Special Issue "Functional Nanocomposite Membranes"

A special issue of Membranes (ISSN 2077-0375). This special issue belongs to the section "Membrane Physics and Theory".

Deadline for manuscript submissions: closed (15 October 2023) | Viewed by 769

Special Issue Editors

Dr. Alexey Grekhov
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Guest Editor
Molecular Physics Department, National Research Nuclear University Moscow Engineering Physics Institute, Kashirskoe Highway 31, 119991 Moscow, Russia
Interests: nanotubes; nanomaterials and nanotechnology; priinciples of membrane gas separation
A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky Prospect 29, 119991 Moscow, Russia
Interests: membrane design; membrane fabrication; membrane-based separation processes; high-throughput techniques; industry oriented applications
Special Issues, Collections and Topics in MDPI journals
Dr. Yury Eremin
E-Mail Website
Guest Editor
Molecular Physics Department, National Research Nuclear University Moscow Engineering Physics Institute, Kashirskoe Highway 31, 119991 Moscow, Russia
Interests: nanocomposite membranes; nanomaterials and nanotechnology; carbon nanotube

Special Issue Information

Dear Colleagues,

The development of functional nanocomposite membranes is one of the promising areas of modification of membrane materials for solving unique problems of gas and liquid separation and purification in petrochemistry, medicine, food production, the processing of household and industrial waste, etc. Currently, a fairly large quantity of experimental data has been collected on the unique transport and separation properties of polymer membranes with embedded particles or agglomerates of nanometer size. At the same time, most of the results are explicable within the framework of existing models and the change in properties correlates with the properties and the amount of the embedded phase.

However, there are membrane materials in which nonlinear changes in properties are observed and which cannot be explained consistently within the framework of existing approaches (for example, Maxwell's models, Kahn–Jones–Nair, etc.). The study of such nonlinear threshold phenomena allows us to obtain answers to fundamental questions about the mechanisms of transport in inhomogeneous, disordered media.

Some progress in this field of research has been achieved thanks to applying percolation and fractal approaches to the description of such structures (for example, the Shen and Kripatrick models, etc.). However, some successful publications do not give a complete picture of the causes of such deviations. The purpose of this Special Issue is to publish modern experimental results and models of anomalous effects during separation in nanocomposite membranes. In particular, we are interested in studies in which the influence of anisotropic effects, dimensional and threshold changes in properties, the nonlinear sensitivity of systems, and hysteresis phenomena are studied.

These publications will allow us to assess the limits of applicability and possible development of the direction for the creation of new functional nanocomposite membranes.

Dr. Alexey Grekhov
Dr. Alexey Volkov
Dr. Yury Eremin
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Membranes is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • percolation structures
  • nonlinear effects
  • synergetic effect
  • nanostructures
  • topologically inhomogeneous structures
  • nonlinear effects
  • low-dimensional systems
  • nonlinear transport properties
  • separation of liquids and gases
  • diffusion in inhomogeneous media

Published Papers (1 paper)

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Research

14 pages, 2438 KiB  
Article
Dimensional Transformation of Percolation Structure in Mixed-Matrix Membranes (MMMs)
Membranes 2023, 13(9), 798; https://doi.org/10.3390/membranes13090798 - 16 Sep 2023
Viewed by 561
Abstract
A large number of studies of mixed-matrix membranes (MMMs) have confirmed the possibility of obtaining new materials with unique transport properties, including for solving specific problems in the separation of mixtures of liquids and gases. The choice of particles with a given affinity [...] Read more.
A large number of studies of mixed-matrix membranes (MMMs) have confirmed the possibility of obtaining new materials with unique transport properties, including for solving specific problems in the separation of mixtures of liquids and gases. The choice of particles with a given affinity for the matrix and separable components allows researchers to adjust the selective properties of MMMs in a wide range, which changes the properties of MMMs in a wide range. However, even within the framework of the most complex percolation mechanism of the formation of the MMM structure, it is possible to explain only some of the observed effects. In particular, questions about the required particle concentration and fluctuation of properties in various MMM samples are still the subject of research. The results of the numerical modeling of such structures presented in this paper determined the possible causes of the observed deviations of the experimental results, for example, particle size dispersion, agglomeration, and interaction with the matrix. According to our research, the key factor that qualitatively changes the parameters of percolation structures is the ratio of the geometric dimensions of the system. We have confirmed in a wide range a significant change in the conditions of cluster formation and its power at different particle diameters and lengths (traditional parameters in percolation studies). But in our work, we additionally studied the effect on the cluster parameters of the interfacial layer and the anisotropy of the matrix (the transition from the cube to the film). The results obtained show that changing the parameters of the matrix–particle interaction affects agglomeration, and the degradation of the percolation structure is possible. That is, with an increase in concentration, the parameters of the percolation cluster, its power, and the probability of formation, may decrease. But even more negative changes in percolation structures are observed during the transition from a volumetric matrix to films. The anisotropy of space leads to the formation of percolation through the film in certain areas at low concentrations of particles. At the same time, in a significant part of the matrix, percolation between the film surfaces will be absent, and the effect of changing the properties of MMMs in the matrix as a whole decreases. Our study explains the observed instability of MMM properties at fixed concentrations and parameters of embedded particles, including the effect of reducing the influence of particles with increasing concentration. Full article
(This article belongs to the Special Issue Functional Nanocomposite Membranes)
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