Biomass from specialty crops, including almonds, walnuts, and numerous others, serves as an important resource for energy and materials as agricultural systems evolve towards greater sustainability and circularity in management and operations. Biochar was produced from almond shells in a laboratory furnace at temperatures between 300 and 750 °C for residence times of 30 and 90 min with moisture contents of 5% to 15% wet basis. Response surface methodology was used to optimize the biochar yield. Feedstock and product temperatures were continuously monitored throughout the experiments. In addition, larger batches of biochar were also produced in a fixed-bed pilot-scale pyrolyzer. The yield of biochar was determined as a weight fraction of the amount of oven-dry almond shells used in each experiment. Physical and chemical characteristics of biochars were evaluated. Pyrolysis temperature and time were found to be the significant parameters affecting the biochar yield, with second-order regression models derived to fit yield results. As anticipated, highest biochar yields (65%) were obtained at a pyrolysis temperature of 300 °C and a pyrolysis time of 30 min due to the limited volatilization at this short residence at low temperature affecting torrefaction of the feedstock. The average biochar yield from the fixed-bed pilot-scale experiments was 39.5% and more closely aligned with the fixed carbon from standard proximate analyses. Higher pyrolysis temperatures resulted in higher C:N ratio and pH with the highest C:N ratio of 19:1 and pH of 10.0 obtained at a pyrolysis temperature of 750 °C for 90 min. Particle density increased with the increase of pyrolysis temperature. Results of this study can aid in predicting biochar yields from almond shells under different pyrolysis conditions and determining the amount of biochar required for different applications. Full article

Population growth and the associated increase in the use of Onsite Wastewater Treatment Systems (OWTS) in the Black Hills have been a reason for interest in nitrate contamination within the public water supply over the past few years. The main concern for the Black Hills is the presence of karst formation that all OWTS for wastewater travel faster, limiting the natural attenuation of wastewater contaminants. The treatment performance of common soils in the Black Hills and wood-based media was evaluated using soil column experiments and a numerical model, HYDRUS 2D. Nitrate treatment performances were evaluated using alluvial and cedar soils collected from the Black Hills, sand, woodchips (loose and dense), and biochar. This research investigated hydraulic and reaction parameters through a combination of experimental and inverse modeling approaches. A good agreement was obtained between the measured and model-predicted soil moisture content, with R² values ranging from 0.57 to 0.99. The model was calibrated using flow data and nitrate concentration data measured from leachate collected at the bottom of the experimental columns. Nitrate removal rates varied from 32.3% to 70%, with the highest removal rate in loose woodchips, followed by dense woodchip and biochar, and the lowest removal rate in alluvial materials. The biochar and loose woodchips removed an additional 20% compared to common soils, attributable to the enhanced denitrification rate due to higher water content and organic content. The use of woodchips and biochar should be implemented in OWTS, where there are known karst formations. Full article

Ammoniacal nitrogen (N-NH₃) is one of the pollutants that has adverse effects on the environment and is present in most effluents generated by mining operations. Therefore, mining companies must manage it to keep it below the regulated discharge criteria to avoid environmental contamination. In this context, the present study aims to valorize N-NH₃ in the form of ammonium sulphate ((NH₄)₂SO₄) for the manufacture of biochar pellets used as growth substrates for the production of forest seedlings. The biochar was first produced by fast pyrolysis, at 320 °C, and different recipes of pellets were then prepared to evaluate their hardness, binder type and content, humidity and durability. The optimal granule chosen was composed of biochar, corn starch and canola oil. Six combinations of different compositions were then prepared as substrates for black spruce growth: (1) Peat (P); (2) Peat and bulk biochar (PB); (3) Peat and bulk biochar impregnated with ammonium sulfate (PBAS); (4) Peat and biochar pellets impregnated with water (PBPeW); (5) Peat and biochar pellets impregnated with an ammonium sulfate solution (PBPeAS); (6) Peat, biochar pellets impregnated with ammonium sulfate and perlite (PBPeASPer). The effects of these substrates on the growth of black spruce seedlings, as well as fertilizer leaching, were measured. The results show that seedling biomass is equivalent to the control for the granular treatment, but higher biomass was obtained with bulk biochar (PB). This shows that a quarter of peat could be replaced by biochar to obtain similar or even better results of biomass yield and, consequently, solve part of the supply issue. As to plant nutrition, no tendency was observed for the experiments apart from the higher proportion of Ca in spruce needles. The prepared biochar-based pellet substrate appears to not only be advantageous for spruce production but also for other uses such as golf courses, forestry producers and horticultural nurseries using conventional fertilizers and peat as growing media. In addition, these approaches could help the Abitibi-Témiscamingue region in Québec, Canada to build a local circular economy. Full article

There has been increasing interest in using biochar for nutrient removal from water, and its application for anionic nutrient removal such as in phosphate (PO₄³⁻) necessitates surface modifications of raw biochar. This study produced avocado seed biochar (AB), impregnated Fe- or Mg-(hydr)oxide onto biochar (post-pyrolysis), and tested their performance for aqueous phosphate removal. The Fe- or Mg-loaded biochar was prepared in either high (1:8 of biochar to metal salt in terms of mass ratio) or low (1:2) loading rates via the co-precipitation method. A total of 5 biochar materials (unmodified AB, AB + High Fe, AB + Low Fe, AB + High Mg, and AB + Low Mg) were characterized according to their selected physicochemical properties, and their phosphate adsorption performance was tested through pH effect and adsorption isotherm experiments. Fe-loaded AB contained Fe₃O₄, while Mg-loaded AB contained Mg(OH)₂. The metal (hydr)oxide inclusion was higher in Fe-loaded AB. Mg-loaded AB showed a unique free O–H functional group, while Fe-loaded AB showed an increase in its specific surface area more than 10-times compared to unmodified AB (1.8 m² g⁻¹). The effect of the initial pH on phosphate adsorption was not consistent between Fe-(anion adsorption envelope) vs. Mg-loaded AB. The phosphate adsorption capacity was higher with Fe-loaded AB in low concentration ranges (≤50 mg L⁻¹), while Mg-loaded AB outperformed Fe-loaded AB in high concentration ranges (75–500 mg L⁻¹). The phosphate adsorption isotherm by Fe-loaded AB fit well with the Langmuir model (R² = 0.91–0.96), indicating the adsorptive surfaces were relatively homogeneous. Mg-loaded biochar, however, fit much better with Freundlich model (R² = 0.94–0.96), indicating the presence of heterogenous adsorptive surfaces. No substantial benefit of high loading rates in metal impregnation was found for phosphate adsorption. The enhanced phosphate removal by Mg-loaded biochar in high concentration ranges highlights the important role of the chemical precipitation of phosphate associated with dissolved Mg²⁺. Full article

In this study, the efficacy of biochar to mitigate ammonia stress and improve methane production is investigated. Chicken manure (CM) was subjected to high-solid mesophilic anaerobic digestion (15% total solid content) with wood biochar (BC). Wood biochar was further treated using HNO₃ and NaOH to produce acid–alkali-treated wood biochar (TBC), with an improvement in its overall ammonium adsorption capacity and porosity. Three treatments were loaded in triplicate into the digesters, without biochar, with biochar and with acid–alkali-treated biochar and maintained at 37 °C for 110 days. The study found a significant improvement in CH₄ formation kinetics via enhanced substrate degradation, leading to CH₄ production of 74.7 mL g⁻¹ VS and 70.1 mL g⁻¹ VS by BC and TBC treatments, compared to 39.5 mL g⁻¹ VS by control treatments on the 28th day, respectively. However, only the use of TBC was able to prolong methane production during the semi-inhibition phase. The use of TBC also resulted in the highest removal of total ammonia nitrogen (TAN) of 86.3%. In addition, the treatment with TBC preserved the highest microbial biomass at day 110. The presence of TBC also resulted in an increase in electrical conductivity, possibly promoting DIET-mediated methanogenesis. Overall, the acid–alkali treatment of biochar can be a novel approach to improve biochar’s existing characteristics for its utilisation as an additive in anaerobic digestion. Full article