Special Issue "Exclusive Papers of the Editorial Board Members and Topical Advisory Panel Members of Catalysts in Section "Catalysis in Organic and Polymer Chemistry""

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalysis in Organic and Polymer Chemistry".

Deadline for manuscript submissions: 30 October 2023 | Viewed by 2256

Special Issue Editors

Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University (TMU), 1-1 Minami Osawa, Hachioji, Tokyo 192-0397, Japan
Interests: homogeneous catalysis; organometallics; catalysis and fine chemicals; precise olefin polymerization
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Laboratory of Industrial and Synthetic Organic Chemistry (LISOC), Department of Chemistry and Chemical Technologies, University of Calabria, Via Pietro Bucci 12/C, 87036 Arcavacata di Rende, CS, Italy
Interests: innovative syntheses of high-value molecules through catalytic process; new syntheses of heterocyclic compounds of pharmaceutical interest; carbonylation catalyzed chemistry; application of unconventional solvents in advanced organic synthesis; synthesis of novel materials for advanced applications
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State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
Interests: polymer chemistry; organometallic catalysis; coordination polymerization
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Institut de Chimie de Strasbourg, CNRS-Université de Strasbourg, 1 Rue Blaise Pascal, 67000 Strasbourg, France
Interests: organometallic complexes; homogeneous catalysis; polymerization; oxophilic and electrophilic metal species
Schulich Faculty of Chemistry, Technion - Israel Institute of Technology, Haifa 3200008, Israel
Interests: actinide and lanthanide organometallic chemistry; polymerisation catalysis; organo-f-complexes in catalysis; small molecule activation; transition metal organometallic chemistry; metal-ligand multiple bonding; group 4 organometallics in catalysis
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Institute of Chemistry of Organometallic Compounds, National Research Council of Italy (ICCOM-CNR), Via Madonna del Piano 10, 50019 Sesto Fiorentino, Florence, Italy
Interests: organometallics and catalysis in water and biphasic systems; CO2 activation and utilization processes; hydrogen activation, production, and storage by organometallics; homogeneous catalysis; catalytic mechanisms
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Department of Organic Chemistry, Faculty of Science, Charles University, Hlavova 8, 12843 Prague, Czech Republic
Interests: transition metal complex catalysis; asymmetric synthesis; organometallic chemistry; organocatalysis
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Department of Molecular Science and Technology, Ajou University, Suwon 16499, Republic of Korea
Interests: organic chemistry; polymer synthesis; green chemistry; organometallics; polymerization catalyst chemistry
Key Laboratory of Biobased Polymer Materials, College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
Interests: organometallic catalysts for olefin polymerization; organocatalysts for ring-opening polymerization; structure-property relationships of catalysts
Centro de Química Estrutural e Departamento de Engenharia Química, Institute of Molecular Sciences, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal
Interests: green chemistry; innovative product design; sustainable processes; functionalized materials (in particular, involving C-scorpionates); catalysis (homogeneous, supported or nano- catalysis); electrochemistry
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1. Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan
2. Frontier Chemistry Center, Faculty of Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan
Interests: dual catalysis; allylic alcohol; asymmetric cyanation; combined metal catalyst; unsaturated ketone; unsaturated carbonyl compound; asymmetric isomerization; box ligands; Cu complexes; Pd nanoparticles; photocyclization; kinetic resolution; DPEN; DAIPEN; XylBINAP; BINAP; TolBINAP; DMAPEN; PICA; IPHAN; LiCl; organometallic chemistry; synthetic organic chemistry (4602); organometallic chemistry (4072); asymmetric catalysis (4072); research areas applied chemistry/functional materials chemistry
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Centro de Quimica Estrutural, Instituto Superior Tecnico, Lisbon, Portugal
Interests: coordination chemistry; oxidation catalysis; electrocatalysis; alkane functionalization; carboxylation; C-C coupling; non-covalent interactions in synthesis
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Dipartimento di Chimica, Università degli Studi di Milano, Via C. Golgi 19, 20133 Milan, Italy
Interests: homogeneous catalysis; carbonylation reactions; nitroarene reductive cyclization; nitroarene reductive carbonylation; catalytic synthesis of isocyanates, carbamates, and ureas; oxidative carbonylation of amines; nitrogen-enriched graphitic metal catalysts; synthesis and use of nitrogen ligands
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UMR 8181—UCCS—Unité de Catalyse et Chimie du Solide, Université de Lille, CNRS, Centrale Lille, Université d'Artois, F-59000 Lille, France
Interests: coordinative polymerization catalysis; rare-earth and iron organometallic chemistry
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China
Interests: catalysts for living polymerization; chiral polymers; functional materials
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan
Interests: copper catalysis; borylation; stannylation; silylation; main group organometallics; cross-coupling; multicomponent coupling; aryne chemistry
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Department of Natural Science, Graduate School of Science and Technology, Tokushima University, Minamijosanjima-cho, Tokushima 770-8506, Japan
Interests: organometallic chemistry; homogeneous catalysis; asymmetric synthesis

Special Issue Information

Dear Colleagues,

We are pleased to announce the launch of a new Special Issue, “Exclusive Papers of the Editorial Board Members and Topical Advisory Panel Members of Catalysts in Section "Catalysis in Organic and Polymer Chemistry"”. This will be a collection of papers edited by the editorial board members of the Section “Catalysis in Organic and Polymer Chemistry.” The issue will covers papers with a wide scope in the field of homogeneous catalysis, organometallic chemistry, and polymer chemistry, including such topics as sustainable polymers (prepared by coordination polymerization, ring opening polymerization), polyolefin synthesis, chemical recycling (conversion to monomers) and upcycling (conversion to upgraded chemicals, polymers), biobased polymers, and related catalysis chemistry. Topics related to the design of molecular catalysis, including mechanistic studies, which are at the core of homogeneous catalysis, will be highly welcome to this Special Issue.

We look forward to receiving many outstanding submissions on the topics above, which will contribute to the creation of an important Special Issue in this journal.

Prof. Dr. Kotohiro Nomura
Prof. Dr. Raffaella Mancuso
Prof. Dr. Zhengguo Cai
Prof. Dr. Samuel Dagorne
Prof. Dr. Moris S. Eisen
Dr. Luca Gonsalvi 
Prof. Dr. Martin Kotora
Prof. Dr. Bun Yeoul Lee
Prof. Dr. Shaofeng Liu
Prof. Dr. Luísa Margarida Martins
Prof. Dr. Takeshi Ohkuma
Prof. Dr. Armando Pombeiro
Prof. Dr. Fabio Ragaini 
Prof. Dr. Carl Redshaw
Prof. Dr. Marc Visseaux
Prof. Dr. Zongquan Wu
Prof. Dr. Hiroto Yoshida
Prof. Dr. Masamichi Ogasawara
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Catalysts is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • molecular catalyst
  • green sustainable catalysts
  • sustainable polymers
  • chemical recycling
  • upcycling
  • organometallics
  • polymerization
  • catalyzed fine chemicals synthesis
  • designed catalysts
  • green reaction pathways

Published Papers (3 papers)

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Research

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Article
Expression of Reaction Selectivity and the Substituent Effect in Ullmann, Suzuki, Hiyama, and Allylic Arylation Reactions Caused by Reducing Catalyst Loading
Catalysts 2023, 13(7), 1115; https://doi.org/10.3390/catal13071115 - 17 Jul 2023
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Abstract
The control of stereo-, regio-, and chemo-selectivity in transition-metal-catalyzed coupling reactions is a key topic in organic synthesis. Several methods for controlling selectivity have been reported thus far. On the other hand, the reduction of catalyst loading during reactions is one of the [...] Read more.
The control of stereo-, regio-, and chemo-selectivity in transition-metal-catalyzed coupling reactions is a key topic in organic synthesis. Several methods for controlling selectivity have been reported thus far. On the other hand, the reduction of catalyst loading during reactions is one of the most important issues in organic synthesis from the standpoint of green sustainable chemistry. As another advantage of reducing catalyst loading, the expression of reaction selectivity and the substituent effect caused by the reduction of catalyst loading to the parts-per-million (ppm) level in various catalytic reactions is presented herein. Full article
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Article
Synthesis of Cationic [4], [5], and [6]Azahelicenes with Extended π-Conjugated Systems
Catalysts 2023, 13(5), 912; https://doi.org/10.3390/catal13050912 - 22 May 2023
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Abstract
The scope of Rh-catalyzed C–C bond cleavage/annulation of biphenylene with various aromatic nitriles was studied. The subsequent Rh- and Ir-catalyzed C–H bond activation/annulation sequence of the formed 9-arylphenanthridines with alkynes gave rise to cationic [4], [5], [6] helical quinolizinium salts. The scope of [...] Read more.
The scope of Rh-catalyzed C–C bond cleavage/annulation of biphenylene with various aromatic nitriles was studied. The subsequent Rh- and Ir-catalyzed C–H bond activation/annulation sequence of the formed 9-arylphenanthridines with alkynes gave rise to cationic [4], [5], [6] helical quinolizinium salts. The scope of the reaction with respect to the structural features of the starting 9-arylphenanthridines and alkynes was studied. Their helical arrangement was confirmed through single-crystal X-ray analyses of selected compounds. Most of the prepared quinolizinium salts exhibited fluorescence emission maxima in the region of 525–623 nm with absolute quantum yields up to 25%. Full article
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Review

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Review
Comprehensive Overview of Homogeneous Gold-Catalyzed Transformations of π-Systems for Application Scientists
Catalysts 2023, 13(6), 921; https://doi.org/10.3390/catal13060921 - 23 May 2023
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Abstract
We present an overview of fundamental catalytic reactions of nucleophiles with π-systems in relation to gold chemistry. We present examples of reactions with gold-activated π-systems, alkynyl or allenyl moieties, and the regulation of their reactivity due to the presence of an electron-donating or [...] Read more.
We present an overview of fundamental catalytic reactions of nucleophiles with π-systems in relation to gold chemistry. We present examples of reactions with gold-activated π-systems, alkynyl or allenyl moieties, and the regulation of their reactivity due to the presence of an electron-donating or -withdrawing group. The reactions describe furnished hard-to-reach heterocyclic building blocks for medicinal chemistry purposes. Important gold(I) or gold(III) complexes that are used as catalysts are presented. We examine the activation of such π-systems using gold(I) or gold(III) catalysts and the corresponding divergent catalytic transformations. We provide examples of divergent catalysis using gold(I) catalyst and other metal catalysts (Pt, Ag, Pd, Rh, Sc, Cu) or by changing the ligands in gold(I) catalyst complexes. We also discuss the role of the solvent, counterions and additives in gold(I)-catalyzed reactions. We mention, in a few cases, characteristic experimental or computational studies of these gold-catalyzed reactions of nucleophiles with π-systems. Full article
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Planned Papers

The below list represents only planned manuscripts. Some of these manuscripts have not been received by the Editorial Office yet. Papers submitted to MDPI journals are subject to peer-review.

Title: Chemical Recycling of Polyesters for Future Circular Economy: Role of Catalyst Develoment
Authors: Kotohiro Nomura
Affiliation: Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University (TMU), 1-1 Minami Osawa, Hachioji, Tokyo 192-0397, Japan

Title: Transition metal phosphide catalysts for Green Sustainable Molecular transformations
Authors: Takato Mitsudome
Affiliation: Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan

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