Research

17 pages, 33464 KiB

Open AccessArticle

Mechanical Behaviour of As-Manufactured and Repaired Aligned Discontinuous Basalt Fibre-Reinforced Vitrimer Composites

by Leon L. Messmer, Ali Kandemir, Burak Ogun Yavuz, Marco L. Longana and Ian Hamerton

Polymers 2024, 16(8), 1089; https://doi.org/10.3390/polym16081089 - 13 Apr 2024

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The aim of this research is to investigate basalt as a natural mineral-based fibre together with a vitrimeric resin as a sustainable alternative to standard composite materials. Vitrimers combine the properties of thermoset and thermoplastic polymers, enabling the repair of specimens and hence [...] Read more.

The aim of this research is to investigate basalt as a natural mineral-based fibre together with a vitrimeric resin as a sustainable alternative to standard composite materials. Vitrimers combine the properties of thermoset and thermoplastic polymers, enabling the repair of specimens and hence prolonging the lifetime of the composite material. The micro-mechanical characteristics between the basalt fibres and the vitrimer resin are reported and shown to match those of a standard Skyflex K51 epoxy resin. Discontinuous (4 mm) basalt fibres were employed to produce aligned discontinuous fibre-reinforced composites (ADFRCs) using the high-performance discontinuous fibre (HiPerDiF) technology. The mechanical characteristics of the laminates were investigated through tensile testing and the fracture zones were analysed under a scanning electron microscope. By normalising the results by their respective fibre volume fraction, it was discovered that the vitrimer–basalt ADFRCs exhibited, on average, a 4% higher strength and a 25% higher stiffness compared to their basalt epoxy counterparts. The repair potential of the vitrimer ADFRC specimens was explored during low-temperature compression repair. Two approaches were tested using double-sided local- and full-patch repair. Both successfully recovered a significant amount of their prime strength. In conclusion, the potential of the sustainable vitrimer–basalt composite is shown by its competitive mechanical performance. Combining this with the manufacturing flexibility, repair potential, and recyclability of the material, the vitrimer–basalt composite seems to be a competitive alternative to standard glass epoxies. Full article

(This article belongs to the Special Issue Mechanical Behavior of Polymeric Materials: Recent Trends and Advancements)

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19 pages, 8732 KiB

Open AccessArticle

Experimental Study on the Optimization of the Autoclave Curing Cycle for the Enhancement of the Mechanical Properties of Prepreg Carbon–Epoxy Laminates

by Soňa Rusnáková, Michal Grunt, Milan Žaludek, Jakub Javořík and Barbora Kotlánová

Polymers 2024, 16(1), 47; https://doi.org/10.3390/polym16010047 - 22 Dec 2023

Viewed by 758

Abstract

In this study, the influence of the technological parameters of autoclave curing on the resulting mechanical properties of laminates was investigated. The main criterion for optimizing the curing was to extend the processing window with a lower prepreg viscosity. At the same time, [...] Read more.

In this study, the influence of the technological parameters of autoclave curing on the resulting mechanical properties of laminates was investigated. The main criterion for optimizing the curing was to extend the processing window with a lower prepreg viscosity. At the same time, the issue of setting the pressure level before the heat ramp to the final cure temperature was also addressed. An experimental method of measuring the indentation viscosity of the prepreg was used to determine the viscosity profile. Despite the experimental nature of the method, the reliability of this method for rapid approximate identification of the processing window of the prepreg was verified by the results of the study. Several laminates with the same ply orientation were produced using the selected cure cycles, from which test specimens were cut with a water jet and inspected by confocal microscopy. The mechanical properties of tension and flexure were measured within the individual curing cycles using tests according to ISO standards. The data reported demonstrate that the experimental method of optimizing the curing parameters has successfully increased the selected mechanical properties. The resulting mechanical properties of the laminates were enhanced by up to 20% compared to the non-optimized cure cycle. The influence of the type of cure cycle on the resulting thickness of the cured laminate was evaluated in this study. Full article

(This article belongs to the Special Issue Mechanical Behavior of Polymeric Materials: Recent Trends and Advancements)

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14 pages, 4358 KiB

Open AccessArticle

Morphologies of Comb-like Polyacrylic Acid/Polyacrylate Copolymers as Functions of the Degree of Derivatization with n-C₂₂H₄₅ Side Chains

by Tomoya Okada, Mizuho Ishii, Harumi Sato and Go Matsuba

Polymers 2023, 15(24), 4663; https://doi.org/10.3390/polym15244663 - 11 Dec 2023

Viewed by 1148

Abstract

Polymers with crystallizable side chains have numerous applications, and their properties depend on their crystal morphologies and phase separation. Structural analysis on a wide spatial scale plays an important role in controlling the thermal properties and higher-order structures of these polymers. In this [...] Read more.

Polymers with crystallizable side chains have numerous applications, and their properties depend on their crystal morphologies and phase separation. Structural analysis on a wide spatial scale plays an important role in controlling the thermal properties and higher-order structures of these polymers. In this study, we elucidated the melting and crystallization processes of copolymers with varying crystallizable side-chain fractions over a wide spatial range. Differential scanning calorimetry revealed that the enthalpies of melting and crystallization increased linearly with increasing crystallizable side-chain fraction. The results of wide-angle X-ray scattering indicated that the crystal lattice was hexagonal. Conversely, spherulite-like higher-order architectures with linear structures and radial spreading were observed in the highly crystallizable components, but no micrometer-scale structures were observed in the less crystallizable components. In situ small-angle X-ray scattering was used to elucidate the phase separation and mixing processes. Lamellar crystallites were observed at crystallizable side-chain fractions of >55 wt.%, whereas small crystallites were observed at fractions of <45 wt.%. At temperatures above the order-disorder transition temperature, density fluctuations caused by correlation holes were observed. These properties have a strong effect on the crystallizable side-chain fraction. Full article

(This article belongs to the Special Issue Mechanical Behavior of Polymeric Materials: Recent Trends and Advancements)

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13 pages, 12871 KiB

Open AccessArticle

Direct 3D Printing of Recycled PET/PP Granules by Shear Screw Extrusion

by Dashan Mi, Jie Zhang, Xianqing Zhou, Xinhe Zhang, Shikui Jia and Haiqing Bai

Polymers 2023, 15(24), 4620; https://doi.org/10.3390/polym15244620 - 05 Dec 2023

Cited by 1 | Viewed by 981

Abstract

This article introduces a one-step extrusion-based fused deposition modeling (FDM) approach for the challenging separation of polypropylene (PP) and polyethylene terephthalate (PET) during recycling. A shear screw printer (SSP) with shear elements was designed, and it was compared to a conventional single-screw printer [...] Read more.

This article introduces a one-step extrusion-based fused deposition modeling (FDM) approach for the challenging separation of polypropylene (PP) and polyethylene terephthalate (PET) during recycling. A shear screw printer (SSP) with shear elements was designed, and it was compared to a conventional single-screw printer (CSP) to investigate the differences in print stability, degradation levels, tensile performance, molecular orientation, and crystallization when preparing recycled PP and recycled PET blends. Although the retention effect of the SSP screw slightly increases the degradation of the blended rPP/rPET, the strong shear (2.6 × 10⁴ s⁻¹) applied near the extrusion exit improves the blending efficiency. The SSP also enhances molecular orientation, modulus of the parts, and reduces performance fluctuations. Additionally, the SSP has the potential to simplify the recycling process, enabling the transformation of blended recycled materials into products with just one melt process. Full article

(This article belongs to the Special Issue Mechanical Behavior of Polymeric Materials: Recent Trends and Advancements)

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18 pages, 6205 KiB

Open AccessArticle

The Impact of Liquid Components on Alteration of the Adhesion of Polyacrylate and Silicone Patches

by Bartosz Maciejewski, Joanna Dłabiszewska, Barbara Mikolaszek and Małgorzata Sznitowska

Polymers 2023, 15(22), 4355; https://doi.org/10.3390/polym15224355 - 08 Nov 2023

Viewed by 861

Abstract

Polyacrylates and polysiloxanes are polymers used in pressure-sensitive adhesive (PSA) patches. Liquid additives are co-solvents of the active substances or permeation enhancers, and their compatibility with the polymeric matrix and the effect on adhesive properties should be considered. The patches were prepared from [...] Read more.

Polyacrylates and polysiloxanes are polymers used in pressure-sensitive adhesive (PSA) patches. Liquid additives are co-solvents of the active substances or permeation enhancers, and their compatibility with the polymeric matrix and the effect on adhesive properties should be considered. The patches were prepared from commercial polyacrylates (three types of Duro-Tak^®) and siloxanes (Bio-PSA^® and Soft Skin Adhesive^®). Propylene glycol, polyoxyethylene glycol, isopropyl myristate, triacetin, triethyl citrate and silicone oil were added (10% w/w). Formulations were evaluated microscopically and with a texture analyzer in terms of in vitro adhesiveness and hardness. Only silicone oil was compatible with the silicone matrices. The best compatibility of acrylic PSA was observed with triethyl citrate; one out of three Duro-Tak matrices was incompatible with every additive. In all compositions, the adhesiveness was impaired by the liquid additives. A significant drop in adhesiveness was noted after immersion of the patches in buffer and drying. The probe tack test was considered as the most useful for evaluation of the effect of the liquid additive on adhesiveness, but the results obtained with a spherical and cylindrical probe were contradictory. The structural changes caused by the additives were also demonstrated by a 90° peel test, considered as complementary to the tack test. Full article

(This article belongs to the Special Issue Mechanical Behavior of Polymeric Materials: Recent Trends and Advancements)

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15 pages, 3540 KiB

Open AccessArticle

Investigation of the Mechanical and Tribological Behavior of Epoxy-Based Hybrid Composite

by Thamer Albahkali, Ahmed Fouly, Ibrahim A. Alnaser, Mahmoud B. Elsheniti, Ahmed Rezk and Hany S. Abdo

Polymers 2023, 15(19), 3880; https://doi.org/10.3390/polym15193880 - 25 Sep 2023

Cited by 2 | Viewed by 921

Abstract

The main target of this study is to evaluate the impact of hybrid reinforcement using Al₂O₃ nanoparticles and graphite on the epoxy nanocomposites’ mechanical and tribological properties. Various weight fractions of the reinforcement materials, ranging from 0 to 0.5 wt.%, [...] Read more.

The main target of this study is to evaluate the impact of hybrid reinforcement using Al₂O₃ nanoparticles and graphite on the epoxy nanocomposites’ mechanical and tribological properties. Various weight fractions of the reinforcement materials, ranging from 0 to 0.5 wt.%, were incorporated into the epoxy. The aim is to enhance the characteristics and durability of the polymers for potential utilization in different mechanical applications. The addition of hybrid additives consisting of Al₂O₃ nanoparticles and graphite to the epoxy resin had a noticeable effect on the performance of the epoxy nanocomposites. The incorporation of these additives resulted in increased elasticity, strength, toughness, ductility, and hardness as the concentration of reinforcement increased. The enhancement in the stiffness, mechanical strength, toughness and ductility reached 33.9%, 25.97%, 25.3% and 16.7%, respectively. Furthermore, the frictional tests demonstrated a notable decrease in both the coefficient of friction and wear with the rise of the additives’ weight fraction. This improvement in the structural integrity of the epoxy nanocomposites led to enhanced mechanical properties and wear resistance. The SEM was utilized to assess the surfaces of tested samples and provide insights into the wear mechanism. Full article

(This article belongs to the Special Issue Mechanical Behavior of Polymeric Materials: Recent Trends and Advancements)

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26 pages, 5928 KiB

Open AccessArticle

Innovative Strategies for Technical-Economical Optimization of FDM Production

by Dragoș Gabriel Zisopol, Maria Tănase and Alexandra Ileana Portoacă

Polymers 2023, 15(18), 3787; https://doi.org/10.3390/polym15183787 - 16 Sep 2023

Cited by 5 | Viewed by 732

Abstract

This article introduces a multi-objective optimization approach for determining the best 3D printing parameters (layer thickness and infill percentage) to efficiently produce PLA and ABS parts, extensively analyzing mechanical behavior under tests for different traits such as tensile strength, compression, flexural, impact, and [...] Read more.

This article introduces a multi-objective optimization approach for determining the best 3D printing parameters (layer thickness and infill percentage) to efficiently produce PLA and ABS parts, extensively analyzing mechanical behavior under tests for different traits such as tensile strength, compression, flexural, impact, and hardness. The value analysis method is used to optimize settings that balance use value (V_i- represented by mechanical characteristics) and production cost (C_p). Findings reveal that the infill percentage significantly influences the V_i/C_p ratio for tensile, compression, and hardness tests, while flexural tests are influenced by layer thickness. Impact strength is influenced nearly equally by both factors, with material-specific variations. The desirability function proved useful for optimizing processes with multiple responses, identifying the optimal parameters for the FDM process: a layer thickness of 0.15 mm with 100% infill percentage for PLA, a layer thickness of 0.20 mm with 100% infill percentage for annealed PLA, and a layer thickness of 0.15 mm with 100% infill percentage for ABS. Overall, this study guides efficient 3D printing parameter selection through a technical-economic optimization based on value analysis. Full article

(This article belongs to the Special Issue Mechanical Behavior of Polymeric Materials: Recent Trends and Advancements)

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21 pages, 5192 KiB

Open AccessArticle

Studies on the Effect of the Addition of Nano-Spherical Particles of Aluminum on the Thermal, Mechanical, and Morphological Properties of PBT–PET Blend Composites

by Abdullah Alhamidi, Arfat Anis, Zahir Bashir, Mohammad Asif Alam and Saeed M. Al-Zahrani

Polymers 2023, 15(17), 3625; https://doi.org/10.3390/polym15173625 - 01 Sep 2023

Cited by 3 | Viewed by 977

Abstract

In previous works, we had found that the addition of micron-sized, irregular-shaped aluminum (Al) powder, or Al nano platelets (flakes), improved the mechanical properties of polyesters, and that, additionally, the flakes led to an increase in electrical conductivity. The aim of this work [...] Read more.

In previous works, we had found that the addition of micron-sized, irregular-shaped aluminum (Al) powder, or Al nano platelets (flakes), improved the mechanical properties of polyesters, and that, additionally, the flakes led to an increase in electrical conductivity. The aim of this work was to examine the effect of nano-spherical particles of aluminum in a 60/40 PBT/PET polyester blend. A blend was used because it can help with the formation of a segregated network of metal particles that allows electrical conductivity at low loading. The notched Izod impact of Al nano-spherical composites increased with nano Al content up to an addition level of 2 vol.%. However, the tensile strength and flexural strength decreased gradually with increasing filler loading. Thus, the spherical shape and nano size of the Al particle caused it to be less effective than the micron-sized, irregular-shaped Al powder, or the Al flakes. The reason for this is that, while nano spherical particles have high surface area for bonding with the matrix, the Al–Al aggregation stands in the way of wetting by the polymer melt, whereas aggregation in flakes does not cause as much of a problem. The segregated network structure to enhance electrical conductivity did not form in this blend system with nano spherical particles. The nano-spherical Al acted as a nucleating agent but did not cause transesterification between the two polyesters or make it more susceptible to degradation. Full article

(This article belongs to the Special Issue Mechanical Behavior of Polymeric Materials: Recent Trends and Advancements)

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16 pages, 3495 KiB

Open AccessArticle

Multicomponent Acrylic Formulation Design for Corrosion Casting with Controlled Mechanical Properties

by Pablo Reyes, Mariya Edeleva, Dagmar R. D’hooge, Ludwig Cardon and Pieter Cornillie

Polymers 2023, 15(15), 3236; https://doi.org/10.3390/polym15153236 - 29 Jul 2023

Viewed by 756

Abstract

Corrosion casting based on the curing of acrylic resins enables one to create casts as replicas of body systems, enhancing our knowledge of veterinary medicine. The identification of the optimal chemical formulations as well as the processing conditions, the delivery of good control [...] Read more.

Corrosion casting based on the curing of acrylic resins enables one to create casts as replicas of body systems, enhancing our knowledge of veterinary medicine. The identification of the optimal chemical formulations as well as the processing conditions, the delivery of good control during the liquid state and the excellent macroscopic properties during solidification and after use are remaining challenges. In the present work, based on the identification of more qualitative trends, it is demonstrated that multicomponent comonomer mixtures are interesting materials that can be used to expand the range of mechanical properties and can specifically result in a better balance between stiffness and flexibility while guaranteeing dimensional stability. Emphasis is put on a large pool of formulations in the testing phase to then perform a detailed mechanical flexural analysis for the most promising cases during a more rigorous testing phase, accounting for a new pragmatic protocol for the pot life. This protocol consists of a vial-based turning test and a measurement of the viscosity variation up to 1000 mPa∙s and highlights the complex interplay between the overall initial concentrations and the impact of the absence of mixing once the system is at rest. It is demonstrated that the use of only low-molar-mass crosslinkers should be avoided, and overall, an intermediate amount of crosslinkers is recommendable. Full article

(This article belongs to the Special Issue Mechanical Behavior of Polymeric Materials: Recent Trends and Advancements)

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21 pages, 8218 KiB

Open AccessArticle

The Effect of Mechanical Elongation on the Thermal Conductivity of Amorphous and Semicrystalline Thermoplastic Polyimides: Atomistic Simulations

by Victor M. Nazarychev and Sergey V. Lyulin

Polymers 2023, 15(13), 2926; https://doi.org/10.3390/polym15132926 - 01 Jul 2023

Cited by 1 | Viewed by 1226

Abstract

Over the past few decades, the enhancement of polymer thermal conductivity has attracted considerable attention in the scientific community due to its potential for the development of new thermal interface materials (TIM) for both electronic and electrical devices. The mechanical elongation of polymers [...] Read more.

Over the past few decades, the enhancement of polymer thermal conductivity has attracted considerable attention in the scientific community due to its potential for the development of new thermal interface materials (TIM) for both electronic and electrical devices. The mechanical elongation of polymers may be considered as an appropriate tool for the improvement of heat transport through polymers without the necessary addition of nanofillers. Polyimides (PIs) in particular have some of the best thermal, dielectric, and mechanical properties, as well as radiation and chemical resistance. They can therefore be used as polymer binders in TIM without compromising their dielectric properties. In the present study, the effects of uniaxial deformation on the thermal conductivity of thermoplastic PIs were examined for the first time using atomistic computer simulations. We believe that this approach will be important for the development of thermal interface materials based on thermoplastic PIs with improved thermal conductivity properties. Current research has focused on the analysis of three thermoplastic PIs: two semicrystalline, namely BPDA-P3 and R-BAPB; and one amorphous, ULTEM^TM. To evaluate the impact of uniaxial deformation on the thermal conductivity, samples of these PIs were deformed up to 200% at a temperature of 600 K, slightly above the melting temperatures of BPDA-P3 and R-BAPB. The thermal conductivity coefficients of these PIs increased in the glassy state and above the glass transition point. Notably, some improvement in the thermal conductivity of the amorphous polyimide ULTEM^TM was achieved. Our study demonstrates that the thermal conductivity coefficient is anisotropic in different directions with respect to the deformation axis and shows a significant increase in both semicrystalline and amorphous PIs in the direction parallel to the deformation. Both types of structural ordering (self-ordering of semicrystalline PI and mechanical elongation) led to the same significant increase in thermal conductivity coefficient. Full article

(This article belongs to the Special Issue Mechanical Behavior of Polymeric Materials: Recent Trends and Advancements)

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15 pages, 3685 KiB

Open AccessArticle

Influence of Molecular Weight on Thermal and Mechanical Properties of Carbon-Fiber-Reinforced Plastics Based on Thermoplastic Partially Crystalline Polyimide

by Gleb Vaganov, Maria Simonova, Margarita Romasheva, Andrey Didenko, Elena Popova, Elena Ivan’kova, Almaz Kamalov, Vladimir Elokhovskiy, Vyacheslav Vaganov, Alexander Filippov and Vladimir Yudin

Polymers 2023, 15(13), 2922; https://doi.org/10.3390/polym15132922 - 01 Jul 2023

Cited by 1 | Viewed by 1692

Abstract

For the first time, a study of the influence of the molecular weight of the thermoplastic partially crystalline polyimide R-BAPB on the thermophysical and mechanical properties of carbon plastics was presented. The molecular weight of polyimide was determined using the method of light [...] Read more.

For the first time, a study of the influence of the molecular weight of the thermoplastic partially crystalline polyimide R-BAPB on the thermophysical and mechanical properties of carbon plastics was presented. The molecular weight of polyimide was determined using the method of light scattering and the study of the intrinsic viscosity of polyamic acid solutions. To obtain CFRPs, the uniform distribution of polyimide powder on continuous carbon fibers via electrostatic spraying and further hot calendering and pressing were applied. The study of the structure of the obtained carbon plastics via scanning electron microscopy has shown that the growth of the molecular weight of polyimide prevents the impregnation of carbon fiber with the introduced polyimide. Moreover, an increase in the molecular weight of polyimide leads to a rise in glass transition and thermal decomposition temperatures up to 590 °C, while the degree of crystallinity of CFRP falls. Nonetheless, raising the molecular weight from 22,000 to 70,000 g/mol of a binder polymer improves the interlayer fracture toughness G_1C by more than five times. Full article

(This article belongs to the Special Issue Mechanical Behavior of Polymeric Materials: Recent Trends and Advancements)

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27 pages, 12422 KiB

Open AccessArticle

Tribo-Mechanical Investigation of Glass Fiber Reinforced Polymer Composites under Dry Conditions

by Corina Birleanu, Marius Pustan, Mircea Cioaza, Paul Bere, Glad Contiu, Mircea Cristian Dudescu and Daniel Filip

Polymers 2023, 15(12), 2733; https://doi.org/10.3390/polym15122733 - 19 Jun 2023

Cited by 4 | Viewed by 1527

Abstract

Tribo-mechanical experiments were performed on Glass Fiber Reinforced Polymer (GRFP) composites against different engineering materials, and the tribological behavior of these materials under dry conditions was investigated. The novelty of this study consists of the investigation of the tribomechanical properties of a customized [...] Read more.

Tribo-mechanical experiments were performed on Glass Fiber Reinforced Polymer (GRFP) composites against different engineering materials, and the tribological behavior of these materials under dry conditions was investigated. The novelty of this study consists of the investigation of the tribomechanical properties of a customized GFRP/epoxy composite, different from those identified in the literature. The investigated material in the work is composed of 270 g/m² fiberglass twill fabric/epoxy matrix. It was manufactured by the vacuum bag method and autoclave curing procedure. The goal was to define the tribo-mechanical characteristics of a 68.5% weight fraction ratio (wf) of GFRP composites in relation to the different categories of plastic materials, alloyed steel, and technical ceramics. The properties of the material, including ultimate tensile strength, Young’s modulus of elasticity, elastic strain, and impact strength of the GFPR, were determined through standard tests. The friction coefficients were obtained using a modified pin-on-disc tribometer using sliding speeds ranging from 0.1 to 0.36 m s⁻¹, load 20 N, and different counter face balls from Polytetrafluoroethylene (PTFE), Polyamide (Torlon), 52,100 Chrome Alloy Steel, 440 Stainless Steel, and Ceramic Al₂O₃, with 12.7 mm in diameter, in dry conditions. These are commonly used as ball and roller bearings in industry and for a variety of automotive applications. To evaluate the wear mechanisms, the worm surfaces were examined and investigated by a Nano Focus—Optical 3D Microscopy, which uses cutting-edge μsurf technology to provide highly accurate 3D measurements of surfaces. The obtained results constitute an important database for the tribo-mechanical behavior of this engineering GFRP composite material. Full article

(This article belongs to the Special Issue Mechanical Behavior of Polymeric Materials: Recent Trends and Advancements)

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27 pages, 6005 KiB

Open AccessArticle

VO-Notches Subjected to Tension–Torsion Loading: Experimental and Theoretical Fracture Study on Polymeric Samples

by Hossein Talebi, Mohsen Askari, Majid Reza Ayatollahi and Sergio Cicero

Polymers 2023, 15(11), 2454; https://doi.org/10.3390/polym15112454 - 25 May 2023

Cited by 1 | Viewed by 955

Abstract

In this research, the fracture behavior of brittle specimens weakened by V-shaped notches with end holes (VO-notches) is studied. First, an experimental investigation is conducted to evaluate the effect of VO-notches on fracture behavior. To this end, VO-notched samples of PMMA are made [...] Read more.

In this research, the fracture behavior of brittle specimens weakened by V-shaped notches with end holes (VO-notches) is studied. First, an experimental investigation is conducted to evaluate the effect of VO-notches on fracture behavior. To this end, VO-notched samples of PMMA are made and exposed to pure opening mode loading, pure tearing mode loading, and some combinations of these two loading types. As part of this study, samples with end-hole radii of 1, 2, and 4 mm are prepared to determine the effect of the notch end-hole size on the fracture resistance. Second, two well-known stress-based criteria, namely the maximum tangential stress (MTS) criterion and the mean stress (MS) criterion, are developed for VO-shaped notches subjected to mixed-mode I/III loading, also determining the associated fracture limit curves. A comparison between the theoretical and the experimental critical conditions indicates that the resulting VO-MTS and VO-MS criteria predict the fracture resistance of VO-notched samples with about 92% and 90% accuracy, respectively, confirming their capacity to estimate fracture conditions. Full article

(This article belongs to the Special Issue Mechanical Behavior of Polymeric Materials: Recent Trends and Advancements)

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