Chemical and Photoinduced Surface Modifications of Inorganic Nanoparticles and Their Applications

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Inorganic Materials and Metal-Organic Frameworks".

Deadline for manuscript submissions: closed (31 January 2023) | Viewed by 2405

Special Issue Editor


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Guest Editor
1. Department of Chemical, Materials and Production Engineering, University of Naples Federico II, P. le Tecchio 80, 80125 Naples, Italy
2. Center for Colloid and Surface Science (CSGI), Via della Lastruccia, 80100 Sesto Fiorentino, Italy
Interests: nanochemistry; colloids; amphiphiles; hybrid nanomaterials; functional biointerfaces; emulsions; EPR spectroscopy; neutron scattering
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Special Issue Information

Dear Colleagues,

The surface modification of inorganic nanoparticles is a motivating approach to tailor their bio-physicochemical and functional features. Many modification strategies (i.e., chemical and photochemical) are attracting a great deal of attention with the aim of realizing multifunctional nanomaterials with tunable size, morphology and surface composition, by coating with inorganic, organic or bioderived moieties.

This Special Issue will address topics concerning the chemical and photoinduced strategies capable of functionalizing the surface of inorganic nanoparticles, thus addressing their functionality for technological applications in various fields, such as nanomedicine, food packaging, optics and optoelectronic devices, semiconductor devices, textiles, cosmetics, agriculture, energy and catalysis.

Dr. Giuseppe Vitiello
Guest Editor

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Keywords

  • metals and metal oxide nanoparticles
  • nanostructured materials and interfaces
  • chemical conjugation
  • exchange ligand binding
  • photo-deposition
  • photo-oxidation and photo-reduction methods
  • functional groups
  • organic and photosensitizer ligands
  • amphiphiles and biomolecules

Published Papers (2 papers)

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Research

12 pages, 5710 KiB  
Article
The Low-Temperature Sol-Gel Synthesis of Metal-Oxide Films on Polymer Substrates and the Determination of Their Optical and Dielectric Properties
by Lyudmila Borilo, Vladimir Kozik, Alexander Vorozhtsov, Viktor Klimenko, Olga Khalipova, Alexander Agafonov, Tatiana Kusova, Anton Kraev and Yana Dubkova
Nanomaterials 2022, 12(23), 4333; https://doi.org/10.3390/nano12234333 - 06 Dec 2022
Viewed by 1240
Abstract
Photoactive, optically transparent heterostructures from silver nanowires and titanium dioxide were obtained by the sol-gel method on the surface of a polyethylene terephthalate film. The characteristics of optical transmission on the wavelength and those of dielectric permittivity, conductivity and dissipation on frequency in [...] Read more.
Photoactive, optically transparent heterostructures from silver nanowires and titanium dioxide were obtained by the sol-gel method on the surface of a polyethylene terephthalate film. The characteristics of optical transmission on the wavelength and those of dielectric permittivity, conductivity and dissipation on frequency in the range of 25–1,000,000 Hz were investigated. Full article
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16 pages, 3681 KiB  
Article
Manganese Dioxide Nanoparticles Prepared by Laser Ablation as Materials with Interesting Electronic, Electrochemical, and Disinfecting Properties in Both Colloidal Suspensions and Deposited on Fluorine-Doped Tin Oxide
by Jhonatan Corrales, Jorge Acosta, Sandra Castro, Henry Riascos, Efraim Serna-Galvis, Ricardo A. Torres-Palma and Yenny Ávila-Torres
Nanomaterials 2022, 12(22), 4061; https://doi.org/10.3390/nano12224061 - 18 Nov 2022
Cited by 1 | Viewed by 1613
Abstract
Nanoparticles (NPs) of α-MnO2 have high applicability in photoelectrochemical, heterogeneous photocatalysis, optical switching, and disinfection processes. To widen this panorama about MnO2 NPs, the formation of this material by laser ablation and deposition by dip-coating on fluorine-doped tin oxide (FTO), were [...] Read more.
Nanoparticles (NPs) of α-MnO2 have high applicability in photoelectrochemical, heterogeneous photocatalysis, optical switching, and disinfection processes. To widen this panorama about MnO2 NPs, the formation of this material by laser ablation and deposition by dip-coating on fluorine-doped tin oxide (FTO), were considered in this study. The optical, spectroscopic, electrochemical characterization, and the evaluation of the antimicrobial activity, plus the photocatalytic response, were measured herein in colloidal media and deposited. For the deposition of NPs on FTO sheet, an anode is produced with a pseudocapacitive behavior, and 2.82 eV of band gap (GAP) in comparison with colloidal NPs for a value of 3.84 eV. Both colloidal suspension and deposited NPs have intrinsic antibacterial activity against two representative microorganisms (E. coli and S. aureus), and this biological activity was significantly enhanced in the presence of UVA light, indicating photocatalytic activity of the material. Thus, both the colloidal suspension and deposited NPs can act as disinfecting agents themselves or via light activation. However, an antibacterial behavior different for E. coli and S. aureus was observed, in function of the aggregation state, obtaining total E. coli disinfection at 30 min for deposited samples on FTO. Full article
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