Adsorption of Cations and Anions on Mineral Surfaces

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Environmental Mineralogy and Biogeochemistry".

Deadline for manuscript submissions: closed (13 May 2023) | Viewed by 1258

Special Issue Editors


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Guest Editor
Department of Hydro & Electrometallurgy, CSIR-Institute of Minerals and Materials Technology, Bhubaneswar 751013, India
Interests: adsorption; hydrometallurgy; leaching; precipitation

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Guest Editor
Department of Chemical Engineering, Institute of Chemical Technology, Mumbai 400019, India
Interests: nanotechnology; chemical reaction engineering

Special Issue Information

Dear Colleagues,

The adsorption of cations and anions in natural geological minerals has many advantages, as they are plentifully available and have low cost, thus making the process economical. Non-geological materials such as secondaries are either waste materials or process residues which are cheaper and also available in large excess. The utilization of these materials in adsorption not only contributes to the adsorption process but also contributes to the recycling of the material, representing a green solution. Process residues in the course of plant processing acquire active sites by thermal treatment, chemical attack, or heavy-duty physical processing (e.g., grinding). These materials can also be used as adsorbents. Modification of minerals’ surfaces as well as synthetic minerals have found very specialized applications because of their specialized tailor-made modification and synthesis.

Heavy metal contamination in water reserves has created havoc in the last several decades. Organic pollutants, toxic substances, oils and greasy matter, fertilizers, etc. are released into water bodies and percolated to groundwater when discarded in landfills, directly or indirectly making water polluted and unfit for drinking and domestic uses. The removal of these pollutants is essential, and has drawn attention worldwide.

This Special Issue is projected to collect research related to cationic and anionic adsorption on mineral surfaces and aims to assemble in one frame in different specialized categories.

This Special Issue is organized into three sections:

Section 1: Adsorption of cations and anions in broad areas such as inorganic heavy and light metals, organic ions, biological waste or biomaterials (e.g., nucleic acids, amino acids, carbohydrates and derivatives) as well as the loading and release of drugs from medical and pharmaceutical waste, as well as ions released and taken up in different substrates in the agricultural and fertilizer sector. Comprehensive research on advances in the selective adsorption of inorganic and organic ions.

Section 2: Research on types of adsorbents, as well as the structural and textural properties of adsorbents (e.g., naturally occurring geological minerals); research on non-geological materials like acid/base/polymer-modified minerals, synthetic clays and minerals such as porous and layered clays, synthetic zeolite and geopolymers, waste secondaries and plant residues/foundry wastes.

Section 3: Computational simulation and modelling as well as kinetic modelling of adsorbent surface and adsorption mechanism, including first-principles calculation and surface science related to the mineral–solute interface.

The objective of this Special Issue is to collect recent research on a broad range of topics related to cationic and anionic adsorption on natural and synthetic mineral surfaces, including inorganic, organic, medical, agricultural, and fertilizer sectors, in one special forum.

Dr. Barsha Dash
Dr. Manishkumar D. Yadav
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Minerals is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2400 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • cationic and anionic adsorption of inorganic and organic ions, agriculture and fertilizer, medical and pharmaceutical sectors
  • selective adsorption, computational modelling and kinetics
  • natural and synthetic porous and layered clays, zeolite and geopolymers
  • non-geological materials like secondaries, plant residues, and acid/base/polymer-modified minerals as adsorbents
  • molecular modelling and simulation of adsorbent surfaces and adsorption mechanisms

Published Papers (1 paper)

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Research

13 pages, 3971 KiB  
Article
Effect of La Doping and Al Species on Bastnaesite Flotation: A Density Functional Theory Study
by Xiancheng Shao, Guoyuan Wu, Gongliang Jiang, Ye Wang, Shikun Pu, Yaozhong Lan and Dengbang Jiang
Minerals 2023, 13(4), 583; https://doi.org/10.3390/min13040583 - 21 Apr 2023
Cited by 1 | Viewed by 932
Abstract
The recovery of rare earth elements from ores is crucial because of their applications in modern technology. Bastnaesite (La/Ce(CO3)F) is typically found in deposits with other gangue minerals but can be purified by flotation. Accordingly, we investigated the interactions of the [...] Read more.
The recovery of rare earth elements from ores is crucial because of their applications in modern technology. Bastnaesite (La/Ce(CO3)F) is typically found in deposits with other gangue minerals but can be purified by flotation. Accordingly, we investigated the interactions of the collector nonyl hydroxamic acid (NHA) with bastnaesite using density functional theory (DFT) calculations. In addition, we replaced Ce sites on the bastnaesite (100) surface with La and investigated the effect on NHA adsorption. Finally, we examined the effects of co-present aluminum species, which are frequently used inhibitors for associated gangue minerals during bastnaesite flotation, on NHA adsorption and, thus, the flotation efficiency. We found that doping with La increased the strength of adsorption between NHA and the bastnaesite (100) surface. In addition, we found that Al(OH)3(s) was adsorbed more strongly than NHA. Consequently, when Al(OH)3(s) is present in the flotation pulp, it is preferentially adsorbed, which reduces the number of sites for NHA adsorption and its flotation efficiency. These findings suggest that La doping can enhance the recovery of bastnaesite and indicate that the presence of Al minerals should be minimized. Full article
(This article belongs to the Special Issue Adsorption of Cations and Anions on Mineral Surfaces)
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