Recycling

During recent years, gasification technology has gained a high potential and attractiveness to convert biomass and other solid wastes into a valuable syngas for energy production or synthesis of new biofuels. The implementation of real gasification facilities implies a good insight of all expenses that are involved, namely investments required in equipment during the project and construction phases (capital expenditures, CapEx) and costs linked to the operation of the plant, or periodic maintenance interventions (operational expenditures, OpEx) or costs related to operations required for an efficient and sustainable performance of a gasification plant (e.g., feedstock pre-treatment and management of by-products). Knowledge of these economic parameters and their corresponding trends over time may help decision-makers to make adequate choices regarding the eligible technologies and to perform comparisons with other conventional scenarios. The present work aims to provide an overview on CapEx associated with gasification technologies devoted to convert biomass or solid waste sources, with a view of reducing the carbon footprint during energy generation or production of new energy carriers. In addition, an analysis of technology cost trends over time using regression methods is also presented, as well as an evaluation of specific capital investments according to the amount of output products generated for different gasification facilities. The novelty of this work is focused on an analysis of CapEx of existing gasification technologies to obtain distinct products (energy and fuels), and to determine mathematical correlations relating technology costs with time and product output. For these purposes, a survey of data and categorization of gasification plants based on the final products was made, and mathematical regression methods were used to obtain the correlations, with a statistical analysis (coefficient of determination) for validation. Specific investments on liquid biofuel production plants exhibited the highest decreasing trend over time, while electricity production became the least attractive solution. Linear correlations of specific investment versus time fitted better for electricity production plants (R² = 0.67), while those relating the product output were better for liquid biofuel plants through exponential regressions (R² = 0.65). Full article

The global population has increased over time, therefore the need for sufficient energy has risen. However, many countries depend on nonrenewable resources for daily usage. Nonrenewable resources take years to produce and sources are limited for generations to come. Apart from that, storing and energy distribution from nonrenewable energy production has caused environmental degradation over the years. Hence, many researchers have been actively participating in the development of energy storage devices for renewable resources using batteries. For this purpose, the lithium-ion battery is one of the best known storage devices due to its properties such as high power and high energy density in comparison with other conventional batteries. In addition, for the fabrication of Li-ion batteries, there are different types of cell designs including cylindrical, prismatic, and pouch cells. The development of Li-ion battery technology, the different widely used cathode and anode materials, and the benefits and drawbacks of each in relation to the most appropriate application were all thoroughly studied in this work. The electrochemical processes that underlie battery technologies were presented in detail and substantiated by current safety concerns regarding batteries. Furthermore, this review collected the most recent and current LIB recycling technologies and covered the three main LIB recycling technologies. The three recycling techniques—pyrometallurgical, hydrometallurgical, and direct recycling—have been the subject of intense research and development. The recovery of valuable metals is the primary goal of most recycling processes. The growth in the number of used LIBs creates a business opportunity to recover and recycle different battery parts as daily LIB consumption rises dramatically. Full article

Asphalt recycling technology with a high content of reclaimed asphalt pavement (RAP) is becoming more important as the price of paving materials rises and sustainable development and environmental conservation rules become more rigorous. Nevertheless, road authorities in numerous countries still prohibit the utilisation of RAP in asphalt mixes due to the negative impacts of RAP on the performance of asphalt mixtures. Consequently, different rejuvenators have been introduced to reinstate the original attributes of aged asphalt to resolve this issue. This study incorporated vacuum residue (VR) into mixtures with 40% RAP. The physical, rheological, and mechanical traits of the resultant samples were assessed. The results show that the 7.5% VR rejuvenator minimised the RAP asphalt ageing impact. Furthermore, the rejuvenating agent demonstrated physical and rheological rehabilitative benefits for the aged asphalt. The mechanical attributes of the rejuvenated samples were also enhanced compared to the virgin asphalt (VA) specimens. Full article

Less than half of e-waste plastics are sorted worldwide, and this rate is likely to decline as major processing countries have banned importation of e-waste plastics. This forces the development of decentralized processing facilities, also known as microfactories. The present work investigates the recyclability of different grades of acrylonitrile-butadiene-styrene (ABS) copolymer, polycarbonate, and polypropylene, which were found to be very abundant in a recycling site in the UK. The determination of the matrix relied on the resin identification codes imprinted in the e-waste plastics and subsequent Fourier-transform infrared spectroscopy (FTIR). Melt-blend extrusion technology enabled the valorization of the wasted thermoplastics as 3D filament without significant degradation of the polymers. The recycled materials maintained the tensile strength at around 2.5 MPa in agreement with the specifications offered by virgin polymers. Further characterization was done by means of laser microscope, thermogravimetric analysis, and X-ray fluorescence to determine the commercial viability of the recycled filament. A modified solvent-based method was developed with acetone to remove the brominated flame retardants: 25 g/100 mL, 30 min of contact time, and 4 extraction steps. The FTIR results show that the degradation of the rubbery dispersed phase corresponding to the butadiene can be accumulated in the less soluble fraction of the extracted ABS. Full article

The aim of this paper is twofold: (a) to present the existing regional research related to customer education and communication in municipal waste recycling from the viewpoint of a comparative bibliometric analysis and (b) to illustrate how municipal waste recycling practices in the two countries mirror the theoretical trends identified in the literature and the EU institutional and policy requirements. We discuss the practical implementation of municipal waste recycling practices in the two European countries and provide practical recommendations for local governments, municipal companies, and other stakeholders of the municipal waste management process. Full article

The growth of civil construction and agroindustry, resulting from population growth, caused an increase in the demand for non-renewable resources and for the exploitation of natural resources. Consequently, it caused a greater generation of waste, causing the current scenario to require alternatives for the reuse of these materials. Particleboard panels, for example, used in civil construction, can add value to waste or materials of low acceptance, such as thinning wood, mechanical wood processing waste or agro-industrial waste. Thus, this study proposed to analyse the life cycle of the sugarcane bagasse, considering the stages of extraction of materials and energy resources until their final disposal. This study aimed to compare impacts generated by the production of particleboards panels produced with wood from plantations (pine) and with the sugarcane bagasse. As a result, a better environmental performance was obtained from the panel composed of sugarcane bagasse, as it generated lower environmental impacts in all impact categories studied. The benefits range from the reduction in waste disposed of in landfills, which increase its useful life, the lower demand for reforestation, with steps that generate atmospheric emissions and degrade the soil. Full article

Recovering and recycling nitrogen available in waste streams would reduce the demand for conventional fossil-based fertilizers and contribute toward food security. Based on life cycle assessment (LCA), this study aimed to evaluate the environmental performance of nitrogen recovery for fertilizer purposes from sewage sludge treatment in a municipal wastewater treatment plant (WWTP). Utilizing either air stripping or pyrolysis-derived biochar adsorbent, nitrogen was recovered from ammonium-rich reject streams generated during mechanical dewatering and thermal drying of anaerobically digested sewage sludge. A wide range of results was obtained between different scenarios and different impact categories. Biochar-based nitrogen recovery showed the lowest global warming potential with net negative GHG (greenhouse gas) emissions of −22.5 kt CO₂,eq/FU (functional unit). Ammonia capture through air stripping caused a total GHG emission of 2 kt CO₂,eq/FU; while in the base case scenario without nitrogen recovery, a slightly lower GHG emission of 0.2 kt CO₂,eq/FU was obtained. This study contributes an analysis promoting the multifunctional nature of wastewater systems with integrated resource recovery for potential environmental and health benefits. Full article

The need to reduce the negative environmental impact of energetics with the growing energy demand in the world is the core objective of the industry for the upcoming decades. The global agenda in the field of environmental protection increases the requirements for evaluation of the energy investment projects, in particular for their environmental efficiency. Currently, much attention is paid to assessing the impact of the project on atmospheric air, water bodies and land resources, including the formation of industrial waste during the operational stage. The formation of production and consumption waste at other stages of the project life cycle is not considered either when generating cash flows or when conducting the assessment pf environmental efficiency. It might significantly reduce the reliability of assessment results. The purpose of this study is to develop a system of integrated accounting for all types of waste generated and the environmental costs incurred for handling them during the environmental and economic assessment of energy projects. The paper discusses modern waste management practices at energy enterprises, waste generation at various stages of investment projects implementation, and provides recommendations on waste accounting when assessing their environmental and economic efficiency. Full article

This article presents the numerical modeling of the thermochemical conversion of biomass and tires as alternative fuels in kilns dedicated to the production of cement. The study seeks to understand and control the phenomena that occur when heavy fuel oil (traditional fuel) is partially replaced by biomass and tires. These are thoroughly mixed with meal at the entrance to the rotary kiln and form the bed of solids. The mathematical model developed takes into account both chemical reactions of meal and alternative fuels. At the entrance, the meal is made up of species such as CaCO₃, MgCO₃, Al₂O₃, SiO₂, Fe₂O₃, MgO, CaO, C₂S, C₃A, C₄AF and C₃S, some of which form along the kiln. The article focuses specifically on the influence of alternative fuels on the clinker or cement obtained. The properties (moisture, organic matter, composition, energy value, etc.) of the biomass and the tires, which are associated with the operating parameters of the kiln, greatly influence the production of clinker. In order to understand and control the behavior of each material and the operating parameters in the clinker (cement) production process, the mathematical model follows the evolution of each species and parameters step-by-step, until the clinker is obtained. The effect of alternative fuels on clinker production was found for the kiln’s operational parameters, the dynamic angle of the bed (30°), the angle of inclination of the kiln (2°), rotation (2 rpm), the length and the inside diameter, respectively (80 m) and (4 m); the chemical and physical properties (humidity, organic, inorganic matter, C, H, O, N, S, Cl); the lower calorific value, raw material); and the numerical parameters (spatial discretization 30 and 120). Despite the high energy content of tire fuels, the results of the use of biomass give better characteristics of clinker/cement (52.36% C3S and 3.83% CaO).The results found show that biomass pyrolysis is endothermic, with the heat of reaction found to be ${∆}_r{H}^{pyro}=184.9 \mathrm{kJ}/\mathrm{kg}$, whereas for tires, a heat of reaction of ${∆}_r{H}^{pyro}=-1296.3 \mathrm{kJ}/\mathrm{kg}$ was found, showing that the pyrolysis of this material is exothermic. Char production is higher in the case of tires than in the case of biomass, with rates of 0.261 kg/kgOrg.Mat. and 0.196 kg/kgOrg.Mat., respectively. In both cases, waste conversion was complete (100%). The cement obtained in the different cases meets the requirements of Portland cements (73.06% silicates and 18.76% aluminates), the conversion of alternative fuels is complete (100%), and the specific energy consumption is almost consistent with values from the literature. Full article

This study aimed to investigate the relationships between knowledge, attitudes, and values in promoting zero-waste, pro-environmental behaviour among the university campus community and how technology plays its role. A survey instrument was developed from the findings of earlier focus group discussions and in-depth interviews, which were based on the adaptation and adoption of previous studies, especially Kollmuss and Agyeman’s 2002 Model of Pro-Environmental Behaviour and a modified Knowledge-Attitude-Practises Model. Three hundred ninety-three respondent samples from Universiti Kebangsaan Malaysia, Universiti Putra Malaysia, and Universiti Sains Malaysia were analysed for their insights regarding their vision of a Zero-Waste Campus using the Structural Equation Modelling approach. The results show positive relationships between the five studied variables and the proposed hypotheses. Knowledge and attitudes serve as moderating variables, enhancing the strength of the causal effects of the related relationships. As the results show good significance, proper planning for integrating the studied variables and the proposed zero-waste campus framework can be used by university management, other institutions, or national-level agencies to develop an environment-specific plan to promote zero-waste, pro-environmental behaviour. Full article

Post-consumer polystyrene (PS) recyclates behind a functional barrier of virgin PS polymer is an attractive way to introduce post-consumer PS recyclates in packaging materials. However, until now, there has been no official guidance published on how to test the performance of a functional barrier. In addition, no threshold limits for the evaluation of post-consumer recyclates behind FBs have been published by competent authorities. This is a drawback in the food law compliance evaluation and novel technology notification of post-consumer recyclates behind a functional barrier. In this study, co-extruded yogurt cups with an artificially spiked core layer were investigated with respect to migration of the applied surrogates. The applied migration kinetic testing method into the gas phase was shown to be sensitive and suitable for the evaluation of the functional barrier performance. For consumer safety evaluation, two worst-case scenarios were used. As a result, due to the high processing temperatures used during co-extrusion, the virgin PS functional barrier layer was partly contaminated with the surrogates from the core layer. However, on the basis of the conditions, data, and the evaluation presented, the use of post-consumer recycled PS behind an FB of virgin PS can be considered as safe. Full article

Increasing conditions of economic and social well-being have led to an increase in waste production. Among the waste products, a significant portion consists of plastic materials that are popular in the components of consumer goods. For this reason, the conversion of plastic to energy via controlled combustion and plastic to fuel via thermal/catalytic pyrolysis or gasification can be proposed to treat the residual heterogeneous mixed plastics that cannot be recovered as individual polymers. The quality and type of fuels that are possible to obtain from these processes are different, as is the quality of their emissions, which generally contain VOCs, PCBs, dioxins, PAHs, and heavy metals. In this work, we propose a methodology based on human health risk assessment to compare controlled combustion and catalytic pyrolysis. Many pathways are analyzed, and pollutant concentrations are computed in the atmosphere, water, vegetables, fish, and food. Exposure is evaluated for inhalation and ingestion routes by taking into account uncertainties. Our results show that the risk profile of catalytic pyrolysis is low. Controlled combustion remains an interesting process, but even if Best Available Technologies (BAT) are adopted, the cancer risk due to PAHs contained in particulate is around the threshold for people living near the plant if a long period of operation is considered. Full article

The Voluntary Agreement for Collecting and Recycling Plastic Waste (VA), including polyvinyl chloride (PVC) profiles and flooring materials, will be converted to an Extended Producer Responsibility (EPR) system from 2023. The objective of this study is to calculate the standard recycling cost and the recycling market size for preparing the new system. Among the total recycling companies participating in the VA, a cost analysis was conducted for 11 profile businesses (35% of the total businesses) and seven flooring businesses (58% of the total businesses). As a result, the standard recycling cost was calculated as 0.45 USD/kg for PVC profiles and 0.36 USD/kg for PVC flooring materials. As of 2020, the total market size is 1135 million USD (5.86 million USD for PVC profiles and 5.49 million USD for PVC flooring materials). Our research shows that few countries have nationally managed accurate data regarding PVC profiles and flooring waste. Compared to the European Union (EU), the total amount of recycled PVC products in Korea seems lower, but the recycling rate per capita is higher. This study can provide basic data about the recycling industry for the recycling academia and the manufacturing field. Full article

Facilitating solid waste separating behavior at home continues to be a challenge for municipal programs in emerging economies. Large cities concentrate the generation of solid waste and, in Latin America, a great percentage of this waste is not re-used. Therefore, in this research, we explore the drivers motivating solid waste separation at home in Lima. We applied 450 surveys in two municipalities of Lima and analyzed the results through Structural Equation Modeling (SEM). The results demonstrate that attitude, perception of technical knowledge, and availability of physical space influence solid waste separation behavior. Additionally, the mediating role of intention between solid waste separation attitude and behavior is demonstrated. Municipal solid waste recycling programs in emerging economies tend to focus on educational and motivational actions, without giving due importance to space at home in order to manage solid waste. The lack of urban equipment and the limited availability of space at home introduce barriers that limit solid waste separating behaviors in emerging economies. Full article

In this study, we investigated flotation muds (FM) deriving from the recovery processes of precious metals contained in e-waste (wastes from electronics) and exhausted catalysts. FM consist of an amorphous phase, corresponding to a Ca- and Al-rich silicatic glass, potentially usable as a secondary raw material (SRM) to obtain a final ceramic product (CFM). A high FM amount was used in our ceramic tests, and suitably mixed with variable percentages of other phases. Chemical analysis, phase composition, microstructure, pore pattern and technological properties of the new ceramic products were determined using different analytical techniques, including bulk XRF, XRD, SEM-EDS and µCT. The CFM product predominantly consists of nepheline, pyroxene and wollastonite as the main crystalline phases, with a minor amorphous phase occurring as a compact interstitial matrix. The ceramic product has a porous interconnected microstructure. Nevertheless, this microstructure does not negatively affect the mechanical properties of the ceramic product, as testified by the geo-mechanical tests, revealing good properties in terms of bending and uniaxial strength. These preliminary results point out that FM recycling is feasible, at least at the laboratory scale. Full article

The search for ways to utilize and recycle industrial by-products is the basic principle that governs rational environmental management, synthesis of “green” materials, and appears as one of the main criteria for sustainable development in most countries of the world. Gypsum-containing waste (GCW) derived from industries, represents a large-tonnage product. The production of gypsum materials could be one of the ways to recycle GCW products. GCW from various industries can be used as an alternative to natural raw materials when producing gypsum binders. However, the features of GCW do not allow the production of a high-quality binder when traditional technologies are applied, so it requires the development of additional methods or the introduction of various modifiers to the binder system. One of the ways to increase the efficiency of GCW as a raw material for the production of gypsum binders is to apply a semi-dry pressing method, at reduced values of the W/S ratio of the binder. The objective of this research was to study the possibility of increasing the efficiency of GCW using citrogypsum for production of gypsum materials, by optimization of the mix design and by applying a semi-dry pressing method, using a lower pressure load at the molding stage. The mix design and technological parameters were optimized using mathematical planning of the experimental method. Parameters such as the amount of citrogypsum as an additive in the raw mixture, molding pressure, and water–solid (W/S) ratio were taken as input parameters of variation. To plot the relationship of the input–output parameters, the SigmaPlot software was applied, to analyze and demonstrate scientific and statistical data in the form of nomograms. It has been established that the use of the semi-dry pressing method with the optimal mix design and technological parameters, makes it possible to obtain gypsum samples with demolding strengths up to 2 MPa, and final compressive strengths up to 26 MPa. The incorporation of citrogypsum and the optimal W/S ratio of 0.25, results in positive effects, such as a reduction in the sticking properties of the mix during the demolding stage, and the homogeneity of compaction and visual appearance of the samples were also improved. Full article

Vinyl, such as those in the form of mulching and vinyl houses, is used to improve agricultural productivity. It is generated as an agriculture waste vinyl (AWV) after use. The collected AWV is transported to a recycling facility and shredded, washed, and compressed to be recycled. Recycled materials can contribute to the circular economy of agriculture as they are used again as an agricultural plastic product. However, in Korea, there are concerns about the illegal disposal (landfill, incineration) of AWV. So, a new management model is needed in which stakeholders voluntarily establish an AWV management system. In this study, a sustainable management strategy was proposed. This strategy is reinforcing the responsibility of the producers of AWV and forms a value chain in the proper discharge after consumption by applying the deposit system proposed to recover AWV. Local governments and the National Agricultural Cooperative Federation (NH) proposed education to curb the illegal disposal of AWV, and for managing areas where a collection system has not yet been established, biodegradable mulching vinyl (BMV) was proposed to minimize the environmental pollution caused by AWV. It was calculated that the EPR contribution was 0.16 USD/kg, and the introduction of BMV was 0.42 USD/kg in Korea. This study will provide a new alternative in countries struggling with AWV management. Full article

Global objectives to mitigate climate change in the construction industry have led to increasing geopolymer development as an alternative to carbon-intensive cement. Geopolymers can have similar mechanical properties and a lower carbon footprint. However, geopolymer production is not as homogeneous as cement because it is produced by synthesizing alkali solutions with different aluminosilicate precursors. This study assessed the feasibility of using conventional (fly ash, blast furnace slag, and metakaolin) and alternative precursors (steel slag, mine tailings, glass waste, sewage sludge ashes, and municipal solid waste incineration bottom ashes (MSWI BA)) in geopolymer mixes for different European regions (Belgium and Finland) from a sustainability perspective, using environmental, economic, and resource availability indicators as the criteria. A multi-objective optimization technique was applied to identify optimal precursors for geopolymer mixes using two scenarios: (1) considering both conventional and alternative precursors; (2) only considering alternative precursors. The results from the first scenario show that one of the most optimal precursor combinations for the geopolymer mix is 50% fly ash, 25% MSWI BA, and 25% sewage sludge ash for Belgium. For Finland, it is 19% fly ash, 27% mine tailings, and 45% MSWI BA. For the second scenario, one of the most optimal precursor combinations for Belgium is 87% MSWI BA and 13% steel slag. For Finland, it is 25% mine tailings and 75% MSWI BA. Subsequently, linear regression analysis was applied to predict the compressive strength of the identified optimal mixes, and the results for Belgium and Finland were between 31–55 MPa and 31–50 MPa for the first scenario and between 50–59 MPa and 50–55 Mpa for the second scenario, respectively. Full article

One of the main tasks of the circular economy is the decoupling between economic growth and natural resource consumption at the input and the volume of generated waste at the output. The effectiveness of this process can be assessed by the dynamics of the eco-intensity indicators at the macro-, meso- and micro-levels. The article presents the assessment results of the decoupling and growth color of the mining sector in Russia, which show the dynamics of eco-intensity indicators and may reflect the trend towards a circular economy. For the period 2010–2021, it was revealed that negative expansion decoupling and “Black” growth have been observed in terms of generated waste and atmospheric pollution, strong decoupling and “Green” growth in terms of hydrosphere pollution, weak decoupling and “Brown” growth in terms of electricity consumption, and according to water intake from natural water bodies, expansion coupling and “Black” growth. During the study period, the gross value added (GVA) of the mining industry in Russia in comparable prices increased by 77%, while the industry’s negative impact on the atmosphere increased by 34%; the volume of production and consumption waste generation increased by 131%, and the negative impact on the hydrosphere decreased by 51%. The growth of the environmental and economic efficiency of any system can be achieved by influencing the drivers and barriers to moving towards a circular economy, so it is important to identify the most significant factors of influence for a particular industry, region or country in the current conditions. Using the ordinary least squares (OLS) method, it was revealed that factors reflecting innovative activities of the mining industry have a significant impact on reducing eco-intensity in the field of electricity consumption and water intake from natural water bodies. The significance of these factors’ influence has been confirmed not only at the macro-level, but also at the micro-level. Full article