Enhancing Separation Performance of Mixed Matrix Membranes

A special issue of Membranes (ISSN 2077-0375). This special issue belongs to the section "Membrane Applications".

Deadline for manuscript submissions: closed (5 August 2022) | Viewed by 2515

Special Issue Editor


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Guest Editor
Chemical & Environmental Engineering Department, Nanoscience and Materials Institute of Aragon (INMA), Universidad de Zaragoza-CSIC, Mariano Esquillor s/n., 50018 Zaragoza, Spain
Interests: mixed matrix membranes; polymer membranes; metal organic frameworks; zeolitic imidazolate frameworks; synthesis and characterization; gas separation; CO2 capture; chemical looping combustion

Special Issue Information

Dear Colleagues,

In the last century, energy consumption (mainly from fossil fuels) has experienced a rise 20 times greater than the growth of the world’s population. It is estimated that energy demand will grow 30% by 2040, moving away from complying with the Paris Agreement.

Many international organizations agree that the atmospheric CO2 is reaching very high levels; reducing these emissions to fight climate change is a matter of urgency. To accomplish this, a combination of solutions dealing with the technological development of CO2 capture and storage (CCS) is required. Membrane technology, which has seen an extensive level of research and development, plays an important role in this. Even though polymeric membranes have been commercialized, there are certain limitations restricting their cost-effective implementation, with the research advances of hybrid membranes or mixed-matrix membranes (MMMs) gaining special attention in the field of membrane technology.

This Special Issue of Membranes aims to provide an overview of the latest challenges in the MMM embedding of novel functional porous materials such as zeolites, graphene derivatives, MOF, COF, etc.. It could be possible to control membranes’ surface chemistry and textural properties to improve their separation ability while maintaining a good polymer integration. This issue covers the latest advances in MMM technology in academia, aiming at their large-scale industrial implementation. Some of the topics discussed include strategies to improve filler–polymer compatibility, dense flat-sheet or supported hollow fiber membrane configurations with special inputs in the preparation of thin-film composites, and the separation of mixtures under realistic industrial conditions (feed composition, pressure, temperature, etc.). Applications are focused on pre- and post-combustion CO2 capture but are not limited to other gas- (hydrogen purification, the separation of volatile organic compounds, hydrocarbon separations, etc.) or liquid-phase separations (pervaporation, organic solvent nanofiltration, etc.). Both original research articles and reviews are welcome.

Dr. Beatriz Zornoza
Guest Editor

Manuscript Submission Information

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Keywords

  • mixed-matrix membranes
  • membrane characterization
  • membrane fabrication
  • advanced nanostructured materials
  • filler-polymer compatibility
  • flat-sheet membrane
  • hollow-fiber membrane
  • thin-film composite
  • gas separation
  • CO2 capture

Published Papers (1 paper)

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Research

14 pages, 3854 KiB  
Article
Cross-Linked Polyimide/ZIF-8 Mixed-Matrix Membranes by In Situ Formation of ZIF-8: Effect of Cross-Linking on Their Propylene/Propane Separation
by Sunghwan Park and Hae-Kwon Jeong
Membranes 2022, 12(10), 964; https://doi.org/10.3390/membranes12100964 - 01 Oct 2022
Cited by 3 | Viewed by 2182
Abstract
Despite their potential for the scalable production of mixed-matrix membranes (MMMs), the MMMs prepared by the polymer-modification-enabled in situ metal–organic framework formation (PMMOF) process showed a considerable reduction in gas permeability as the filler loading increased. It was hypothesized that a correlation existed [...] Read more.
Despite their potential for the scalable production of mixed-matrix membranes (MMMs), the MMMs prepared by the polymer-modification-enabled in situ metal–organic framework formation (PMMOF) process showed a considerable reduction in gas permeability as the filler loading increased. It was hypothesized that a correlation existed between the decrease in permeability and the change in the properties of the polymer, such as free volume and chain flexibility, upon in situ MOF formation. Herein, we aim to address the permeability reduction by using a cross-linked polyimide (6FDA-DAM:DABA (3:2)). It was found the degree of cross-linking affected not only the properties of the polymer, but also the in situ formation of the ZIF-8 filler particles in the cross-linked polymer. The proper degree of cross-linking resulted in suppressing C3H6 permeability reduction, suggesting a possible strategy to overcome the issue of PMMOF. The swelling of the polymer followed by chain rearrangement during the PMMOF, as well as the structural rigidity of the polymer, were found to be critical in mitigating permeability reduction. Full article
(This article belongs to the Special Issue Enhancing Separation Performance of Mixed Matrix Membranes)
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