Mineralization in Subduction Zone

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Mineral Deposits".

Deadline for manuscript submissions: closed (30 November 2023) | Viewed by 6970

Special Issue Editors


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Guest Editor
Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China
Interests: porphyry Cu-Mo deposits; W-Sn deposits; plate subduction; oxygen fugacity and mineralization
Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China
Interests: accessory minerals; LA-ICP-MS; IOCG; isotope geochemistry

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Guest Editor
Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China
Interests: element–isotope geochemical cycling during plate subduction

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Guest Editor
School of Resource Environment and Safety Engineering, University of South China, Hengyang 421009, China
Interests: subduction zone; W-Sn deposit; geochemistry; Tethyan evolution

Special Issue Information

Dear Colleagues,

Subduction zones are the most important areas of mineralization. Different types of ore deposits occur in these zones, and have different temporal and spatial distribution, controlled by the properties of ore-forming elements. The thermal state of the subduction zone, the fluid composition and oxygen fugacity at different subduction depths, and the type of subducted sediments all affect the process and type of mineralization. The purpose of this Special Issue is to provide a platform for discussing the most recent developments in deposit exploration as well as mineralization processes and mechanisms in subduction zones. High-quality papers on creative views, novel methods, and practical applications are welcomed. This Special Issue is focused on relevant topics, including but not limited to: (1) high-precision geochronology of ore deposits; (2) application of new geochemical methods to the study of ore deposits; (3) progress in the application of accessory minerals in the study of ore deposits; and (4) deposit exploration in subduction zones.

Dr. Lipeng Zhang
Dr. Saijun Sun
Dr. Jianghong Deng
Dr. Qinglin Sui
Guest Editors

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Keywords

  • plate subduction
  • oxygen fugacity
  • accessory minerals
  • geochemistry and geochronology
  • mineralization
  • subduction zone

Published Papers (6 papers)

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Research

20 pages, 5258 KiB  
Article
Geochronology and Geochemistry of Cretaceous Adakitic Rocks of the Dongguashan Cu Deposit in the Lower Yangtze River Belt: Insights into Petrogenesis and Mineralization
by Zanzan Zhang, Xiaoyan Jiang, Jia Guo and Kenan Jiang
Minerals 2023, 13(7), 953; https://doi.org/10.3390/min13070953 - 17 Jul 2023
Viewed by 853
Abstract
The Lower Yangtze River Belt (LYRB) is a well-known and important base area with regard to Cu polymetallic resources in China. Large Cu polymetallic deposits in the LYRB are strongly associated with Cretaceous adakitic rocks. However, the petrogenesis of the Early Cretaceous adakites [...] Read more.
The Lower Yangtze River Belt (LYRB) is a well-known and important base area with regard to Cu polymetallic resources in China. Large Cu polymetallic deposits in the LYRB are strongly associated with Cretaceous adakitic rocks. However, the petrogenesis of the Early Cretaceous adakites and the temporal–genetic relationship with mineralization are still disputable. The Dongguashan (DGS) Cu polymetallic deposit in the Tongling ore cluster is one of the largest Cu deposits in the LYRB. The DGS intrusion mainly comprises quartz monzodiorite, with SiO2 contents varying from 63.7 to 67.9 wt%. Zircons from the quartz monzonite yield a SIMS U-Pb age of 138.9 ± 1.8 Ma, which indicates that the Cretaceous magmatism is coeval with mineralization. The studied rocks show typical geochemical signatures of adakites, characterized by high Al2O3 (14.9–16.2 wt%) and Sr (800–910 ppm) and low Y (15.2–17.5 ppm) and Yb (1.37–1.52 ppm) contents, with consequently high Sr/Y (46–61) and (La/Yb)N (14.8–18.5) ratios. The zircon δ18O values of the DGS adakites range from 5.7‰ to 7.3‰, indicating a heterogeneous source. Whole-rock Sr-Nd isotopic compositions show an enriched character, with ISr ratios from 0.70783 to 0.70794 and εNd(t) values around −11.0, which fall intermediately in the area of MORB (mid-ocean ridge basalt), marine sediment, and the ancient lower crust. Comprehensively, whole-rock geochemical compositions and isotopic values suggest that the adakites are generated from the partial melting of the subducted oceanic crust and possibly with the involvement of sedimentary materials derived from the slab or continental crust. Moreover, the bulk-rock high-Cu composition, and the physical–chemical conditions (high oxygen fugacity and high volatile contents) revealed by apatites, plays critical roles in the formation of Cu mineralization in the DGS Tongling ore cluster, LYRB. Full article
(This article belongs to the Special Issue Mineralization in Subduction Zone)
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19 pages, 16908 KiB  
Article
Petrogenesis and Geodynamic Implications of the North Kudi Granitoids in the West Kunlun Orogen, NW China
by Kai Wu, Meijun Gong, Xiaoyan Jiang, Mingxing Ling and Honglin Yuan
Minerals 2023, 13(7), 941; https://doi.org/10.3390/min13070941 - 14 Jul 2023
Cited by 1 | Viewed by 811
Abstract
The petrogenesis of aluminous A-type granites is a contentious subject. Here, we focused on the North Kudi pluton in the Western Kunlun orogen to investigate the origin and magmatic processes responsible for generating A-type granites. Samples from the North Kudi pluton are metaluminous [...] Read more.
The petrogenesis of aluminous A-type granites is a contentious subject. Here, we focused on the North Kudi pluton in the Western Kunlun orogen to investigate the origin and magmatic processes responsible for generating A-type granites. Samples from the North Kudi pluton are metaluminous to weakly peraluminous. K-feldspar granite samples are characterized by high alkali and Cl contents, high HFSE concentrations and FeO/MgO, low F content, negative Ba, Sr, P, Eu, and Ti anomalies, and high magma temperature (>903 °C), showing affinity to aluminous A-type granites. However, their 10,000 × Ga/Al ratios (1.86–3.18) are relatively lower than typical A-type granites. Quartz-monzonite displays similar Sr–Nd isotopic compositions and Ga/Al ratios with the K-feldspar granite but less pronounced negative Sr, P, and Ti anomalies and no discernable negative Ba and Eu anomalies. Fractional crystallization of alkali-rich, Cl-rich, and F-poor magmas can generate some typical geochemical characteristics of A-type granites (e.g., negative Ba, Sr, P, and Eu anomalies) but has little influence on Ga/Al ratios. The enriched Sr–Nd isotopic compositions, high Cl and alkali contents, arc-like geochemical features, and the involvement of slab-derived components, as indicated by high zircon Ce4+/Ce3+ (up to 503), suggest that the North Kudi pluton was possibly derived from partial melting of the metasomatized lithospheric mantle in the time of asthenosphere upwelling during the post-collisional stage. The emplacement of the North Kudi pluton thus indicates the onset of the post-orogenic stage in the Western Kunlun orogen. Full article
(This article belongs to the Special Issue Mineralization in Subduction Zone)
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16 pages, 10069 KiB  
Article
Petrogenesis of Syn-Collisional Adakitic Granitoids and Their Copper Mineralization Potential in the North Qilian Suture Zone
by Yuxiao Chen, Tianqi Zhang, Ying Cui and Shuguang Song
Minerals 2023, 13(7), 892; https://doi.org/10.3390/min13070892 - 30 Jun 2023
Cited by 1 | Viewed by 867
Abstract
The petrogenesis of late Ordovician–early Silurian adakitic plutons in the North Qilian suture zone (NQSZ) and their copper mineralization potential remain poorly understood. Here we present a detailed study of the Heishishan (HSS) granodiorite–granite pluton, spatially associated with Cu–Au mineralization in the eastern [...] Read more.
The petrogenesis of late Ordovician–early Silurian adakitic plutons in the North Qilian suture zone (NQSZ) and their copper mineralization potential remain poorly understood. Here we present a detailed study of the Heishishan (HSS) granodiorite–granite pluton, spatially associated with Cu–Au mineralization in the eastern section of the NQSZ. Zircon U–Pb dating confirms that the granodiorite–granite were formed at ca. 438–435 Ma, in association with a continental collision. Geochemically, the granitoids resemble low-Mg adakitic rocks featured by elevated Sr/Y and (La/Yb)N ratios with depleted MgO, Cr, and Ni concentrations, suggesting minimal mantle contribution. They are sodium rich with K2O/Na2O < 1, and have higher and more varied Sr/Y, but lower La/Yb than those from the continental lower crust. The εHf(t) values of zircon grains are positive and vary in a wide range of +2.0–12.7, indicating a heterogeneous source rather than a single arc basaltic source. They show moderately radiogenic Sr and Nd isotope compositions with initial 87Sr/86Sr ratios of 0.705101–0.706312 and εNd(t) values of +0.5–1.0, most likely a mixed source of the oceanic basaltic crust plus ca. 15–20% overlying sediments. The magmatic oxygen fugacity was relatively low as indicated by zircon Ce(IV)/Ce(III) ratios of 32–156, which is unfavorable for a large copper mineralization. Full article
(This article belongs to the Special Issue Mineralization in Subduction Zone)
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23 pages, 5993 KiB  
Article
Geochronology and Petrogenesis of the Early Paleozoic Jilongjie Granites in the Central South China Block: Implication for Post-Kinematic Lithospheric Delamination
by Haiyang He, Tingting Wang, Qinglin Sui, Xianzhe Duan, Xuan Ren, Danping Hou, Yanshi Xie, Shan Liu, Peng Feng, Huanbao Zhang and Liang Chen
Minerals 2023, 13(6), 734; https://doi.org/10.3390/min13060734 - 29 May 2023
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Abstract
Controversy over the geodynamic interpretation of the early Paleozoic granites in the South China Block constrains understanding of tectonic–magmatic evolution. In this paper, we present zircon U-Pb age, Hf isotope, and major and trace element data of the early Paleozoic granites in the [...] Read more.
Controversy over the geodynamic interpretation of the early Paleozoic granites in the South China Block constrains understanding of tectonic–magmatic evolution. In this paper, we present zircon U-Pb age, Hf isotope, and major and trace element data of the early Paleozoic granites in the Jilongjie region, south-central Hunan Province. A sample that yielded a weighted average 206Pb/238U age of 425 ± 3 Ma falls into the post-collisional granite field in the classification discriminant of magmatic rocks. Geochemical features indicate that the Jilongjie pluton is a shoshonitic metaluminous rock. The Jilongjie pluton’s chondrite-normalized rare earth element patterns exhibit a slight enrichment of light rare earth elements (LREEs) relative to heavy rare earth elements (HREEs) with (La/Yb)N ratios of 15.1–23.7 and weak Eu anomalies (Eu/Eu* = 0.68–0.78). Zircon Hf isotope results show εHf(t) ranging from −9.94 to −0.69. Jilongjie granite’s parent magma originated from a mixing of crust-derived felsic and mantle-derived mafic magmas, which then underwent fractional crystallization during its ascent. Jilongjie granite was generated through a post-collisional extensional setting associated with delamination of the thickened lithosphere. Full article
(This article belongs to the Special Issue Mineralization in Subduction Zone)
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17 pages, 9100 KiB  
Article
Petrogenesis of Shihuiyao Rare-Metal Granites in the Southern Great Xing’an Range, NE China
by Deyou Sun, Shicheng Wang, Jun Gou, Duo Zhang, Changzhou Deng, Dongguang Yang and Li Tian
Minerals 2023, 13(5), 701; https://doi.org/10.3390/min13050701 - 21 May 2023
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Abstract
Shihuiyao Rb–Nb–Ta-rich granites from the Late Jurassic period are newly discovered rare-metal-bearing granites found in the southern Great Xing’an Range, NE China. Further research of these granites may contribute to better understanding the petrogenesis of rare-metal granites and their associated mineralization mechanisms. The [...] Read more.
Shihuiyao Rb–Nb–Ta-rich granites from the Late Jurassic period are newly discovered rare-metal-bearing granites found in the southern Great Xing’an Range, NE China. Further research of these granites may contribute to better understanding the petrogenesis of rare-metal granites and their associated mineralization mechanisms. The granites are high-silica (SiO2 = 73.66–77.08 wt%), alkali-rich (K2O + Na2O = 8.18–9.49 wt%) and weakly to mildly peraluminous with A/CNK values (molar ratios of Al2O3/(CaO + Na2O + K2O)) ranging from 1.06 to 1.16. High differentiation indexes (DI = 95–97) and low P2O5 contents demonstrate that Shihuiyao rocks are low-P and peraluminous rare-metal granites. Mineral chemistry and whole-rock geochemistry can be used to obtain the following lithological sequence: zinnwaldite granite, muscovite–zinnwaldite granite, amazonite-bearing granite and amazonite pegmatite. The effect of the rare-earth element tetrad; low K/Rb (18.98–32.82), Nb/Ta (2.41–4.64) and Zr/Hf (5.99–8.80) ratios; and the occurrence of snowball-textured quartz suggest that extreme magmatic fractionation might be the key factor that causes Rb–Nb–Ta enrichment. Full article
(This article belongs to the Special Issue Mineralization in Subduction Zone)
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20 pages, 5984 KiB  
Article
Comparison of Granites from the Eastern and Western Districts of the Gejiu Ore District in South China: Implication for Petrogenesis and Tin Metallogeny
by Saijun Sun, Junjie Zhang, Shuang Li, Haobin Niu, Zhaojian Wu and Weidong Sun
Minerals 2023, 13(5), 691; https://doi.org/10.3390/min13050691 - 19 May 2023
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Abstract
Late Cretaceous granitoids are developed in the eastern and western districts of the Gejiu ore district, but tin deposits mainly occur in the eastern district, and the reasons for the difference in mineralization between the eastern and western districts are still controversial. Considering [...] Read more.
Late Cretaceous granitoids are developed in the eastern and western districts of the Gejiu ore district, but tin deposits mainly occur in the eastern district, and the reasons for the difference in mineralization between the eastern and western districts are still controversial. Considering the main factors controlling granite Sn fertility, the whole-rock geochemical characteristics of granites on both sides are compared. LA-ICP-MS zircon U-Pb analyses of the Gejiu granites yielded two age periods: the early phase from 79.2 to 83.3 Ma and the later phase from 73.8 to 75.6 Ma. The western district granites have higher zircon εHf(t), CaO/Na2O, Ba, and Sr concentrations and lower Rb/Sr ratios than the eastern district granites, indicating that the western district granites have more mantle-derived materials in the source than the eastern district granites. Results of oxygen fugacity show that the western granites have a higher oxygen fugacity condition. More depleted Ba, Sr, P, Eu and Ti characteristics with obviously negative Eu anomalies in the eastern granites also have high Rb/Sr ratios and low Nb/Ta and Zr/Hf ratios, indicating that the eastern granites experienced highly magmatic differentiation, attributed to high volatile F contents that can reduce the viscosity and solidus of magma. Combined with the differences in field observations and structural styles, on the whole, the western district granites have higher oxygen fugacities and lower F contents and magmatic differentiation than those in the eastern district granites, indicating that the western district granites are not conducive to mineralization. Full article
(This article belongs to the Special Issue Mineralization in Subduction Zone)
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