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High-Stability and Efficient Perovskite Solar Cells

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Energy Materials".

Deadline for manuscript submissions: closed (20 January 2024) | Viewed by 783

Special Issue Editor


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Guest Editor
École Polytechnique Fédérale de Lausanne, Lausanne, Switzerland
Interests: perovskite solar cells; organic and inorganic semiconductor materials

Special Issue Information

Dear Colleagues,

The popularly applied perovskite films are polycrystalline; therefore, trap states at the grain boundaries are still present, becoming one of the significant obstacles that hamper further improvement. These shallow defects at the grain boundary can scatter the carriers during their diffusion. Simultaneously, heterogeneous contact with the corresponding buffer layers (hole transport layer and electron transport layer) can lead to distortion of the interfacial crystal structure owing to the large lattice mismatch, which always produces deep trap states and decreases the output voltage severely. Therefore, in order to improve the performance and stability of devices, appropriate strategies and compounds need to be applied to overcome these defects, including grain boundary passivation compounds, upper and lower interface passivation compounds for perovskite layers, low-doped or no-doped hole transport materials, polymer hole transport layer materials, low photocatalytic activity electron transport layer materials, and so on.

Dr. Yi Zhang
Guest Editor

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Keywords

  • perovskite solar cells
  • high efficiency
  • high stability
  • passivation material
  • hole transport material
  • electron transport material

Published Papers (1 paper)

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Research

10 pages, 3410 KiB  
Article
Improved Thermal and Electrical Properties of P-I-N-Structured Perovskite Solar Cells Using ZnO-Added PCBM as Electron Transport Layer
by Younghun Jeong, Dongwoon Han, Seongtak Kim and Chan Bin Mo
Materials 2024, 17(6), 1376; https://doi.org/10.3390/ma17061376 - 17 Mar 2024
Viewed by 598
Abstract
Not only can perovskite solar cells be exposed to high temperatures, up to 80 °C, depending on the operating environment, but absorbed energy is lost as heat, so it is important to have thermal stability for commercialization. However, in the case of the [...] Read more.
Not only can perovskite solar cells be exposed to high temperatures, up to 80 °C, depending on the operating environment, but absorbed energy is lost as heat, so it is important to have thermal stability for commercialization. However, in the case of the recently reported p-i-n structure solar cell, most of the electron and hole transport layers are composed of organic materials vulnerable to heat transfer, so the light absorption layer may be continuously exposed to high temperatures when the solar cell is operated. In this study, we attempted to improve the thermal conductivity of the electron transport layer using phenyl-C61-butyric acid methyl ester (PCBM) containing zinc oxide (ZnO). As a result, the thermal conductivity was improved by more than 7.4% and 23.5% by adding 6.57vol% and 22.38vol% of ZnO to PCBM, respectively. In addition, the insertion of ZnO resulted in changes in the electron transport behavior and energy level of the electron transport layer. As a result, it was confirmed that not only could the temperature stability of the perovskite thin film be improved, but the efficiency of the solar cell could also be improved from 14.12% to 17.97%. Full article
(This article belongs to the Special Issue High-Stability and Efficient Perovskite Solar Cells)
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