N-Annulation of the BTI Rylene Imide Organic Building Block: Impact on the Optoelectronic Properties of π-Extended Molecular Structures
Abstract
:1. Introduction
2. Results and Discussion
3. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Compound | λmax Solution (nm) | ε (L·mol−1·cm−1) | λem Solution (nm) | Qf a | λmax Film (nm) | Onset Film (nm) | Egopt Film (eV) | HOMO (eV) b | LUMO (eV) c |
---|---|---|---|---|---|---|---|---|---|
DPP-BTI | 577 480 411 308 | 48,000 50,000 27,000 43,000 | 655 | 0.62 | 601 488 426 337 | 708 | 1.75 | −5.68 | −3.93 |
DPP-TCI | 588 499 416 324 | 48,000 43,000 32,000 35,500 | 661 | 0.60 | 616 505 425 340 | 733 | 1.69 | −5.45 | −3.76 |
Compound | VOC (V) | JSC (mA·cm−2) | FF (%) | PCE (%) |
---|---|---|---|---|
DPP-BTI | 1.02 (1.01 ± 0.02) | 8.55 (8.49 ± 0.07) | 31 (29 ± 2) | 2.70 (2.48 ± 0.18) |
DPP-TCI | 0.88 (0.87 ± 0.01) | 8.19 (8.15 ± 0.08) | 28 (27 ± 1) | 2.01 (1.93 ± 0.07) |
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Andrés Castán, J.M.; Abidi, S.; Ghanem, T.; Touihri, S.; Blanchard, P.; Welch, G.C.; Zagranyarski, Y.; Boixel, J.; Walker, B.; Josse, P.; et al. N-Annulation of the BTI Rylene Imide Organic Building Block: Impact on the Optoelectronic Properties of π-Extended Molecular Structures. Colorants 2023, 2, 22-30. https://doi.org/10.3390/colorants2010002
Andrés Castán JM, Abidi S, Ghanem T, Touihri S, Blanchard P, Welch GC, Zagranyarski Y, Boixel J, Walker B, Josse P, et al. N-Annulation of the BTI Rylene Imide Organic Building Block: Impact on the Optoelectronic Properties of π-Extended Molecular Structures. Colorants. 2023; 2(1):22-30. https://doi.org/10.3390/colorants2010002
Chicago/Turabian StyleAndrés Castán, José María, Sana Abidi, Tatiana Ghanem, Saad Touihri, Philippe Blanchard, Gregory C. Welch, Yulian Zagranyarski, Julien Boixel, Bright Walker, Pierre Josse, and et al. 2023. "N-Annulation of the BTI Rylene Imide Organic Building Block: Impact on the Optoelectronic Properties of π-Extended Molecular Structures" Colorants 2, no. 1: 22-30. https://doi.org/10.3390/colorants2010002