Solar, Volume 3, Issue 1 (March 2023) – 11 articles

On one side, the capacity of the world’s photovoltaic (PV) systems is experiencing unprecedented growth; on the other side, the number of connected devices is rapidly increasing due to the development of advanced communication technologies. These fields are not completely independent, and recent studies show that indoor energy harvesting is a great candidate for answering the energy challenges of future generations of telecommunications, namely 5G and 6G, ideal for internet-of-things (IoT) scenarios, i.e., smart homes, smart cities, and smart factories. The emerging PV technologies have shown amazing capabilities for indoor energy harvesting, displaying high power conversion efficiency, good flexibility, and champion-specific powers. Recently, the excellent dynamic performance of PV devices enabled them to be used as data receivers in optical wireless communication (OWC) scenarios, calling forth an innovative system able to simultaneously harvest energy and receive communication data with a single PV device. This article reviews the recent literature devoted to the exploitation of photovoltaic technologies for simultaneous indoor energy harvesting and OWC data reception. This contribution highlights the strong potential of the approach toward the next generation of Green IoT systems and the current challenges that need to be addressed with regard to the physics of solar cells, from laboratory to large-scale applications. Full article

Concentrating solar power (CSP) is a high-potential renewable energy source that can leverage various thermal applications. CSP plant development has therefore become a global trend. However, the designing of a CSP plant for a given solar resource condition and financial situation is still a work in progress. This study aims to develop a mathematical model to analyze the levelized cost of electricity (LCOE) of Thermal Energy Storage (TES)-integrated CSP plants in such circumstances. The developed model presents an LCOE variation for 18 different CSP configurations with TES incorporated for Rankine, Brayton, and combined power generation cycles, under regular TES materials and nano-enhanced TES materials. The model then recommends the most economical CSP plant arrangement. Within the scope of this study, it was found that the best configuration for electricity generation is a solar power tower with nano-enhanced phase change materials as the latent heat thermal energy storage medium that runs on the combined cycle. This returns an LCOE of 7.63 ct/kWh with a 22.70% CSP plant efficiency. The most favorable option in 50 MW plants is the combined cycle with a regular TES medium, which has an LCOE of 7.72 ct/kWh with a 22.14% CSP plant efficiency. Full article

In parabolic trough technology, the development of thermally and structurally stable solar coatings plays a key role in determining the efficiency, durability, and economic feasibility of tube receivers. A cermet-based solar coating is typically constituted by a thin film stratification, where a multilayer graded cermet is placed between an infrared metallic reflector and an antireflection filter. This work reports the realization of materials based on Al₂O₃ and W characterized by high structural and chemical stability in vacuum at high temperature, obtained through the optimization of high-deposition-rate processes. Al₂O₃ material, employed as the antireflection layer, was deposited through a reactive magnetron sputtering process at a high deposition rate. Cermet materials based on W-Al₂O₃ were deposited and employed as absorber layers by implementing reactive magnetron co-sputtering processes. An investigation into the stability of the realized samples was carried out by means of several material characterization methods before and after the annealing process in vacuum (1 × 10⁻³ Pa) at high temperature (620 °C). The structural properties of the samples were evaluated using Raman spectroscopy and XRD measurements, revealing a negligible presence of oxides that can compromise the structural stability. Spectrophotometric analysis showed little variations between the deposited and annealed samples, clearly indicating the high structural stability. Full article

Cu-oxide nanophases (CuO, Cu₂O, Cu⁰) constitute highly potent nanoplatforms for the development of efficient Artificial Photosynthesis catalysts. The highly reducing conduction band edge of the d-electrons in Cu₂O dictates its efficiency towards CO₂ reduction under sunlight excitation. In the present review, we discuss aspects interlinking the stability under photocorrosion of the (CuO/Cu₂O/Cu⁰) nanophase equilibria, and performance in H₂-production/CO₂-reduction. Converging literature evidence shows that, because of photocorrosion, single-phase Cu-oxides would not be favorable to be used as a standalone cathodic catalyst/electrode; however, their heterojunctions and the coupling with proper partner materials is an encouraging approach. Distinction between the role of various factors is required to protect the material from photocorrosion, e.g., use of hole scavengers/electron acceptors, band-gap engineering, nano-facet engineering, and selectivity of CO₂-reduction pathways, to name a few possible solutions. In this context, herein we discuss examples and synthesis efforts that aim to clarify the role of interfaces, faces, and phase stability under photocatalytic conditions. Full article

The materials used to manufacture solar receivers for tower power plants must withstand high fluxes of concentrated solar radiation (from $0.1$ to even $1.5$ MWm${}^{-2}$) and operate at high operating temperatures (>800 °C). Durability is a key aspect in these systems, which must be ensured under these demanding operating conditions, which also include daily heating–cooling cycles throughout the lifetime of these power plants. So far, to the authors’ knowledge, which wavelengths of concentrated solar radiation have the greatest influence on the mechanisms and speed of aging of materials used in solar receivers has not been analyzed. Yet, such an analysis is pertinent in order to implement strategies that delay or inhibit such phenomena, and, thus, increase the durability of central tower systems’ receivers. To perform such analyses, a new solar furnace was recently designed and installed at the Plataforma de Almería (Spain). This paper describes the components of this new solar furnace. The components are as follows: a heliostat to redirect the direct solar radiation towards a Fresnel lens that concentrates the solar radiation on the material under study, a shutter that allows varying the amount of concentrated solar radiation incident on the Fresnel lens, and reflective filters with selective reflectance that are placed between the Fresnel lens and the material. This paper also describes the procedure and the first results of the energetic and spectral characterization of this new solar furnace. The first experimental results of the characterization of this new test bed using the heliostat and the Fresnel lens showed that concentration ratios of up to 1000 suns (1 sun = 1000 Wm${}^{-2}$) could be achieved. Furthermore, the paper presents the results of the spectral characterization of the test system, using selective reflectance mirrors in the near-visible–IR wavelength range (400–1125 nm) and in the visible–IR red region (700–2500 nm). Full article

This work presents the modeling and energy management of a microgrid through models developed based on physical equations for its optimal control. The microgrid’s energy management system was built with one of the most popular control algorithms in microgrid energy management systems: model predictive control. This control strategy aims to satisfy the load demand of an office located in the CIESOL bioclimatic building, which was placed in the University of Almería, using a quadratic cost function. The simulation scenarios took into account real simulation parameters provided by the microgrid of the building. For case studies of one and five days, the optimization was aimed at minimizing the input energy flows of the microgrid and the difference between the energy generated and demanded by the load, subject to a series of physical constraints for both outputs and inputs. The results of this work show how, with the correct tuning of the control strategy, the energy demand of the building is covered through the optimal management of the available energy sources, reducing the energy consumption of the public grid, regarding a wrong tuning of the controller, by 1 kWh per day for the first scenario and 7 kWh for the last. Full article

Renewable energy systems design using average year weather data is a standard approach that works well for grid-tied systems, but for stand-alone ones, it leads to dramatic mistakes. We considered the effect of meteorological data temporal resolution (5, 10, 15, 20, 30 min; 1, 2, 3, 4 h) on a stand-alone hybrid system’s layout in terms of equipment cost, power supply reliability and maximum duration of interruption for monitoring equipment in the Alps. We have shown that lifecycle costs could be strongly (order of magnitude) underestimated for off-grid systems, as well as their reliability overestimated. Lower temporal resolution data lead to the underestimation of energy storage charge–discharge cycles (considering depth of discharge too)—real batteries are to be replaced more often, which matches our practical experience as well. Even a 5 to 10 min decrease in weather data temporal resolution leads to the estimated annual expenses being halved. In general, we recommend using 30 min resolution. Full article

This paper presents a model of an energy system for a private household extended by a lifetime prognosis. The energy system was designed for fully covering the year-round energy demand of a private household on the basis of electricity generated by a photovoltaic (PV) system, using a hybrid energy storage system consisting of a hydrogen unit and a lithium-ion battery. Hydrogen is produced with a Proton Exchange Membrane (PEM) electrolyser by PV surplus during the summer months and then stored in a hydrogen tank. Mainly during winter, in terms of lack of PV energy, the hydrogen is converted back into electricity and heat by a fuel cell. The model was created in Matlab/Simulink and is based on real input data. Heat demand was also taken into account and is covered by a heat pump. The simulation period is a full year to account for the seasonality of energy production and demand. Due to high initial costs, the longevity of such an energy system is of vital interest. Therefore, this model was extended by a lifetime prediction in order to optimize the dimensioning with the aim of lifetime extension of a hydrogen-based energy system. Lifetime influencing factors were identified on the basis of a literature review and were integrated in the model. An extensive parameter study was performed to evaluate different dimensionings regarding the energy balance and the lifetime of the three components, electrolyser, fuel cell and lithium-ion battery. The results demonstrate the benefits of a holistic modelling approach and enable a design optimization regarding the use of resources, lifetime and self-sufficiency of the system. Full article

TiO₂ photocatalysts can provide carbon-capture utilization and storage by converting atmospheric CO₂ to green hydrogen, but the efficiency of the current photocatalysts is still too low for economical usage. Anatase TiO₂ is effective in transferring the electrons and holes produced by the photoelectric effect to reactants because of its oxygen-terminated surfaces. However, the anatase TiO₂ bandgap is 3.2 eV, which requires photons with wavelengths of 375 nm or less to produce electron–hole pairs. Therefore, TiO₂ is limited to using a small part of the solar spectrum. Strain engineering has been used to design ZrO₂@TiO₂ core@shell structures with large strains in the TiO₂ shell, which reduces its bandgap but maintains octahedral facets for charge separation and oxygen-terminated surfaces for the catalysis of reactants. Finite element analysis shows that shell thicknesses of 4–12 nm are effective at obtaining large strains in a large portion of the shell, with the largest strains occurring next to the ZrO₂ surface. The c-axis strains for 4–12 nm shells are up to 7%. The strains reduce the bandgap in anatase TiO₂ up to 0.35 eV, which allows for the use of sunlight with wavelengths up to 421 nm. For the AM 1.5 standard spectrum, electron–hole pair creation in 4 nm thick and 10 nm thick TiO₂ shells can be increased by a predicted 25% and 23%, respectively. The 10 nm thick shells provide a much larger volume of TiO₂ and use proportionally less ZrO₂. In addition, surface-plasmon resonators could be added to further extend the usable spectrum and increase the production of electron–hole pairs many-fold. Full article

We present our own Interdigitated Back Contact (IBC) technology, which was developed at ISC Konstanz and implemented in mass production with and at SPIC Solar in Xining, China, with production efficiencies of over 24%. To our knowledge, this is the highest efficiency achieved in the mass production of crystalline silicon solar cells without the use of charge-carrier-selective contacts. With an adapted screen-printing sequence, it is possible to achieve open-circuit voltages of over 700 mV. Advanced module technology has been developed for the IBC interconnection, which is ultimately simpler than for conventional double-sided contacted solar cells. In the next step, we will realize low-cost charge-carrier-selective contacts for both polarities in a simple sequence using processes developed and patented at ISC Konstanz. With the industrialisation of this process, it will be possible to achieve efficiencies well above 25% at low cost. We will show that with the replacement of silver screen-printed contacts by copper or aluminium metallisation, future IBC technology will be the end product for the PV market, as it is the best performing c-Si technology, leading to the lowest cost of electricity, even in utility-scale applications. Full article