Special Issue "Perovskites – New and Old Materials"

A special issue of Crystals (ISSN 2073-4352). This special issue belongs to the section "Materials for Energy Applications".

Deadline for manuscript submissions: closed (30 November 2023) | Viewed by 3162

Special Issue Editors

Department of Physics, Faculty of Mechanical Engineering and Mechatronics, West Pomeranian University of Technology, Al. Piastów 17, 70-310 Szczecin, Poland
Interests: solid state physics; EPR (electron paramagnetic resonance); magnetic properties of solids and magnetic measurements (SQUID); optical; infrared and XRD spectroscopy; crystallography
Special Issues, Collections and Topics in MDPI journals
Department of Technical Physics, Faculty of Mechanical Engineering and Mechatronics, West Pomeranian University of Technology, Al. Piastów 17, 70-310 Szczecin, Poland
Interests: laser diodes; scintillators; solid and nanoparticles materials characterization; EPR investigations, magnetic properties
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Perovskites are one of the best-known compounds. Research on them has been going on for almost two hundred years. Lew Perovski (1792 - 1852) is a Russian mineralogist whose study of the crystal structure of calcium titanium oxide (CaTiO3) gave the name to the class of compounds with the same crystal structure (ABX3), known as the perovskite structure. We are currently seeing a great resurgence in the study of perovskites, both for cognitive and application reasons. LiNbO3 is frequently investigated owing to its good electrooptic and acousto-optic properties. Similarly, the same as LiNbO3, LiTaO3 can also be widely used as a surface acoustic wave substrate, electro-optic modulator and second harmonic generation material. The power of perovskites lies in their structure. Conventional oxide perovskites are cubic. Hexagonal oxide perovskites, e.g., SrIrO3, are especially relevant due to their significance as quantum materials.

A new and great example of the significant applications of perovskites is their ability to convert solar energy into electricity. Perovskite solar sells could be the future of this kind energy. They are cheap cost, highly efficient, thin, lightweight and flexible since they can be printed by inks, and an interesting alternative to traditional silicon solar panels. They can be used as a thin film laid on glass or plastic. Perovskite solar cells convert sunlight into electricity around 50 % more efficiently than silicon cells. Ink jet printing and roll-to-roll methods can be used to produce the solar cells. Perovskites have reached about 30 % efficiency in lab tests. A perovskite–silicon combination might even achieve a 45 % efficiency, more than double that of today’s silicon panels.

The subject of this Special Issue is perovskites, presenting results from the latest research on their structural, physical, optical, magnetic, and other properties, as well as computer simulation and theoretical studies. It also covers perovskites as crystals, powders, and thin films, pure and doped. The properties of perovskites are the key to their future applications.

Prof. Dr. Tomasz Bodziony
Prof. Dr. SŁawomir Kaczmarek
Guest Editors

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Keywords

  • perovskites
  • nanomaterials
  • optical materials
  • quantum materials
  • lasers
  • waveguides
  • electro-optic modulators
  • solar cells
  • energy converters. 

Published Papers (2 papers)

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Research

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8 pages, 1089 KiB  
Communication
Evaluation of the Minority-Carrier Lifetime of IMM3J Solar Cells under Proton Irradiation Based on Electroluminescence
Crystals 2023, 13(2), 297; https://doi.org/10.3390/cryst13020297 - 10 Feb 2023
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Abstract
The shortening of the minority carrier lifetime is the main reason for the degradation of the electrical performance of solar cells; therefore, it is particularly important to evaluate the minority carrier lifetime of inverted metamorphic triple junction (IMM3J) GaInP/GaAs/InGaAs solar cells. We evaluate [...] Read more.
The shortening of the minority carrier lifetime is the main reason for the degradation of the electrical performance of solar cells; therefore, it is particularly important to evaluate the minority carrier lifetime of inverted metamorphic triple junction (IMM3J) GaInP/GaAs/InGaAs solar cells. We evaluate the minority carrier lifetime of each subcell of IMM3J solar cells before and after 2 MeV proton irradiation by the electroluminescence (EL) method. Before proton irradiation, the minority carrier lifetimes of the GaInP, GaAs, and InGaAs subcells were 6.99 × 10−9 s, 3.09 × 10−8 s, and 2.31 × 10−8 s, respectively. After proton irradiation, the minority carrier lifetime of GaInP, GaAs, and InGaAs subcells degraded significantly. When the proton fluence was 2 × 1012 cm−2, the minority carrier lifetimes of the GaInP, GaAs, and InGaAs subcells degraded to 1.63 × 10−10 s, 1.56 × 10−11 s, and 1.65 × 10−10 s, respectively. These results provide a reference for predicting the degradation of the short-circuit current and open-circuit voltage of each subcell. Full article
(This article belongs to the Special Issue Perovskites – New and Old Materials)
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Review

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15 pages, 5606 KiB  
Review
All Inorganic Lead-Free Zero-Dimensional Metal Halide Luminescent Materials and Applications
Crystals 2023, 13(3), 499; https://doi.org/10.3390/cryst13030499 - 14 Mar 2023
Cited by 1 | Viewed by 1674
Abstract
Recently, zero-dimensional luminescent material has attracted researchers because of its optical properties, which is a possible candidate to replace lead halide perovskite. This review focused on the recent development of tetrahedrally and octahedrally coordinated inorganic halide semiconductor luminescent materials. We discuss the synthesis [...] Read more.
Recently, zero-dimensional luminescent material has attracted researchers because of its optical properties, which is a possible candidate to replace lead halide perovskite. This review focused on the recent development of tetrahedrally and octahedrally coordinated inorganic halide semiconductor luminescent materials. We discuss the synthesis methods and crystal structures of these materials in this review. The materials are categorized based on the valence of central metal cations (monovalent, divalent, and trivalent). Finally, we have summarized the applications of these luminescent materials, such as light-emitting diodes, ultrafast switching memories, photodetectors, and scintillators. This review article provides an overview of recent progress on zero-dimensional materials and their applications for further development in the future. Full article
(This article belongs to the Special Issue Perovskites – New and Old Materials)
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