Effect of the Modification of Catalysts on the Catalytic Performance, 2nd Edition

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: 31 August 2024 | Viewed by 3740

Special Issue Editors


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Guest Editor
Romanian Academy, “Ilie Murgulescu” Physical Chemistry Institute, Bucharest, Romania
Interests: catalytic and photocatalytic reaction; mono and bimetallic nanoparticles synthesis by alkaline polyol method; oxidation of C1-C4 aliphatic hydrocarbons on simple and doped oxides; oxidative coupling of methane on rare earth oxides; selective catalytic reduction of nitrates and nitrites in the liquid phase; catalytic oxidation of ammonia nitrogen with ozone in water; modified catalysts and their fractal properties
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E-Mail Website
Guest Editor
Romanian Academy, “Ilie Murgulescu” Physical Chemistry Institute, Bucharest, Romania
Interests: catalysis; kinetics of gas-solid interaction; catalytic synthesis; lower olefin (C3–C4) oxidation on multicomponent oxide catalysts; semiconductor properties of oxide catalysts; AC in situ electrical conductivity measurements on catalytic systems; dynamics of the lattice oxygen in oxide catalysts for selective oxidation catalysis; synthesis of well-defined mono/bimetallic nanoparticles supported; photocatalytic degradation of organic compounds in water
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
Romanian Academy, “Ilie Murgulescu” Physical Chemistry Institute, Bucharest, Romania
Interests: surface science; fractal theory; adsorption mechanism; modelling gases adsorption and desorption from metal-supported catalysts; applying fractal theory to characterize surfaces; modelling adsorption on fractal surfaces; computing fractal dimension from micrographs (TEM, SEM, AFM, STM); growth surfaces and computing the time and spatial scaling exponents using the variable scaling method
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

A great challenge in the field of catalysis is the synthesis of catalysts with enhanced catalytic activity, selectivity, and durability. The structural and compositional complexity of the catalytic system requires a strong systematic approach to elucidate the nature of the catalyst’s active sites. A catalytic active site is a mono- or polyatomic entity with a specific electronic surface configuration, able to generate a catalytic act (adsorption, dissociation of reactant molecules, and desorption of reaction products).

In-depth knowledge of the composition, structure, and nature of active sites provides the possibility of tailoring the catalytic properties in order to improve catalytic performance (activity and selectivity). Such properties that can be targeted by synthesis are controlled porosity, sintering, resistance, large specific surface area, optimal acid–base properties, lattice vacancies, metal–support interaction, catalyst design, conductivity, etc.

Therefore, the change in catalyst properties leads to modified kinetic parameters (reaction rate, activation energy) and the reaction mechanism.

Improving catalytic performance by modifying catalysts should play an important role in the current global situation by reducing the negative impact on the environment and supporting the sustainable use of natural resources.

The purpose of this issue is to present state-of-the-art strategies for modifying catalysts, aiming to provide an important contribution to the development of research in this area from both practical and theoretical perspectives.

We aim to gain a better understanding of catalytic systems, facilitating the establishment of correlations between composition and physical–chemical properties and performance.

Original research papers and topical reviews are welcome in this Special Issue of Catalysts. Submit your paper and select the Journal Catalysts and the Special Issue “Effect of the Modification of Catalysts on the Catalytic Performance II” via the MDPI submission system. Please contact the Guest Editor or the journal editor (maeve.yue@mdpi.com) for any queries. Our papers will be published on a rolling basis, and we will be pleased to receive your submission once you have finished it.

Dr. Florica Papa
Dr. Anca Vasile
Dr. Gianina Dobrescu
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Catalysts is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • catalytic performance
  • catalyst
  • synergetic effect
  • modification of catalysts
  • selectivity
  • catalyst synthesis
  • reaction mechanism
  • catalytic activity

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Published Papers (3 papers)

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Research

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15 pages, 62227 KiB  
Article
Effect of pH on Microstructure and Catalytic Oxidation of Formaldehyde in MnO2 Catalyst
by Wenrui Zhang, Meilu Hao, Yonghui Wang, Pengfei Sun, Dongjuan Zeng, Xinya Wang and Peng Liang
Catalysts 2023, 13(3), 490; https://doi.org/10.3390/catal13030490 - 28 Feb 2023
Viewed by 1452
Abstract
Layered δ-MnO2 catalysts were prepared using the one-step redox method in precursor solutions with five different pH values (pH = 7, 9, 11, 13, and 14). The effects of pH on the physical properties and catalytic activity of the catalyst were investigated [...] Read more.
Layered δ-MnO2 catalysts were prepared using the one-step redox method in precursor solutions with five different pH values (pH = 7, 9, 11, 13, and 14). The effects of pH on the physical properties and catalytic activity of the catalyst were investigated through XRD, SEM, TEM, BET, XPS, H2-TPR, and HCHO degradation tests at room temperature. The results showed that the layer spacing, manganese vacancy content, Mn4+/Mn3+ ratio, and surface-reactive oxygen species content of MnO2 increased with the increase in pH value in the alkaline range. When the catalyst was prepared at pH = 13, the above characteristics of the catalyst reached the optimal value which contributed to the high catalytic activity. Combined with the related characterization results, it was proved that changing the pH can affect the degree of oxidation in the catalyst synthesis process, increase the number of active oxygen and the oxygen mobility of the catalyst, and effectively improve the catalytic activity of the manganese dioxide catalyst for HCHO. This work represents a giant step toward the preparation of an effective catalyst for practical applications of HCHO removal at room temperature at a low concentration and high velocity. Full article
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13 pages, 3878 KiB  
Article
The Pincer Ligand Supported Ruthenium Catalysts for Acetylene Hydrochlorination: Molecular Mechanisms from Theoretical Insights
by Xingtao Wang, Jiangshan Zhao, Yongwang Li, Xubin Zhang, Fumin Wang, Botao Wu and Tian Wang
Catalysts 2023, 13(1), 31; https://doi.org/10.3390/catal13010031 - 24 Dec 2022
Viewed by 1490
Abstract
Pincer ligand supported RuII chloride complexes may be used for acetylene hydrochlorination as non-mercury molecular catalysts. Based on theoretical calculations, the catalytic mechanism and the interaction between catalysts and reactants has been evaluated, indicating that the (pincer)RuIICl2 platform supports [...] Read more.
Pincer ligand supported RuII chloride complexes may be used for acetylene hydrochlorination as non-mercury molecular catalysts. Based on theoretical calculations, the catalytic mechanism and the interaction between catalysts and reactants has been evaluated, indicating that the (pincer)RuIICl2 platform supports electrophilic proton-ruthenation of C2H2. Energy decomposition studies further illustrate the electron-rich property of the RuII center, which can increase the negative charge of C2H2 via 4d-electron backdonation. Thus, the electrophilic reaction mechanism is favored due to lower energetic barriers. By improving the electron-donating ability of ligands, this lowering of energetic barriers can be enhanced. Therefore, non-mercury catalysts for acetylene hydrochlorination with milder reaction conditions and higher catalytic activity can be designed. Full article
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Review

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15 pages, 4007 KiB  
Review
A Review of Ozone Decomposition by a Copper-Based Catalyst
by Guojun Ma, Jian Guan, Qiuyi Zhu, Yishan Jiang, Ning Han and Yunfa Chen
Catalysts 2024, 14(4), 264; https://doi.org/10.3390/catal14040264 - 16 Apr 2024
Viewed by 346
Abstract
The threat of ozone in indoor spaces and other enclosed environments is receiving increasing attention. Among numerous ozone catalytic decomposition technologies, copper catalytic material has a superior performance and relatively low cost, making it one of the ideal catalyst materials. This review presents [...] Read more.
The threat of ozone in indoor spaces and other enclosed environments is receiving increasing attention. Among numerous ozone catalytic decomposition technologies, copper catalytic material has a superior performance and relatively low cost, making it one of the ideal catalyst materials. This review presents the recent Cu catalyst studies on ozone decomposition, particularly morphological design, the construction of heterostructures, and monolithic catalyst design used to improve their performance. Moreover, this review proposes further improvement directions based on Cu materials’ inherent limitations and practical needs. On this basis, in the foreseeable future, Cu materials will play a greater role. Full article
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