating on the outside. The sheet metal half-shells were manufactured by highly innovative incremental sheet forming (ISF), which allows seamless integration into existing facades. As a part of this paper, the initial test results on thermal efficiency and the energy accumulation of the new collector type are presented.
]]>Solar doi: 10.3390/solar3020013
Authors: Sahand Hosouli João Gomes Muhammad Talha Jahangir George Pius
Concentrating Photovoltaic Thermal (CPVT) collectors are suitable for integration in limited roof space due to their higher solar conversion efficiency. Solar sunlight can be used more effectively by CPVT collectors in comparison to individual solar thermal collectors or PV modules. In this study, the experimental investigation of a novel CPVT collector called a PC (power collector) has been carried out in real outdoor conditions, and the test set-up has been designed based on ISO 9806:2013. A quasi-dynamic testing method has been used because of the advantages that this method can offer for collectors with a unique construction, such as the proposed collector, over the steady-state testing method. With a quasi-dynamic testing method, it is possible to characterize the collector within a wide range of incidence angles and a complex incidence angle modifier profile. The proposed novel collector has a gross area of 2.57 m2. A maximum power output per collector unit area of 1140 W is found at 0 °C reduced temperature (1000 W/m2 irradiance level), while at a higher reduced temperature (70 °C), it drops down to 510 W for the same irradiance level. The data have been fitted through a multiple linear regression method, and the obtained efficiency curve coefficients are 0.39, 0.192, 1.294, 0.023, 0.2, 0, −5929 and 0 for Kθd, b0, c1, c2, c3, c4, c5 and c6, respectively. The experimental characterization carried out on the collector proved that the output powers calculated by using the obtained parameters of the quasi-dynamic testing method are in good agreement with experimental points.
]]>Solar doi: 10.3390/solar3020012
Authors: Timon Vaas Bart Pieters Andreas Gerber Uwe Rau
Reverse breakdown in Cu(In,Ga)Se2 (CIGS) solar cells can lead to defect creation and performance degradation. We present pulsed reverse-bias experiments, where we stress CIGS solar cells with a short reverse voltage pulse of ten milliseconds and detect the electrical and thermal response of the cell. This way, we limit the duration of the reverse stress, allowing us to study the initial stages of reverse-bias defect creation in CIGS solar cells and modules. Our results show that permanent damage can develop very fast in under milliseconds. Furthermore, we find the location of defect creation as well as the susceptibility to defect creation under reverse bias depends strongly on whether the cell is encapsulated or not, where encapsulated cells are generally more robust against reverse bias.
]]>Solar doi: 10.3390/solar3010011
Authors: Johann Bouclé Daniel Ribeiro Dos Santos Anne Julien-Vergonjanne
On one side, the capacity of the world’s photovoltaic (PV) systems is experiencing unprecedented growth; on the other side, the number of connected devices is rapidly increasing due to the development of advanced communication technologies. These fields are not completely independent, and recent studies show that indoor energy harvesting is a great candidate for answering the energy challenges of future generations of telecommunications, namely 5G and 6G, ideal for internet-of-things (IoT) scenarios, i.e., smart homes, smart cities, and smart factories. The emerging PV technologies have shown amazing capabilities for indoor energy harvesting, displaying high power conversion efficiency, good flexibility, and champion-specific powers. Recently, the excellent dynamic performance of PV devices enabled them to be used as data receivers in optical wireless communication (OWC) scenarios, calling forth an innovative system able to simultaneously harvest energy and receive communication data with a single PV device. This article reviews the recent literature devoted to the exploitation of photovoltaic technologies for simultaneous indoor energy harvesting and OWC data reception. This contribution highlights the strong potential of the approach toward the next generation of Green IoT systems and the current challenges that need to be addressed with regard to the physics of solar cells, from laboratory to large-scale applications.
]]>Solar doi: 10.3390/solar3010010
Authors: Darsha Jayathunga Jinendrika Anushi Weliwita Hirushie Karunathilake Sanjeeva Witharana
Concentrating solar power (CSP) is a high-potential renewable energy source that can leverage various thermal applications. CSP plant development has therefore become a global trend. However, the designing of a CSP plant for a given solar resource condition and financial situation is still a work in progress. This study aims to develop a mathematical model to analyze the levelized cost of electricity (LCOE) of Thermal Energy Storage (TES)-integrated CSP plants in such circumstances. The developed model presents an LCOE variation for 18 different CSP configurations with TES incorporated for Rankine, Brayton, and combined power generation cycles, under regular TES materials and nano-enhanced TES materials. The model then recommends the most economical CSP plant arrangement. Within the scope of this study, it was found that the best configuration for electricity generation is a solar power tower with nano-enhanced phase change materials as the latent heat thermal energy storage medium that runs on the combined cycle. This returns an LCOE of 7.63 ct/kWh with a 22.70% CSP plant efficiency. The most favorable option in 50 MW plants is the combined cycle with a regular TES medium, which has an LCOE of 7.72 ct/kWh with a 22.14% CSP plant efficiency.
]]>Solar doi: 10.3390/solar3010009
Authors: Claudia Diletto Antonio D’Angelo Salvatore Esposito Antonio Guglielmo Daniele Mirabile Gattia Michela Lanchi
In parabolic trough technology, the development of thermally and structurally stable solar coatings plays a key role in determining the efficiency, durability, and economic feasibility of tube receivers. A cermet-based solar coating is typically constituted by a thin film stratification, where a multilayer graded cermet is placed between an infrared metallic reflector and an antireflection filter. This work reports the realization of materials based on Al2O3 and W characterized by high structural and chemical stability in vacuum at high temperature, obtained through the optimization of high-deposition-rate processes. Al2O3 material, employed as the antireflection layer, was deposited through a reactive magnetron sputtering process at a high deposition rate. Cermet materials based on W-Al2O3 were deposited and employed as absorber layers by implementing reactive magnetron co-sputtering processes. An investigation into the stability of the realized samples was carried out by means of several material characterization methods before and after the annealing process in vacuum (1 × 10−3 Pa) at high temperature (620 °C). The structural properties of the samples were evaluated using Raman spectroscopy and XRD measurements, revealing a negligible presence of oxides that can compromise the structural stability. Spectrophotometric analysis showed little variations between the deposited and annealed samples, clearly indicating the high structural stability.
]]>Solar doi: 10.3390/solar3010008
Authors: Areti Zindrou Loukas Belles Yiannis Deligiannakis
Cu-oxide nanophases (CuO, Cu2O, Cu0) constitute highly potent nanoplatforms for the development of efficient Artificial Photosynthesis catalysts. The highly reducing conduction band edge of the d-electrons in Cu2O dictates its efficiency towards CO2 reduction under sunlight excitation. In the present review, we discuss aspects interlinking the stability under photocorrosion of the (CuO/Cu2O/Cu0) nanophase equilibria, and performance in H2-production/CO2-reduction. Converging literature evidence shows that, because of photocorrosion, single-phase Cu-oxides would not be favorable to be used as a standalone cathodic catalyst/electrode; however, their heterojunctions and the coupling with proper partner materials is an encouraging approach. Distinction between the role of various factors is required to protect the material from photocorrosion, e.g., use of hole scavengers/electron acceptors, band-gap engineering, nano-facet engineering, and selectivity of CO2-reduction pathways, to name a few possible solutions. In this context, herein we discuss examples and synthesis efforts that aim to clarify the role of interfaces, faces, and phase stability under photocatalytic conditions.
]]>Solar doi: 10.3390/solar3010007
Authors: Noelia Estremera-Pedriza Jesús Fernández-Reche Jose A. Carballo
The materials used to manufacture solar receivers for tower power plants must withstand high fluxes of concentrated solar radiation (from 0.1 to even 1.5 MWm−2) and operate at high operating temperatures (>800 °C). Durability is a key aspect in these systems, which must be ensured under these demanding operating conditions, which also include daily heating–cooling cycles throughout the lifetime of these power plants. So far, to the authors’ knowledge, which wavelengths of concentrated solar radiation have the greatest influence on the mechanisms and speed of aging of materials used in solar receivers has not been analyzed. Yet, such an analysis is pertinent in order to implement strategies that delay or inhibit such phenomena, and, thus, increase the durability of central tower systems’ receivers. To perform such analyses, a new solar furnace was recently designed and installed at the Plataforma de Almería (Spain). This paper describes the components of this new solar furnace. The components are as follows: a heliostat to redirect the direct solar radiation towards a Fresnel lens that concentrates the solar radiation on the material under study, a shutter that allows varying the amount of concentrated solar radiation incident on the Fresnel lens, and reflective filters with selective reflectance that are placed between the Fresnel lens and the material. This paper also describes the procedure and the first results of the energetic and spectral characterization of this new solar furnace. The first experimental results of the characterization of this new test bed using the heliostat and the Fresnel lens showed that concentration ratios of up to 1000 suns (1 sun = 1000 Wm−2) could be achieved. Furthermore, the paper presents the results of the spectral characterization of the test system, using selective reflectance mirrors in the near-visible–IR wavelength range (400–1125 nm) and in the visible–IR red region (700–2500 nm).
]]>Solar doi: 10.3390/solar3010006
Authors: Solar Editorial Office Solar Editorial Office
High-quality academic publishing is built on rigorous peer review [...]
]]>Solar doi: 10.3390/solar3010005
Authors: Alex Omar Topa Gavilema Juan D. Gil José Domingo Álvarez Hervás José Luis Torres Moreno Manuel Pérez García
This work presents the modeling and energy management of a microgrid through models developed based on physical equations for its optimal control. The microgrid’s energy management system was built with one of the most popular control algorithms in microgrid energy management systems: model predictive control. This control strategy aims to satisfy the load demand of an office located in the CIESOL bioclimatic building, which was placed in the University of Almería, using a quadratic cost function. The simulation scenarios took into account real simulation parameters provided by the microgrid of the building. For case studies of one and five days, the optimization was aimed at minimizing the input energy flows of the microgrid and the difference between the energy generated and demanded by the load, subject to a series of physical constraints for both outputs and inputs. The results of this work show how, with the correct tuning of the control strategy, the energy demand of the building is covered through the optimal management of the available energy sources, reducing the energy consumption of the public grid, regarding a wrong tuning of the controller, by 1 kWh per day for the first scenario and 7 kWh for the last.
]]>Solar doi: 10.3390/solar3010004
Authors: Alexander V. Klokov Egor Y. Loktionov
Renewable energy systems design using average year weather data is a standard approach that works well for grid-tied systems, but for stand-alone ones, it leads to dramatic mistakes. We considered the effect of meteorological data temporal resolution (5, 10, 15, 20, 30 min; 1, 2, 3, 4 h) on a stand-alone hybrid system’s layout in terms of equipment cost, power supply reliability and maximum duration of interruption for monitoring equipment in the Alps. We have shown that lifecycle costs could be strongly (order of magnitude) underestimated for off-grid systems, as well as their reliability overestimated. Lower temporal resolution data lead to the underestimation of energy storage charge–discharge cycles (considering depth of discharge too)—real batteries are to be replaced more often, which matches our practical experience as well. Even a 5 to 10 min decrease in weather data temporal resolution leads to the estimated annual expenses being halved. In general, we recommend using 30 min resolution.
]]>Solar doi: 10.3390/solar3010003
Authors: Marius C. Möller Stefan Krauter
This paper presents a model of an energy system for a private household extended by a lifetime prognosis. The energy system was designed for fully covering the year-round energy demand of a private household on the basis of electricity generated by a photovoltaic (PV) system, using a hybrid energy storage system consisting of a hydrogen unit and a lithium-ion battery. Hydrogen is produced with a Proton Exchange Membrane (PEM) electrolyser by PV surplus during the summer months and then stored in a hydrogen tank. Mainly during winter, in terms of lack of PV energy, the hydrogen is converted back into electricity and heat by a fuel cell. The model was created in Matlab/Simulink and is based on real input data. Heat demand was also taken into account and is covered by a heat pump. The simulation period is a full year to account for the seasonality of energy production and demand. Due to high initial costs, the longevity of such an energy system is of vital interest. Therefore, this model was extended by a lifetime prediction in order to optimize the dimensioning with the aim of lifetime extension of a hydrogen-based energy system. Lifetime influencing factors were identified on the basis of a literature review and were integrated in the model. An extensive parameter study was performed to evaluate different dimensionings regarding the energy balance and the lifetime of the three components, electrolyser, fuel cell and lithium-ion battery. The results demonstrate the benefits of a holistic modelling approach and enable a design optimization regarding the use of resources, lifetime and self-sufficiency of the system.
]]>Solar doi: 10.3390/solar3010002
Authors: John G. Swadener
TiO2 photocatalysts can provide carbon-capture utilization and storage by converting atmospheric CO2 to green hydrogen, but the efficiency of the current photocatalysts is still too low for economical usage. Anatase TiO2 is effective in transferring the electrons and holes produced by the photoelectric effect to reactants because of its oxygen-terminated surfaces. However, the anatase TiO2 bandgap is 3.2 eV, which requires photons with wavelengths of 375 nm or less to produce electron–hole pairs. Therefore, TiO2 is limited to using a small part of the solar spectrum. Strain engineering has been used to design ZrO2@TiO2 core@shell structures with large strains in the TiO2 shell, which reduces its bandgap but maintains octahedral facets for charge separation and oxygen-terminated surfaces for the catalysis of reactants. Finite element analysis shows that shell thicknesses of 4–12 nm are effective at obtaining large strains in a large portion of the shell, with the largest strains occurring next to the ZrO2 surface. The c-axis strains for 4–12 nm shells are up to 7%. The strains reduce the bandgap in anatase TiO2 up to 0.35 eV, which allows for the use of sunlight with wavelengths up to 421 nm. For the AM 1.5 standard spectrum, electron–hole pair creation in 4 nm thick and 10 nm thick TiO2 shells can be increased by a predicted 25% and 23%, respectively. The 10 nm thick shells provide a much larger volume of TiO2 and use proportionally less ZrO2. In addition, surface-plasmon resonators could be added to further extend the usable spectrum and increase the production of electron–hole pairs many-fold.
]]>Solar doi: 10.3390/solar3010001
Authors: Radovan Kopecek Florian Buchholz Valentin D. Mihailetchi Joris Libal Jan Lossen Ning Chen Haifeng Chu Christoph Peter Tudor Timofte Andreas Halm Yonggang Guo Xiaoyong Qu Xiang Wu Jiaqing Gao Peng Dong
We present our own Interdigitated Back Contact (IBC) technology, which was developed at ISC Konstanz and implemented in mass production with and at SPIC Solar in Xining, China, with production efficiencies of over 24%. To our knowledge, this is the highest efficiency achieved in the mass production of crystalline silicon solar cells without the use of charge-carrier-selective contacts. With an adapted screen-printing sequence, it is possible to achieve open-circuit voltages of over 700 mV. Advanced module technology has been developed for the IBC interconnection, which is ultimately simpler than for conventional double-sided contacted solar cells. In the next step, we will realize low-cost charge-carrier-selective contacts for both polarities in a simple sequence using processes developed and patented at ISC Konstanz. With the industrialisation of this process, it will be possible to achieve efficiencies well above 25% at low cost. We will show that with the replacement of silver screen-printed contacts by copper or aluminium metallisation, future IBC technology will be the end product for the PV market, as it is the best performing c-Si technology, leading to the lowest cost of electricity, even in utility-scale applications.
]]>Solar doi: 10.3390/solar2040033
Authors: Carlos Pinzón Nahuel Martínez Guillermo Casas Fernando C. Alvira Nicole Denon Gastón Brusasco Hugo Medina Chanduví Arles V. Gil Rebaza Marcelo A. Cappelletti
Perovskite solar cells (PSCs) have substantially increased their power conversion efficiency (PCE) to more than 25% in recent years. However, the instability of these devices is still a strong obstacle for their commercial applications. Recently, all-inorganic PSCs based on CsPbI3 and CsPbI2Br as the perovskite layer have shown enhanced long-term stability, which makes them potential candidates for commercialization. Currently, all-inorganic PSCs with inverted p-i-n configuration have not yet reached the high efficiency achieved in the normal n-i-p structure. However, the inverted p-i-n architecture has recently drawn attention of researchers because it is more suitable to prepare tandem solar cells. In this work, a theoretical study of inverted p-i-n all-inorganic PSCs based on CsPbI3 and CsPbI2Br as the perovskite layer was carried out using SCAPS-1D software (ver. 3.3.09). The performance of different architectures of PSC was examined and compared by means of numerical simulations using various inorganic materials as the hole transport layer (HTL) and the electron transport layer (ETL). The results reveal that CuI and ZnO are the most suitable as HTL and ETL, respectively. In addition, the performance of the devices was significantly improved by optimizing the hole mobility in CuI as well as the thickness, doping density, and defect density in the absorber layer. Maximum efficiencies of 26.5% and 20.6% were obtained under optimized conditions for the inverted all-inorganic CsPbI3- and CsPbI2Br-based PSCs, respectively. These results indicate that further improvements in the performance of such devices are still possible.
]]>Solar doi: 10.3390/solar2040032
Authors: Mohammad Nur-E-Alam Mohammad Khairul Basher Iftekharuzzaman Kazi Zehad Mostofa Mohammad Aminul Islam A. H. M. Ahashanul Haque Narottam Das
The electricity crisis is a common issue in Bangladesh; however, recently the electricity scenario has been getting worse due to various reasons including power generation and distribution all over the country. Meanwhile, the large number of people requires a huge amount of energy which is not possible to be met by the national grid due to the limited power generation from different plants. Among all renewable energy sources, the solar photovoltaics (PV) system is the best choice as a generation source, either off-grid or with a grid-tied connection, to reduce the pressure on the national grid. In Bangladesh, there are more than 175,000 schools, and it is possible to generate a huge amount of renewable (solar) power to supply all the schools by using rooftop PV systems. We propose a new approach that combines solar energy harvesting and savings to make the schools self-sufficient and energywise. We performed a Hybrid Optimization Model for Multiple Energy Resources (HOMER) pro simulation and find that it was possible to generate approximately 200 megawatts (MW) of power. We conducted a feasibility study on generating power from rooftop PV systems on school buildings and reduced the power consumption using retrofitted thin-film-coated glass by around 16–20% per day depending on the school size, which can help the national power grid system by either making all the schools off-grid or grid-connected to supply power to the national grid. In addition, we perform a HelioScope simulation to investigate the maximum upscaling of PV sizing for the rooftops of school buildings in Bangladesh to realize how to make each school a mini solar power station in the future. The HelioScope simulation performance showed that it was possible to generate approximately 96,993 kWh per year from one school building.
]]>Solar doi: 10.3390/solar2040031
Authors: María Fernanda Cerdá
DSSC technology based on natural dyes still constitutes a tempting alternative to explore. Besides the ease of extraction, most natural dyes fulfill the characteristics to be applied as sensitizers. The presented results summarize the exploration of the features of several southern dyes, mostly coming from the Antarctic region. The explored pigments showed good absorption capacity within the visible region of the light spectra, and their molecules possess functional moieties to coordinate with the TiO2 semiconductor, oxidation potential value near 1 V and reduction potential near −0.8 V, adequate thermal stability, and low fluorescence emission.
]]>Solar doi: 10.3390/solar2040030
Authors: Rolf Klein
Equivalent circuit models of solar cells are important for understanding the behavior of photovoltaic systems under different weather conditions. They provide an equation F(V,I)=0 that expresses the correspondence between voltage V and current I a cell can deliver. The performance of a cell, and, therefore, the parameters of equation F, depend on the cell’s temperature and on the incoming light’s energy and angle. One would like to simulate and visualize these dependencies in real time. Given a fixed set of parameters, no elementary solution s(V)=I of Equation F(V,I)=0 is known. Hence, circuit simulation systems employ numerical methods to solve this equation and to approximate the circuit’s I–V curve, CIV. In this note, we propose a simpler approach. Instead of expressing I as a function of V, we represent both as elementary functions V(u) and I(u) of a real parameter u. In this way, the I–V curve CIV is obtained as the image of the mapping m(u)=(V(u),I(u)) from a u-interval to the VI-plane. Our approach offers both a precise mathematical description of CIV and an easy way to draw it. This allows us to study the influence of environmental changes on CIV by smooth animations, and yet with rather simple means. In this paper, we consider temperature dependence as an example; changes in irradiance or angle could be incorporated as well. Using formulae suggested in the literature that describe how the parameters in equation F(V,I)=0 depend on temperature, it takes only a few lines of code to generate an interactive worksheet that shows how CIV, the location of the maximum power point MPP and the maximum power change as the circuit’s temperature, is altered on a slider. Such a worksheet and its location will be presented in this paper.
]]>Solar doi: 10.3390/solar2040029
Authors: Lisete Fernandes José R. Fernandes Pedro B. Tavares
Solar drying is one of the many ways of efficiently making use of solar energy to meet the human demand for improved sustainability. In this study, we describe the construction and testing of two indirect solar dryer prototypes, especially designed for vegetables and fruits. The dryers had two compartments: a solar panel and a drying chamber. The dryers were mainly made of wood (Prototype 1) and styrofoam (Prototype 2) and both used recycled aluminum cans. The calculated yield of solar panels was 82% and 77% for Prototype 1 and 2, respectively. The drying tests performed with different fresh products showed that it was possible to dry all of them until less than 10% of their initial weight, at different times, depending on the type of product. As regards the apple slices, the solar dryers were able to remove 95.7% and 95.0% of initial moisture on a wet basis for Prototype 1 and 2, respectively. Comparative tests were conducted with an electric commercial dryer using the same product to explore the drying dynamics and costs. The cost of the final dry product, excluding the purchase of fresh goods, was 6.83 €/kg for the electric dryer, 1.78 €/kg for Prototype 1 and 1.72 €/kg for Prototype 2. Dehydrated apple slices are currently available on the market for around 34.50 €/kg. Our solar dryers can dry quality products at a very low cost for their entire life span, which allows them to compete with electric systems to prevent food waste in a cheaper and environmentally friendly way.
]]>Solar doi: 10.3390/solar2040028
Authors: Youngil Kim Allie Skaggs James Ferrell
The United States is experiencing a large growth in the solar sector. The U.S. solar power capacity has grown from 0.34 Gigawatts (GW) in 2008 to an estimated 97.2 GW today. However, some states have had difficulty installing large scale solar farms due to concerns regarding geographic location, political climate, or economic factors. Kentucky (KY) is one of the states which is below the national average for solar energy production. However, KY contains a wealth of potential for these types of farms with decent solar irradiation levels and large tracts of unused land for solar farms. For the study, this paper selects three representative areas of KY by using PVWatts and topographical maps which can theoretically produce enough electricity so that KY can meet or exceed the national generation percentage average (2.3% or 2.06 TWh annually in KY’s case). The study analyzes the economic feasibility of solar photovoltaic systems (PV) farms in terms of Cumulative Cash Flow ($) and Payback Time (Year) by using the Cost of Renewable Energy Spreadsheet Tool (CREST). Furthermore, this paper estimates the Average/Median/High output power (kWh) annually for the scenario among three areas in Kentucky, Smithland, Hickman, and Falls of Rough. In this theoretical scenario, an average 2.27 TWh would be generated annually which exceeds the national generation percentage average. Furthermore, by the sixth year, the cumulative cash flow would exceed the breakeven point, proving the feasibility of these solar farms. The annual average power generation estimates for the areas of Smithland, Hickman, and Falls of Rough are 0.3741 TWh, 1.1628 TWh, and 0.731 TWh respectively. The average profit per MWh estimates for the areas of Smithland, Hickman, and Falls of Rough are $11,130.12/MWh, $10,742.46/MWh, and $11,392.01/MWh respectively. According to CREST, the final cumulative cash flow, after the 25-year life span of the panels, would be approximately $624,566,720.
]]>Solar doi: 10.3390/solar2040027
Authors: Shab Gbémou Julien Eynard Stéphane Thil Stéphane Grieu
With the development of predictive management strategies for power distribution grids, reliable information on the expected photovoltaic power generation, which can be derived from forecasts of global horizontal irradiance (GHI), is needed. In recent years, machine learning techniques for GHI forecasting have proved to be superior to classical approaches. This work addresses the topic of multi-horizon forecasting of GHI using Gaussian process regression (GPR) and proposes an in-depth study on some open questions: should time or past GHI observations be chosen as input? What are the appropriate kernels in each case? Should the model be multi-horizon or horizon-specific? A comparison between time-based GPR models and observation-based GPR models is first made, along with a discussion on the best kernel to be chosen; a comparison between horizon-specific GPR models and multi-horizon GPR models is then conducted. The forecasting results obtained are also compared to those of the scaled persistence model. Four performance criteria and five forecast horizons (10 min, 1 h, 3 h, 5 h, and 24 h) are considered to thoroughly assess the forecasting results. It is observed that, when seeking multi-horizon models, using a quasiperiodic kernel and time as input is favored, while the best horizon-specific model uses an automatic relevance determination rational quadratic kernel and past GHI observations as input. Ultimately, the choice depends on the complexity and computational constraints of the application at hand.
]]>Solar doi: 10.3390/solar2040026
Authors: Philippe Lauret Rodrigo Alonso-Suárez Josselin Le Gal La Salle Mathieu David
In the realm of solar forecasting, it is common to use a clear sky model output to deseasonalise the solar irradiance time series needed to build the forecasting models. However, most of these clear sky models require the setting of atmospheric parameters for which accurate values may not be available for the site under study. This can hamper the accuracy of the prediction models. Normalisation of the irradiance data with a clear sky model leads to the construction of forecasting models with the so-called clear sky index. Another way to normalize the irradiance data is to rely on the extraterrestrial irradiance, which is the irradiance at the top of the atmosphere. Extraterrestrial irradiance is defined by a simple equation that is related to the geometric course of the sun. Normalisation with the extraterrestrial irradiance leads to the building of models with the clearness index. In the solar forecasting domain, most models are built using time series based on the clear sky index. However, there is no empirical evidence thus far that the clear sky index approach outperforms the clearness index approach. Therefore the goal of this preliminary study is to evaluate and compare the two approaches. The numerical experimental setup for evaluating the two approaches is based on three forecasting methods, namely, a simple persistence model, a linear AutoRegressive (AR) model, and a non-linear neural network (NN) model, all of which are applied at six sites with different sky conditions. It is shown that normalization of the solar irradiance with the help of a clear sky model produces better forecasts irrespective of the type of model used. However, it is demonstrated that a nonlinear forecasting technique such as a neural network built with clearness time series can beat simple linear models constructed with the clear sky index.
]]>Solar doi: 10.3390/solar2040025
Authors: S. A. Abdullahi R. Akoba J. Sackey S. Khamlich S. Halindintwali Z. Y. Nuru M. Maaza
In this work, we study the thermal stability of a hydrothermally treated stainless steel (SS) selective solar absorber by annealing in air in a temperature range between 300 °C and 700 °C for a soaking time of 2 h. Thermal stability testing in the presence of air is critical if the vacuum is breached. Therefore, the SS was characterized by X-ray diffraction (XRD), mechanical, and optical techniques. The XRD analysis shows that the grain size of the as-treated absorber is 67 nm, whereas those of the annealed absorbers were found to be in the range between 66 and 38 nm. The phase of the as-treated and annealed SS was further identified by XRD as Fe2O3. The EDS result shows that the elemental components of the SS were C, Cr, Fe, and O. The strain (ε) and stress (σ) calculated for the as-treated absorber are 1.2 × 10−1 and −2.9 GPa, whereas the annealed absorbers are found in the range of 4.4 × 10−1 to 5.2 × 10−1 and −121.6 to −103.2 GPa, respectively, at 300–700 °C. The as-treated SS absorbers exhibit a good spectra selectivity of 0.938/0.431 = 2.176, which compares with 0.941/0.403 = 2.335 after being annealed at 300 °C and 0.884/0.179 = 4.939 after being annealed at 700 °C. These results indicate a small improvement in absorptivity (0.941) and emissivity (0.403) after annealing at 300 °C, followed by a significant decrease after annealing at 700 °C. The obtained analysis confirms that the annealed SS absorber exhibits excellent selectivity and is suitable to withstand any thermal condition (≤700 °C) in air. Thus, using a cost-effective approach as demonstrated in this study, the as-treated and annealed SS absorber could be used for photo-thermal conversion applications.
]]>Solar doi: 10.3390/solar2040024
Authors: Jesús Fernández-Reche Loreto Valenzuela Diego Pulido-Iparraguirre
Linear Fresnel solar collectors are a promising and emerging solution to contribute to renewable heat supply in industrial processes with thermal energy demand in the medium temperature range (<250 °C). An innovative linear Fresnel collector (LFC) prototype has been designed, patented, and built at the Plataforma Solar de Almería (PSA), Spain. This work presents the applied methodology, experimental device, and results obtained in the measurement of the flux density of concentrated solar radiation in the focal plane of the solar collector. The experimental results confirm that an average flux density of (9.8 ± 0.6) kW/m2 was obtained with a direct normal solar irradiance of (870 ± 10) W/m2 in tests performed in May 2002, which is a result similar to that obtained in optical simulations of the system.
]]>Solar doi: 10.3390/solar2040023
Authors: Kakaraparthi Kranthiraja Sujan Aryal Mahdi Temsal Mohin Sharma Anupama B. Kaul
Three dimensional (3D) perovskite solar cells (PSCs) are a promising candidate for third-generation photovoltaics (PV) technology, which aims to produce efficient photon conversion devices to electricity using low-cost fabrication processes. Hybrid organic-inorganic perovskites for-lmed using low-cost solution processing are explored here, which have experienced a stupendous rise in power conversion efficiency (PCE) over the past decade and serve as a prime candidate for third-generation PV systems. While significant progress has been made, the inherent hygroscopic nature and stability issue of the 3D perovskites (3DPs) are an impediment to its commercialization. In this work, we have studied two-dimensional (2D) organometallic halide (CH3(CH2)3NH3)2(CH3NH3)n−1PbnI3n+1) layered perovskites in the Ruddlesden Popper structure, represented as BA2MA3Pb4I13 for the n = 4 formulation, for both photoabsorbers in a two-terminal architecture and solar cells, given that these material are considered to be inherently more stable. In the two-terminal photo absorber devices, the photocurrent and responsivity were measured as a function of incoming laser wavelength, where the location of the peak current was correlated to the emission spectrum arising from the 2DP film using photoluminescence (PL) spectroscopy. The 2D (BA)2(MA)3Pb4I13 films were then integrated into an n-i-p solar cell architecture, and PV device figures of merit tabulated, while our 3D MAPbI3 served as the reference absorber material. A comparative study of the 3DP and 2DP film stability was also conducted, where freshly synthesized films were inspected on FTO substrates and compared to those exposed to elevated humidity levels, and material stability was gauged using various material characterization probes, such as PL and UV-Vis optical absorption spectroscopy, scanning electron microscopy and X-ray diffraction. While the PCE of the 3D-PSCs was higher than the 2D-PSCs, our results confirm the enhanced environmental stability of the 2DP absorber films compared to the 3DP absorbers, suggesting their promise to address the stability issue broadly encountered in 3D PSCs toward third-generation PV technology.
]]>Solar doi: 10.3390/solar2030022
Authors: Hajar Ftouhi Hind Lamkaouane Mustapha Diani Guy Louarn Ludovic Arzel Jean-Christian Bernède Mohammed Addou Linda Cattin
Ternary planar heterojunction organic solar cells (PHJ-OPVs) were fabricated using three organic small molecules, alpha-sexithiophene (α-6T), aluminum phthalocyanine chloride (AlPcCl) and fullerene (C60). These molecules can be easily sublimated under a vacuum; they have complementary optical absorption spectra and their energy band structure alignment is favorable for electronic charge transfers. Moreover, α-6T and AlPcCl have almost the same HOMO, which is desirable to avoid any decrease in open circuit voltage. The AlPcCl intercalated layer bridges the energy levels of the electron donor, α-6T, and the electron acceptor, C60, which facilitates charge transport through the energy cascade effect. Moreover, the charge carrier mobility measurements of AlPcCl, using the space charge limited current method, demonstrated that it iss ambipolar. All these properties combine to improve the power conversion efficiency (PCE) of PHJ-OPVs by moving from binary structures (α-6T/C60, α-6T/AlPcCl and AlPcCl/C60) to ternary ones (α-6T/AlPcCl/C60). We show, in this study, that both interfaces of the ternary PHJ-OPVs are efficient for carrier separation. After optimization of the different layer thickness, we show that, by comparing the optimum efficiencies of the binary PHJ-OPVs, the realization of ternary PHJ-OPVs, based on the active layers α-6T/AlPcCl/C60, using the following optimized method, allows us to achieve a PCE of 4.33%.
]]>Solar doi: 10.3390/solar2030021
Authors: Brighton Mabasa Meena D. Lysko Sabata J. Moloi
The study compares the performance of satellite-based datasets and the Ångström–Prescott (AP) model in estimating the daily global horizontal irradiance (GHI) for stations in South Africa. The daily GHI from four satellites (namely SOLCAST, CAMS, NASA SSE, and CMSAF SARAH) and the Ångström–Prescott (AP) model are evaluated by validating them against ground observation data from eight radiometric stations located in all six macro-climatological regions of South Africa, for the period 2014-19. The evaluation is carried out under clear-sky, all-sky, and overcast-sky conditions. CLAAS-2 cloud fractional coverage data are used to determine clear and overcast sky days. The observed GHI data are first quality controlled using the Baseline Surface Radiation Network methodology and then quality control of the HelioClim model. The traditional statistical benchmarks, namely the relative mean bias error (rMBE), relative root mean square error (rRMSE), relative mean absolute error (rMAE), and the coefficient of determination (R2) provided information about the performance of the datasets. Under clear skies, the estimated datasets showed excellent performance with maximum rMBE, rMAE, and rRMSE less than 6.5% and a minimum R2 of 0.97. In contrast, under overcast-sky conditions there was noticeably poor performance with maximum rMBE (24%), rMAE (29%), rRMSE (39%), and minimum R2 (0.74). For all-sky conditions, good correlation was found for SOLCAST (0.948), CMSAF (0.948), CAMS (0.944), and AP model (0.91); all with R2 over 0.91. The maximum rRMSE for SOLCAST (10%), CAMS (12%), CMSAF (12%), and AP model (11%) was less than 13%. The maximum rMAE for SOLCAST (7%), CAMS (8%), CMSAF (8%), and AP model (9%) was less than 10%, showing good performance. While the R2 correlations for the NASA SSE satellite-based GHI were less than 0.9 (0.896), the maximum rRMSE was 18% and the maximum rMAE was 15%, showing rather poor performance. The performance of the SOLCAST, CAMS, CMSAF, and AP models was almost the same in the study area. CAMS, CMSAF, and AP models are viable, freely available datasets for estimating the daily GHI at South African locations with quantitative certainty. The relatively poor performance of the NASA SSE datasets in the study area could be attributed to their low spatial resolution of 0.5° × 0.5° (~55 km × 55 km). The feasibility of the datasets decreased significantly as the proportion of sky that was covered by clouds increased. The results of the study could provide a basis/data for further research to correct biases between in situ observations and the estimated GHI datasets using machine learning algorithms.
]]>Solar doi: 10.3390/solar2030020
Authors: Naureen Sadanand Pooja Lohia Dilip Dwivedi Sadia Ameen
Quantum dot solar cells have received significant attention in comparison to standard solar cells because of their hybrid nature, low production costs, and higher power conversion efficiency. Although quantum dot solar cells (QDSCs) have several benefits over ordinary solar cells, their performance lags due to carrier combination within the quasi-neutral region (QNR). The electron transport layer (ETL) and hole transport layer (HTL) are the two layers that have the most effect on QDSC performance. This numerical analysis is carried out by using the Solar Cell Capacitance Simulator-1 dimensional software (SCAPS-1D). In this paper, the optimization of two different device structure investigations is performed. In this proposed device structure, WS2 and IGZO are used as two ETL, CdS is used as a buffer layer, Sb2Se3 is used as an absorber layer, and PbS as HTL. Initially, the optimization of the device has been performed, followed by depth analysis of the doping densities. Resistance analysis is also performed to illustrate the effect of resistance on the device. Further, the impact of temperature on the device parameters is also represented, followed by a contour plot between thickness and bandgap for both devices. The impact of the series and shunt resistance on the performance of the solar cell is investigated. The effect of temperature is studied further, and it is observed that the solar device is temperature-sensitive. Finally, the optimized performance with IGZO ETL with PCE of 20.94% is achieved.
]]>Solar doi: 10.3390/solar2030019
Authors: Jingwei Zhu Cong Chen Dewei Zhao
Low-bandgap mixed tin (Sn)–lead (Pb) perovskite solar cells have been extensively investigated in the past few years due to their great potential in high-performance perovskite/perovskite tandem solar cells. From this perspective, we briefly summarize the mechanism of understanding of additives and the advances in the efficiency and stability of such low-bandgap Sn-Pb perovskite materials and solar cells in terms of various effective strategies for suppressing the defects and oxidation of Sn2+, regulating crystallization growth, etc. We then provide a perspective regarding the achievement of high-quality, low-bandgap Sn-Pb perovskites and highly efficient solar cells.
]]>Solar doi: 10.3390/solar2020018
Authors: Filippo Spertino Gabriele Malgaroli Angela Amato Muhammad Qureshi Alessandro Ciocia Hafsa Siddiqi
For a photovoltaic (PV) generator, knowledge of the parameters describing its equivalent circuit is fundamental to deeply study and simulate its operation in any weather conditions. In the literature, many papers propose methods to determine these parameters starting from experiments. In the most common circuit, there are five of these parameters, and they generally refer to specific weather conditions. Moreover, the dependence on irradiance and temperature is not investigated for the entire set of parameters. In fact, a few papers present some equations describing the dependence of each parameter on weather conditions, but some of their coefficients are unknown. As a consequence, this information cannot be used to predict the PV energy in any individual weather condition. This work proposes an innovative technique to assess the generated energy by PV modules starting from the knowledge of their equivalent parameters. The model is applied to a highly efficient PV generator with all-back contact, monocrystalline silicon technology, and rated power of 370 W. The effectiveness of the model is investigated by comparing its energy prediction with the value estimated by the most common model in the literature to assess PV energy. Generated energy is predicted by assuming PV power to be constant for a time interval of 1 min.
]]>Solar doi: 10.3390/solar2020017
Authors: Thaleia Ioannidou Maria Anagnostopoulou Konstantinos Christoforidis
The depletion of fossil fuels and onset of global warming dictate the achievement of efficient technologies for clean and renewable energy sources. The conversion of solar energy into chemical energy plays a vital role both in energy production and environmental protection. A photocatalytic approach for H2 production and CO2 reduction has been identified as a promising alternative for clean energy production and CO2 conversion. In this process, the most critical parameter that controls efficiency is the development of a photocatalyst. Two-dimensional nanomaterials have gained considerable attention due to the unique properties that arise from their morphology. In this paper, examples on the development of different 2D structures as photocatalysts in H2 production and CO2 reduction are discussed and a perspective on the challenges and required improvements is given.
]]>Solar doi: 10.3390/solar2020016
Authors: Dimitrios Raptis Carys Worsley Simone Meroni Adam Pockett Matthew Carnie Trystan Watson
Fully printable carbon-based perovskite solar cells (C-PSCs) represent some of the most promising perovskite solar cell (PSC) architectures. Highly scalable, stable, and low in cost—these devices consist of a TiO2 compact layer (C-TiO2) and three sequentially screen-printed mesoporous layers of TiO2, ZrO2, and carbon, through which perovskite is infiltrated. While there has been remarkable progress in optimizing and scaling up deposition of mesoporous layers and perovskite, few publications have focused on optimizing C-TiO2. In this work, we investigate the potential for substituting commonly used spray pyrolysis with more easily scaled screen-printing. It was found that when comparing layers of similar thickness, 1 cm2 devices fabricated with printed C-TiO2 exhibited similar power conversion efficiency (PCE) to those fabricated with spray pyrolysis. In contrast, thicker-printed C-TiO2 led to lower efficiency. The influence of TiCl4 treatment on the quality of produced compact layers was also examined. This proved beneficial, mostly in the printed films, where a champion PCE of 13.11% was attained using screen-printed, TiCl4 treated C-TiO2. This work proves that screen-printing is a viable replacement for spray pyrolysis in C-PSCs fabrication.
]]>Solar doi: 10.3390/solar2020015
Authors: Renate Zapf-Gottwick Sven Seren Susana Fernandez-Robledo Evariste-Pasky Wete Matteo Schiliro Mohamed Hassan Valentin Mihailetchi Thomas Buck Radovan Kopecek Jürgen Köhler Jürgen Werner
We present laser-doped interdigitated back contact (IBC) solar cells with efficiencies of 23% on an area of 244 cm2 metallized by a screen-printed silver paste. Local laser doping is especially suited for processing IBC cells where a multitude of pn-junctions and base contacts lay side by side. The one-sided deposition of boron-doped precursor layers by atmospheric pressure chemical vapor deposition (APCVD) is a cost-effective method for the production of IBC cells without masking processes. The properties of the laser-doped silicon strongly depend on the precursor’s purity, thickness, and the total amount of boron dopants. Variations of the precursor in terms of thickness and boron content, and of the laser pulse energy density, can help to tailor the doping and sheet resistance. With saturation-current densities of 70 fA/cm2 at sheet resistances of 60 Ohm/sq, we reached maximum efficiencies of 23% with a relatively simple, industrial process for bifacial IBC-cells, with 70% bifaciality measured on the module level. The APCVD-layers were deposited with an inline lab-type system and a metal transport belt and, therefore, may have been slightly contaminated, limiting the efficiencies when compared to thermal-diffused boron doping. The use of an industrial APCVD system with a quartz glass transport system would achieve even higher efficiencies.
]]>Solar doi: 10.3390/solar2020014
Authors: Aristotle T. Ubando Ariel Conversion Renyl B. Barroca Nelson H. Enano Randell U. Espina
Concentrated solar power is an alternative renewable energy technology that converts solar energy into electrical energy by using a solar concentrator and a solar receiver. Computational fluid dynamics have been used to numerically design concentrated solar power. This is a powerful numerical analysis approach that is widely used in energy and environmental engineering applications. In this paper, we review previous work on the applications of computational fluid dynamics in the design of concentrated solar power technology. We performed a bibliometric analysis of journal articles relevant to applications to analyze the current trend of utilization of computational fluid dynamics in these technologies. Then, we conducted a comprehensive analysis focused on the design of solar dish technology using computational fluid dynamics. Furthermore, we reviewed in detail the optical modeling of solar concentrators and solar receivers. Of the 83 retrieved publications from Scopus database, 80 were journal articles, and only three were review papers. Among these 80 journal articles, only 54 were relevant to this study, and 23 were relevant to solar dish technology. The documents were analyzed according to their number of citations, journal sources, and keyword evolution and network map. The information presented in this paper is useful to further recognize the contributions of computational fluid dynamics to the development of concentrated solar power, particularly to solar dish technology. In addition, we also discuss the challenges and future research directions to make solar energy a more sustainable source of renewable energy.
]]>Solar doi: 10.3390/solar2020013
Authors: Adam Jensen Ioannis Sifnaios
In recent years, concentrating solar collectors have been integrated with several district heating systems with the aim of taking advantage of their low heat losses. The present study investigates the Brønderslev combined heat and power plant, which consists of a 16.6 MW parabolic trough collector field, two biomass boilers, and an organic Rankine cycle system. The study focuses on the solar collector field performance and integration with the district heating network. An in situ characterization of the parabolic solar collector field using the quasi-dynamic test method found that the field had a peak efficiency of 72.7%. Furthermore, a control strategy for supplying a constant outlet temperature to the district heating network was presented and implemented in a TRNSYS simulation model of the solar collector field. The developed simulation model was validated by comparison to measurement data. Subsequently, the simulation model was used to conduct a sensitivity analysis of the influence of the collector row spacing and tracking axis orientation. The results showed that the current suboptimal tracking axis rotation, made necessary by the geography of the location, only reduced the annual power output by 1% compared to the optimal configuration. Additionally, there were only minor improvements in the annual heat output when the row spacing was increased past 15 m (ground cover ratio of 0.38).
]]>Solar doi: 10.3390/solar2020012
Authors: Jürgen Werner
At present, the purchasing prices for silicon-based photovoltaic modules with 20% efficiency and more are between 20 and 40 EURct/Wp. These numbers correspond to 40 to 80 EUR/m2 and are in the same range as the mounting costs (material prices plus salaries) of such modules. Installers and operators of photovoltaic systems carefully balance the module and mounting costs when deciding among modules of different efficiencies. This contribution emulates the installer’s decision via a simple, analytical module mounting decision (Mo2De) model. A priori, the model, and the resulting conclusions are completely independent of the photovoltaically active material inside the modules. De facto, however, based on the present state (cost, efficiency, reliability, bankability, etc.) of modules fabricated from (single) crystalline Si cells, conclusions on other photovoltaic materials might also be drawn: On the one hand, the model suggests that lower-efficiency modules with efficiencies below 20% will be driven out of the market. Keeping in mind their installation costs, installers will ask for large discounts for lower-efficiency modules. Technologies based on organic semiconductors, CdTe, CIGS, and even multicrystalline Si, might not survive in the utility market, or in industrial and residential applications. Moreover, this 20% mark will soon reach 23%, and finally will stop at around 25% for the very best, large-area (square meter sized) commercial modules based on single crystalline silicon only. On the other hand, it also seems difficult for future higher-efficiency modules based on tandem/triple cells to compete with standard Si-based reference modules. Compared to their expected higher efficiency, the production costs of tandem/triple cell modules and, therefore, also their required markup in sales, might be too high. Depending on the mounting cost, the Mo2De-model predicts acceptable markup values of 1 EURct/Wp (for low mounting costs of around 10 EUR/m2) to 11 EURct/Wp (for high mounting costs of 100 EUR/m2) if the module efficiency increases from 23% to 30%. Therefore, a 23% to 24% module efficiency, which is possible with silicon cells alone, might be enough for many terrestrial photovoltaic applications.
]]>Solar doi: 10.3390/solar2020011
Authors: George Stamatellos Olympia Zogou Anastassios Stamatelos
Understanding the implications of introducing increasing shares of low-carbon technologies such as heat pumps and electric vehicles on the electricity network demand patterns is essential in today’s fast changing energy mixture. Application of heat pumps for heating and cooling, combined with the rooftop installation of photovoltaic panels, is already considered as a convenient retrofitting strategy towards building electrification. This may further profit from the parallel, rapid electrification of the automotive powertrain, as demonstrated in the present study. Exploitation of the combined battery storage of the house owners’ electric car(s) may help cover, to a significant degree, the building’s and cars’ electricity needs. To this end, an efficient single family house’s energy system with an optimized rooftop PV installation, heat pump heating and cooling, and two high efficiency electric cars is studied by transient simulation. The use of TRNSYS simulation environment makes clear the interaction of the house’s heating, ventilation, and air conditioning (HVAC) system, the house’s and cars’ batteries, and the rooftop PV system in transient operation. The building’s and EV’s energy performance on a daily, monthly, and seasonal level is compared with the respective demand curves and energy sources of the Greek electricity network. The specific design of the house’s energy system makes it a net exporter of electricity to the grid, to an annual amount of 5000 kWh. On the other hand, electricity imports are slightly exceeding 400 kWh and limited to the first two months of the year. In addition to the self-sufficiency of the household, the impact to the electricity grid becomes favorable due to the phase shift of the electricity export towards the late afternoon hours, thus assisting the evening ramp-up and adding to the grid’s stability and resilience. Based on the results of this study, the possibility of combining the financial incentives for the purchase of an EV with those for the installation of rooftop PV in the owners’ house is very promising and worth considering, due to the demonstrated synergy of electrical storage with the rooftop photovoltaic installations.
]]>Solar doi: 10.3390/solar2020010
Authors: José Lorenzo Balenzategui María Molero José Pedro Silva Fernando Fabero José Cuenca Eduardo Mejuto Javier De Lucas
In this work, the method for calculation of uncertainty of pyrheliometers’ responsivity during their outdoor calibration process in the laboratory is exposed. It is applied first for calibration of standard pyrheliometers by comparison to cavity radiometers, and after for calibration of an end-user pyrheliometer against that standard pyrheliometer. The dissemination of the WRR irradiance scale is illustrated in practice and the increasing uncertainty in the traceability chain is quantified. The way of getting traceability to both WRR scale and to SI units in the current situation, where the shift between these radiometric scales is pending to be solved, is also explained. However, the impact of this gap between scales seems to be more important for calibrations of reference Class A pyrheliometers than in the final determination of DNI irradiance, because in this case, the cumulative uncertainty is large enough as to not significantly be affected for the difference. The way to take into account different correction terms in the measurement model function, and how to compute the corresponding uncertainty, is explained too. The influence of temperature of some pyrheliometers during calibration process and the potential impact on the DNI irradiance calculated with these instruments is exemplified.
]]>Solar doi: 10.3390/solar2020009
Authors: Ramona Kuhn Robert Jensch Thomas Fischer Klaus Keuler Isaac Mbir Bryant Marion Martienssen
Aminophosphonate diethylenetriamine penta(methylenephosphonic acid) (DTPMP) is a scale inhibitor commonly used in several industries. DTPMP is suspected to cause anthropogenic pollution through discharge into the aquatic environment. DTPMP is assumed to be degraded by sunlight radiation. We recently predicted a preliminary degradation pathway of DTPMP applying UV treatment. Currently, we have not yet evidenced that DTPMP shows the same degradation pattern with natural sunlight. One major reason leads to the fact that the light spectrum emitted by UV lamps does not completely represent the natural sunlight spectrum, and the emitted UVB and UVA irradiation flux is much higher than for solar light. For that reason, the degradation pattern and kinetics might be different between artificial UV treatment and natural sunlight treatment. Here, we investigated whether DTPMP is degradable under natural sunlight radiation, and whether the degradation mechanisms determined through UV treatment are transferable to sunlight. We investigated five different treatment conditions, i.e., DTPMP degradation in direct or diffuse sunlight, in diffuse sunlight with addition of Ca2+ or Mg2+, and in diffuse sunlight with local TW. Our experiment was carried out from March 2021 to October 2021. We performed LC/MS analyses and measured the release of o-PO43−. DTPMP was degraded with all five treatment conditions. The fastest DTPMP degradation occurred in direct and diffuse sunlight without addition of bivalent cations. The addition of Ca2+ and Mg2+ resulted in inhibited degradation. Similar effects occurred for sunlight treatment with local TW. We evidenced different degradation mechanisms for DTPMP depending on the presence of alkaline earth metals as we previously proposed for UV-treated DTPMP. However, both degradation mechanisms of DTPMP belong to the same degradation pathway determined with UV treatment. Therefore, we conclude that DTPMP undergoes a similar degradation pathway in sunlight as compared to UV light.
]]>Solar doi: 10.3390/solar2020008
Authors: Julio A. Bragagnolo Kurt Taretto Christian Navntoft
There is a large gap between the vast solar resources and the magnitude of solar energy deployment in Argentina. In the case of photovoltaics, the country only reached the 1000 GWh electricity generated yearly landmark in 2020. Solar thermal technology is even less developed, in part due to the low natural gas prices resulting from political strategies that aim to soften the impact of an unstable economy on family budgets. This review describes this gap by summarizing the current state of Argentine solar energy. We summarize the fundamental legal and strategic tools which are available for solar energy deployment, survey the penetration of solar energy into the country’s energy landscape, identify national contributions to the local value chain, and review past and present research and development achievements. Both photovoltaic and solar thermal technologies show a historical fluctuation between local technology development and imported technology and know-how. Finally, a discussion on the main ingredients required to abridge Argentina’s solar gap indicates that stronger, consistent long-term strategies are required in Argentina in order to take advantage of the present window of opportunity, and to play a considerable role in the global energy transition.
]]>Solar doi: 10.3390/solar2020007
Authors: Benjamin A. Saarloos Jason C. Quinn
Wind and solar renewable energy in the United States is projected to triple by 2050 to nearly 30% of total electric energy generation. The upper Midwest region (Iowa, Minnesota, and North and South Dakota in particular) is considered wind energy country and not historically known for solar energy development. In this work, Value of Solar (VOS) is developed as a photovoltaic (PV) optimization measure and analysis tool using a northwest Iowa municipality as a representative case study. By applying a top-down load duration curve system analysis, VOS is used to optimize PV orientation and compare electric rate structures for increasing levels of total PV energy contribution. VOS of a fixed south-southwest orientation exceeds the levelized annual costs of installation with a larger net benefit than a one-axis-tracking solar system. Production-data modeled VOS is up to 12% higher than Typical Meteorological Year (TMY) predictions, indicating significant correlation between PV generation and peak municipal demand. Compared to alternative time-of-use rates, a demand/energy rate structure better matches VOS economic value and optimal orientation. This VOS methodology is an easy-to-use yet meaningful tool for municipalities and smaller utilities to evaluate strategic installation of and investment in PV for their local community.
]]>Solar doi: 10.3390/solar2010006
Authors: Andreas Livera George Paphitis Marios Theristis Javier Lopez-Lorente George Makrides George Georghiou
The timely detection of photovoltaic (PV) system failures is important for maintaining optimal performance and lifetime reliability. A main challenge remains the lack of a unified health-state architecture for the uninterrupted monitoring and predictive performance of PV systems. To this end, existing failure detection models are strongly dependent on the availability and quality of site-specific historic data. The scope of this work is to address these fundamental challenges by presenting a health-state architecture for advanced PV system monitoring. The proposed architecture comprises of a machine learning model for PV performance modeling and accurate failure diagnosis. The predictive model is optimally trained on low amounts of on-site data using minimal features and coupled to functional routines for data quality verification, whereas the classifier is trained under an enhanced supervised learning regime. The results demonstrated high accuracies for the implemented predictive model, exhibiting normalized root mean square errors lower than 3.40% even when trained with low data shares. The classification results provided evidence that fault conditions can be detected with a sensitivity of 83.91% for synthetic power-loss events (power reduction of 5%) and of 97.99% for field-emulated failures in the test-bench PV system. Finally, this work provides insights on how to construct an accurate PV system with predictive and classification models for the timely detection of faults and uninterrupted monitoring of PV systems, regardless of historic data availability and quality. Such guidelines and insights on the development of accurate health-state architectures for PV plants can have positive implications in operation and maintenance and monitoring strategies, thus improving the system’s performance.
]]>Solar doi: 10.3390/solar2010005
Authors: Elias Kaufhold Jan Meyer Peter Schegner
This paper presents a measurement-based stability analysis of commercially available single-phase inverters in public low-voltage networks. In practice, manufacturers typically do not disclose the parameters of the inverter design, although interactions with the low-voltage network need to be assessed and predicted. State-of-the-art modeling methods require knowledge about the internal parameters. The method proposed in the paper is based on measurements in the laboratory and does not require detailed knowledge about the specific inverter design for the identification of the black-box linear time-periodic representation. The gained information is used for the black-box stability analysis in the frequency range up to 2 kHz, which covers the bandwidth of the control of the inverters. The method is validated for a commercially available photovoltaic inverter in the laboratory. An instability that leads to a shutdown of the inverter is demonstrated, while the critical frequency range is predicted accurately.
]]>Solar doi: 10.3390/solar2010004
Authors: Ayooluwa Peter Adeagbo Funso Kehinde Ariyo Kehinde Adeleye Makinde Sunday Adeleke Salimon Oludamilare Bode Adewuyi Olusola Kunle Akinde
The significance of Distributed Generators (DGs) in the technical and economic operations of electric power distribution systems cannot be overemphasized in recent times. This is essential as a result of the incessant increase in electrical energy demand, which is becoming considerably difficult to meet with the conventional means of energy supply. Thus, DGs offer better alternatives for providing a quality supply of energy near the site of consumption. This type of energy supply is cleaner and cheaper most of the time due to the lessened transmission losses, which consequently reduced the cost of operation at the transmission and distribution levels of the power system. In this work, an approach for placement and sizing of solar PV DGs into radial distribution networks (RDN) based on the solar PV capacity factor of the site was analyzed using particle swarm optimization. The aim of this study is to analyze the effect of the approach on the real and reactive power losses within the network as well as the bus voltage profile. Constraints on credible system operation parameters, which includes bus voltage limits, power balance, and power flow limits, are considered in the formulation of the optimization problem. In order to verify the viability of the deployed approach, steady-state performance analyses were executed on IEEE 33-bus RDN; and the results obtained were compared with the results from other approaches reported in the literature.
]]>Solar doi: 10.3390/solar2010003
Authors: Julia Uruel-Sanz Oscar Perpiñán-Lamigueiro
In the last few years, renewable energies became more socially and economically relevant, and among them, photovoltaic systems stand out. Residential self-consumption of electricity is a field with great potential, and implementation of grid-connected photovoltaic systems (GCPS) is in full rise. The installation of distributed generation systems in residential environments could alter the performance of low-voltage distribution networks, since these are designed for unidirectional power flow and adding these generators means fluctuations in power-flows. For these reasons, a study of the fundamental magnitudes of three low-voltage distribution networks located in Madrid was made for various photovoltaic penetration rates, making use of simulations via the software OpenDSS and subsequent analysis of results. The research concludes that, among other aspects, GCPS produce load flow variations that are dependent on: the penetration rates; the distance from the point of interest and the distribution transformer, increasing the voltage variation between the most productive hours and the night hours with that distance; and on the rate between consumption and generation, so that when it diminishes, the self-sufficiency of the system increases, and with it the voltage of all the buses that tend to the rated voltage. Moreover, there are wide seasonal fluctuations: specifically, in summer months, generation profiles override consumption fluctuations, while in winter months consumption guides voltage and power profiles. Both the code implemented and the results of the analysis were published in an open source website using a free software license.
]]>Solar doi: 10.3390/solar2010002
Authors: Shreyas S. Dindorkar Anshul Yadav
Recently, reactive dyes have attracted a lot of attention for dye-sensitized solar cell applications. This study endeavors to design dye sensitizers with enhanced efficiency for photovoltaic cells by modifying the reactive blue 5 (RB 5) and reactive brown 10 (RB 10) dyes. Three different strategies were used to design the sensitizers, and their efficiency was compared using the density functional theory (DFT). The optimized geometry, bang gap values, the density of states, electrostatic potential surface analysis, and theoretical FT-IR absorption spectra of the sensitizers were obtained. In the first strategy, functional groups (electron-donating (C2H5), electron-withdrawing (–NO2) groups) were anchored onto dye molecules, and their effect on the charge transport properties was evaluated using the DFT analysis. The latter two designs were based on a donor-π-acceptor strategy. The second design consisted of intramolecular donor-acceptor regions separated by a benzodithiophene-based π-spacer. In the third strategy, an external acceptor unit was attached to the dye molecules through the benzodithiophene-based π-spacer. The electron-donating strengths of donor moieties in the donor-π-acceptor systems were studied using B3LYP/6-31G level DFT calculations. The quantum chemical analysis of the three designs revealed that the anchoring of functional groups (–NO2 and C2H5) on the dye molecules showed no impact on the charge transport properties. The introduction of a benzodithiophene-based π-spacer improved the conjugation of the dye sensitizers, which enhanced the electron transport properties. The electron transport properties further improved when an external acceptor unit was attached to the dye molecule containing a π-spacer. It was thus concluded that attaching an external acceptor unit to the donor dye molecule containing a π-spacer produced desired results for both of the dyes.
]]>Solar doi: 10.3390/solar2010001
Authors: Johanna Zikulnig Wolfgang Mühleisen Pieter Bolt Marcel Simor Martin De Biasio
Renewable energy sources such as photovoltaic (PV) technologies are considered to be key drivers towards climate neutrality. Thin-film PVs, and particularly copper indium gallium selenide (CIGS) technologies, will play a crucial role in the turnaround in energy policy due to their high efficiencies, high product flexibility, light weight, easy installation, lower labour-intensiveness, and lower carbon footprint when compared to silicon solar cells. Nonetheless, challenges regarding the CIGS fabrication process such as moderate reproducibility and process tolerance are still hindering a broad market penetration. Therefore, cost-efficient and easily implementable in-line process control methods are demanded that allow for identification and elimination of non-conformal cells at an early production step. As part of this work, a practical approach towards industrial in-line photoluminescence (PL) imaging as a contact-free quality inspection tool is presented. Performance parameters of 10 CIGS samples with 32 individually contacted cells each were correlated with results from PL imaging using green and red excitation light sources. The data analysis was fully automated using Python-based image processing, object detection, and non-linear regression modelling. Using the red excitation light source, the presented PL imaging and data processing approach allows for a quantitative assessment of the cell performance.
]]>Solar doi: 10.3390/solar1010005
Authors: Reza Hassanian Morris Riedel Nashmin Yeganeh Runar Unnthorsson
In this study, recorded empirical data were applied with a practical approach to investigate the optimal tilt angle of the flat plate collectors facing south for a long period in Tehran, Iran. The data included 20 years of recorded average total radiation on the horizontal plane in Tehran’s meteorological station. Based on the previous studies, the annual optimum tilt angle for Tehran was estimated at 33 degrees annually; however, this estimation does not focus on the energy absorption and effectiveness of changing the tilt angle monthly, seasonally, and bi-annually via measured data. This paper aims to explain this distinction between various radiation receptions with different tilt angle adjustments. This study shows that annual solar cumulative radiation energy gained via a monthly tilt angle can be approximately 7% higher than that achieved with an annual tilt angle setup. Additionally, the seasonal and bi-annual tilt angles have about 6% more annual cumulative radiation absorption than the annual tilt angle setup. Moreover, with consideration of similar monthly received radiation, the results illustrate that the radiation gained with a monthly tilt angle set up was 20% greater in the summer months than an annual tilt angle adjustment.
]]>Solar doi: 10.3390/solar1010004
Authors: Jaime Cuadra Samuel Porcar Diego Fraga Teodora Stoyanova-Lyubenova Juan Carda
Doped ZnO are among the most attractive transparent conductive oxides for solar cells because they are relatively cheap, can be textured for light trapping, and readily produced for large-scale coatings. Here, we focus on the development of alternative Na and K-doped ZnO prepared by an easy low-cost spray pyrolysis method for conducting oxide application. To enhance the electrical properties of zinc oxide, alkali-doped Zn1−x MxO (x = 0.03) solid solutions were investigated. The resulting layers crystallize in a single hexagonal phase of wurtzite structure with preferred c-axis orientation along a (002) crystal plane. Dense, well attached to the substrate, homogeneous and highly transparent layers were obtained with great optical transmittance higher than 80%. The optical energy band gap of doped ZnO films increase from 3.27 to 3.29 eV by doping with Na and K, respectively. The electrical resistivity of the undoped ZnO could be decreased from 1.03 × 10−1 Ω.cm to 5.64 × 10−2 Ω.cm (K-doped) and 3.18 × 10−2 (Na-doped), respectively. Lastly, the carrier concentrations increased from 5.17 × 1017 (undoped ZnO) to 1 × 1018 (doped ZnO).
]]>Solar doi: 10.3390/solar1010003
Authors: Adrian B. Boivin Jonathan F. Holzman
This work considers an emerging value-based paradigm for solar generation under high penetration, in light of its conflicting cycles of supply and demand. The resulting swings in electricity prices, in locales such as California, call into question the aim of optimizing solar arrays solely in terms of accumulated electrical power. Thus, this work studies solar arrays in terms of value, as an accumulated product of electrical power and price, where solar arrays that generate greater electrical power over more profitable early- and late-day hours yield improved value. Experimental, theoretical, and economic analyses are given to characterize the industry-standard angled-panel, an alternative V-groove, and a new U-groove array over a 5-year study. The trends and projections suggest that the industry-standard angled-panel array realizes the best value-based performance at present, although it will likely be outperformed in the foreseeable future by the V-groove array.
]]>Solar doi: 10.3390/solar1010002
Authors: Juergen H. Werner
Climate change and the consequential environmental catastrophes are real, not only in less developed countries of the so-called “Global South” but also in so-called industrialized and “well-developed” areas of the world! Just within the last few months and years, we have seen high-temperature records in the United States, fire disasters in Canada, Australia, Greece, Italy, and Spain [...]
]]>Solar doi: 10.3390/solar1010001
Authors: Yu Lin Giulia Stefenelli Liliane Auwerter
Solar energy is the basis for life on earth [...]
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