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Laser Spectroscopic Characterization of the Organic Chromophores

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Analytical Chemistry".

Deadline for manuscript submissions: closed (30 June 2023) | Viewed by 4903

Special Issue Editors


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Guest Editor
Faculty of Chemistry, Wrocław University of Science and Technology, Wroclaw, Poland
Interests: nonlinear optics; laser spectroscopy; light amplification studies; materials engineering; 3D printing for photonics; organic laser dyes; photochromic polymers; liquid crystals

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Guest Editor
Faculty of Chemistry, Advanced Materials Engineering and Modelling Group, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-320 Wrocław, Poland
Interests: laser spectroscopy; organic lasers; laser physics; laser processing; photonics of disordered systems; nonlinear optics and holography
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Special Issue Information

Dear Colleagues,

As we all know, laser spectroscopy has delivered new possibilities with the characterization of various materials, including optical and nonlinear optical (NLO) features. Since the very first laser was constructed, many new alternatives have been devised, with extraordinary experiments be performed in our labs. Starting from laser microscopy, and extending to various NLO effects (2nd or 3rd order), and finally considering all kinds of light amplification studies, it is obvious that lasers has revolutionized many fields of science (among others). From these reasons, I would like to cordially invite you to contribute to this Special Issue (SI) of the Molecules journal entitled: “Laser Spectroscopic Characterization of Organic Chromophores”. The SI is dedicated to both experimental and theoretical approaches considering laser light as the source for the investigated phenomena. Classical laser action has been already entirely described; however, during the last few decades, new types of lasing action have been observed. One such example is the random lasing (RL) phenomenon, where the effect is slightly different than the one previously mentioned. More than one laser mode is responsible for effective optical resonator forming. The RL effect can also be related to nanoparticles, or the presence of liquid crystals within active material, which opens new possibilities and features of modern-type lasing devices. All kinds of laser action starts from the efficient light amplification inside (or simply using) the optical resonators differently constructed. Moreover, any kind of new approaches toward laser devices architectures is also of interest in the current SI. Additionally, laser spectroscopic methods implemented to characterize new materials, especially organic chromophores, are invited. Finally, all kinds of experiments where a laser source is implemented and which can provide new insights into various phenomena, their mechanisms, or unknown materials perfectly fit into the present Molecules Special Issue, which it is my great pleasure to lead.

Dr. Adam Szukalski
Dr. Lech Sznitko
Guest Editors

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Molecules is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Laser spectroscopy 
  • Nonlinear optics 
  • Luminescent organic materials 
  • Lasing action 
  • Random lasing
  • Fluorescence

Published Papers (2 papers)

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Research

16 pages, 3546 KiB  
Article
Laser Spectroscopic Characterization for the Rapid Detection of Nutrients along with CN Molecular Emission Band in Plant-Biochar
by Tahani A. Alrebdi, Amir Fayyaz, Haroon Asghar, Samira Elaissi and Lamia Abu El Maati
Molecules 2022, 27(15), 5048; https://doi.org/10.3390/molecules27155048 - 08 Aug 2022
Cited by 10 | Viewed by 2062
Abstract
We report a quantitative analysis of various plant-biochar samples (S1, S2 and S3) by utilizing a laser-induced breakdown spectroscopy (LIBS) technique. For LIBS analysis, laser-induced microplasma was generated on the target surface by using a focused beam through a high-power Nd: YAG laser [...] Read more.
We report a quantitative analysis of various plant-biochar samples (S1, S2 and S3) by utilizing a laser-induced breakdown spectroscopy (LIBS) technique. For LIBS analysis, laser-induced microplasma was generated on the target surface by using a focused beam through a high-power Nd: YAG laser and optical emission spectra were recorded using a charged coupled device (CCD) array spectrometer, with wavelength ranges from 200 nm to 720 nm. The spectroscopical analysis showed the existence of various ingredients, including H, Li, Ca, Na, Al, Zn, Mg, Sr, Si, and Fe, along with a CN molecular emission band due to B2Σ+ − X2Σ+ electronic transition. By assuming conditions of the plasma is optically thin and in LTE, calibration-free laser-induced breakdown spectroscopy (CF-LIBS) was utilized for the compositional analysis of the ingredients present in the three plant-biochar samples. To lower the uncertainties, we used an average composition (%) of the three plant-biochar samples. The quantitative study of the plant-biochar samples was also achieved using the energy dispersive X-ray (EDX) technique, showing good agreement with the CF-LIBS technique. In addition, statistical analysis, such as principal component analysis (PCA), was performed for the clustering and classification of the three plant-biochar samples. The first three PCs explained an overall ~91% of the variation in LIBS spectral data, including PC1 (58.71%), PC2 (20.9%), and PC3 (11.4%). These findings suggest that LIBS is a robust tool for rapid measurement of heavy as well as light elements, such as H, Li, and nutritional metals in plant-biochar samples. Full article
(This article belongs to the Special Issue Laser Spectroscopic Characterization of the Organic Chromophores)
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15 pages, 3272 KiB  
Article
Investigation of the Optical Properties of a Novel Class of Quinoline Derivatives and Their Random Laser Properties Using ZnO Nanoparticles
by Abdulrahman I. Almansour, Natarajan Arumugam, Saradh Prasad, Raju Suresh Kumar, Mohamad S. Alsalhi, Manal Fahad Alkaltham and Haya bint Abdulaziz Al-Tamimi
Molecules 2022, 27(1), 145; https://doi.org/10.3390/molecules27010145 - 27 Dec 2021
Cited by 3 | Viewed by 2239
Abstract
Quinoline Schiff bases display potential applications in optoelectronics and laser fields because of their unique optical properties that arise from extensive delocalization of the electron cloud, and a high order of non-linearity. In this context, a new class of conjugated quinoline-derivative viz. [...] Read more.
Quinoline Schiff bases display potential applications in optoelectronics and laser fields because of their unique optical properties that arise from extensive delocalization of the electron cloud, and a high order of non-linearity. In this context, a new class of conjugated quinoline-derivative viz. N-(quinolin-3-ylmethylene)anilines were synthesized from 2-hydroxyquinoline-3-carbaldehyde in two good yielding steps. The ability of these imines to accept an electron from a donor is denoted by their electron acceptor number and sites, which is calculated using density functional theory (DFT). The optical properties such as FT-IR, Raman, UV-VIS, and EDS spectra were calculated using TD-DFT, which also provided the energy gap, HOMO-LUMO structure. The optical properties of the synthesized imino quinolines were experimentally studied using photoluminescence and absorption spectroscopy. The properties such as Stokes shift and quantum yield were calculated using experimental data. Furthermore, the compound bearing a methyl group on the aryl ring and ZnO nanoparticles (hydrothermally synthesized) were dissolved in toluene, and optically excited with a 355 nm nanosecond laser, which produced a random laser. Full article
(This article belongs to the Special Issue Laser Spectroscopic Characterization of the Organic Chromophores)
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