Surface Modification/Engineering for Electrochemical Applications

A special issue of Coatings (ISSN 2079-6412). This special issue belongs to the section "Surface Engineering for Energy Harvesting, Conversion, and Storage".

Deadline for manuscript submissions: closed (20 November 2023) | Viewed by 5907

Special Issue Editor


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Guest Editor
Department of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an, China
Interests: carbon nanomaterials and their composites for mechanical reinforcement and renewable energy applications; high-entropy alloys for (photo-)electrocatalysis

Special Issue Information

Dear Colleagues,

Surface modification/engineering can usually give a surface new or improved properties, such as hydrophilic/hydrophobic, biocompatibility, corrosion resistance, and reaction activity, etc., while maintaining the unique advantages of the original material. For the application of surface modification in electrochemistry, it normally consists of surface coating, thereby avoiding electrochemical corrosion or harmful side reactions, and the surface modification of materials, which could regulate the microstructure of the surface and composition of the materials, thus increasing the specific surface area, homogenizing the surface morphology, and stabilizing the surface structure. The concerns of this topic include, but are not limited to, the following:

  • Surface modification of various catalysts
  • Surface modification of battery electrode materials
  • Corrosion protection in electrochemical processes
  • Prevention of harmful side reactions in electrochemical processes
  • The latest development of surface modification in electrochemistry

Prof. Dr. Xiao Han
Guest Editor

Manuscript Submission Information

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Published Papers (3 papers)

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Research

9 pages, 3939 KiB  
Communication
Yttria-Doped Ceria Surface Modification Layer via Atomic Layer Deposition for Low-Temperature Solid Oxide Fuel Cells
by Hyeontaek Kim, Yongchan Park, Davin Jeong and Soonwook Hong
Coatings 2023, 13(3), 491; https://doi.org/10.3390/coatings13030491 - 23 Feb 2023
Cited by 2 | Viewed by 1347
Abstract
Atomic layer deposition (ALD) is performed to obtain less than 1 nm thick yttria-doped ceria (YDC) layers as cathode functional layers to increase the surface oxygen incorporation rate for low-temperature solid oxide fuel cells (LT-SOFCs). Introducing a YDC surface modification layer (SML) has [...] Read more.
Atomic layer deposition (ALD) is performed to obtain less than 1 nm thick yttria-doped ceria (YDC) layers as cathode functional layers to increase the surface oxygen incorporation rate for low-temperature solid oxide fuel cells (LT-SOFCs). Introducing a YDC surface modification layer (SML) has revealed that the optimized yttria concentration in YDC can catalyze surface oxygen exchange kinetics at the interface between the electrolyte and cathode. The YDC SML-containing fuel cell performs 1.5 times better than the pristine fuel cell; the result is an increased exchange current density at the modified surface. Moreover, a heavily doped YDC SML degrades the performance of LT-SOFCs, owing to the weakened oxygen surface kinetics due to the increased migration energy of the oxygen ions. Full article
(This article belongs to the Special Issue Surface Modification/Engineering for Electrochemical Applications)
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29 pages, 9266 KiB  
Article
Electrochemical Behavior of Nickel Aluminide Coatings Produced by CAFSY Method in Aqueous NaCl Solution
by Amalia Marinou, Angeliki G. Lekatou, Galina Xanthopoulou and George Vekinis
Coatings 2022, 12(12), 1935; https://doi.org/10.3390/coatings12121935 - 08 Dec 2022
Cited by 1 | Viewed by 1283
Abstract
Combustion-assisted flame spraying (CAFSY) is a novel method that allows in-flight synthesis of alloys during flame spraying. The in-flight synthesis of alloys by the CAFSY method during flame spraying combines two different methods: the self-propagating high-temperature synthesis (SHS) and flame spraying (FS). The [...] Read more.
Combustion-assisted flame spraying (CAFSY) is a novel method that allows in-flight synthesis of alloys during flame spraying. The in-flight synthesis of alloys by the CAFSY method during flame spraying combines two different methods: the self-propagating high-temperature synthesis (SHS) and flame spraying (FS). The present work studies the corrosion performance (by cyclic polarization and chronoamperometry in aerated 3.5 wt.% NaCl) of NiAl coatings fabricated by the CAFSY technique in relation to main process parameters (composition of the initial feedstock, spraying distance, substrate temperature, postdeposition heat treatment) and their effect on the microstructure and porosity of the coatings. Most of the coatings exhibited limited susceptibility to localized corrosion. In all cases, the steel substrate remained intact despite corrosion. Interconnected porosity was the main parameter accelerating uniform corrosion. Localized corrosion had the form of pitting and/or crevice corrosion in the coating that propagated dissolving Al and Al-rich nickel aluminides along coating defects. Substrate preheating and postdeposition heat treatment negatively affected the corrosion resistance. A short spraying distance (1.5 inch) increased the corrosion resistance of the coatings. Full article
(This article belongs to the Special Issue Surface Modification/Engineering for Electrochemical Applications)
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23 pages, 12925 KiB  
Article
The Role of Anodising Parameters in the Performance of Bare and Coated Aerospace Anodic Oxide Films
by Mariana Paz Martinez-Viademonte, Shoshan T. Abrahami, Meisam D. Havigh, Kristof Marcoen, Theodor Hack, Malte Burchardt and Herman Terryn
Coatings 2022, 12(7), 908; https://doi.org/10.3390/coatings12070908 - 27 Jun 2022
Cited by 3 | Viewed by 2530
Abstract
The anodising process parameters (voltage, temperature, and electrolyte) control the morphology and the chemical composition of the resulting anodic oxide film by altering the balance between oxide growth and oxide dissolution reactions. The porosity of the oxide film is reduced by the addition [...] Read more.
The anodising process parameters (voltage, temperature, and electrolyte) control the morphology and the chemical composition of the resulting anodic oxide film by altering the balance between oxide growth and oxide dissolution reactions. The porosity of the oxide film is reduced by the addition of tartaric acid to a sulfuric acid electrolyte, while anodising at elevated temperatures enhances oxide dissolution, leading to wider pores and rougher surfaces. No significant changes in the oxide chemical composition as a function of anodising parameters was found; in particular, no tartrate incorporation took place. The resistance of uncoated anodic oxide films against aggressive media and galvanic stress as a function of anodising parameters has been studied by electrochemical methods. Anodising in a mixed tartaric and sulfuric acid electrolyte improves the resistance of the anodic oxide against galvanic stress and aggressive media in comparison to sulfuric acid anodising processes. However, the corrosion protection performance of the anodic oxide films in combination with a corrosion-inhibitor loaded organic coating is not governed by the blank oxide properties but by the adhesion-enhancing morphological features formed during anodising at elevated temperatures at the oxide/coating interface. Full article
(This article belongs to the Special Issue Surface Modification/Engineering for Electrochemical Applications)
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