Coatings

15 pages, 18171 KiB

Open AccessArticle

Surface Properties of Retrieved Cementless Femoral Hip Endoprostheses Produced from a Ti6Al7Nb Alloy

by Klemen Avsec, Monika Jenko, Marjetka Conradi, Aleksandra Kocijan, Alenka Vesel, Janez Kovač, Matjaž Godec, Igor Belič, Barbara Šetina Batič, Črtomir Donik, Matevž Gorenšek, Boštjan Kocjančič and Drago Dolinar

Coatings 2019, 9(12), 868; https://doi.org/10.3390/coatings9120868 - 17 Dec 2019

Cited by 9 | Viewed by 2635

Abstract

We have investigated new and retrieved cementless hip endoprostheses that prematurely failed due to (i) aseptic loosening, (ii) infection and (iii) latent infection. The aim was to better understand the physico-chemical phenomena on the surfaces and sub-surfaces of the Ti6Al7Nb alloy implant. The [...] Read more.

We have investigated new and retrieved cementless hip endoprostheses that prematurely failed due to (i) aseptic loosening, (ii) infection and (iii) latent infection. The aim was to better understand the physico-chemical phenomena on the surfaces and sub-surfaces of the Ti6Al7Nb alloy implant. The results of our studies should enable us to distinguish the causes of premature failure, optimize the surface modification, achieve optimal osseointegration and extend the useful lifetime of the implants. The surface properties of the Ti6Al7Nb alloys of the hip-stem endoprostheses (30 retrieved and 2 new) were determined by contact-angle measurements and the average surface roughness. The surface chemistry and microstructure were analysed by scanning electron microscopy (SEM) for morphology, energy-dispersive X-ray spectroscopy (EDS) for the chemistry, and electron back-scatter diffraction (EBSD) for the phase analysis; Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS) for the surface chemistry; and electrochemical measurements for the corrosion. The improved wettability of the grit-blasted surface of the Ti6Al7Nb stems after autoclaving was measured, as was the super wettability after oxygen-plasma sterilization. The secondary-electron images showed that the morphology and microstructure of the new and retrieved stems (prematurely failed due to aseptic loosening, infection and latent infection) differ slightly, while the EDS analysis revealed corundum contamination of the grit-blasted surface. We found corundum-contaminated Ti6Al7Nb stem surfaces and sub-surfaces for all the investigated new and retrieved implants. These residues are a potential problem, i.e., third-body wear particles, and probably induce the osteolysis and aseptic loosening. Full article

► Show Figures

Figure 1

13 pages, 4259 KiB

Open AccessArticle

Influence of Sealing Treatment on the Corrosion Resistance of PEO Coated Al-Zn-Mg-Cu Alloy in Various Environments

by Diping Zeng, Zhiyi Liu, Song Bai and Jian Wang

Coatings 2019, 9(12), 867; https://doi.org/10.3390/coatings9120867 - 16 Dec 2019

Cited by 18 | Viewed by 3295

Abstract

In the present work, a coating was prepared on an Al alloy substrate by plasma electrolytic oxidation (PEO). To seal the micro defects in the oxide scale, a siloxane layer was prepared on the PEO coating by sol gel method. The polymer sealant [...] Read more.

In the present work, a coating was prepared on an Al alloy substrate by plasma electrolytic oxidation (PEO). To seal the micro defects in the oxide scale, a siloxane layer was prepared on the PEO coating by sol gel method. The polymer sealant was synthesized from Tetraethoxy silane (TEOS) and methacryloxy propyl trimethoxyl silane (MPTES). The chemical structure of the polymer was studied by Fourier transform infrared spectroscopy (FTIR). The morphologies and microstructure of the PEO coating and siloxane coating were investigated by scanning electron microscopy (SEM). The results showed that siloxane formed a continuous layer on the surface and effectively sealed the micro defects. The corrosion behavior of the coatings in three different corrosion solutions (NaCl, HCl, and NaOH) was examined by electrochemical impedance spectroscopy and potentiodynamic polarization. The corrosion resistance of the sealed coatings was superior to that of the PEO coating because it prevented the penetration of corrosive solutions. The corrosion resistance of the sealed coatings was found to decrease with increasing electrolyte concentration. The work demonstrated that siloxane sealing may greatly enhance the corrosion resistance of Al-based PEO coating in acidic, neutral, and alkaline environments. Full article

► Show Figures

Figure 1

14 pages, 1197 KiB

Open AccessEditor’s ChoiceReview

Innovative Wood Surface Treatments Based on Nanotechnology

by Antonios N. Papadopoulos and Hamid R. Taghiyari

Coatings 2019, 9(12), 866; https://doi.org/10.3390/coatings9120866 - 16 Dec 2019

Cited by 65 | Viewed by 7022

Abstract

This work reviewed innovative wood surface treatments based on nanotechnology. It is well documented in the literature that the cell walls of wood present significant porosity; this porosity is on a molecular scale. The main reason for the use of nanotechnology in wood [...] Read more.

This work reviewed innovative wood surface treatments based on nanotechnology. It is well documented in the literature that the cell walls of wood present significant porosity; this porosity is on a molecular scale. The main reason for the use of nanotechnology in wood science and technology is the unique characteristic of nano-based materials to effectively penetrate deeply into wood substrates, which, in turns, results in the alteration of their surface chemistry. This subsequently causes an improvement in wood properties. Any potential change in the wood properties due to treatment with nanomaterials is based on the higher interfacial area which is developed due to the treatment. This occurs because the number of particles is significantly reduced to the nanoscale. The nanomaterials improve the properties of wood as a raw material and alter its original features to a limited extent. However, their potential impact on both health and the environment should be addressed by applying tools such as life-cycle assessments. This will avoid mistakes being made in which new technologies are released on the market prior to an impact assessment having been carried out. Full article

(This article belongs to the Collection Advanced Surface Coating of Nanoparticles)

► Show Figures

Figure 1

12 pages, 21154 KiB

Open AccessArticle

Production of Phosphorescent Coatings on 6082 Aluminum Using Sr_0.95Eu_0.02Dy_0.03Al₂O_4-δ Powder and Plasma Electrolytic Oxidation

by Krisjanis Auzins, Aleksejs Zolotarjovs, Ivita Bite, Katrina Laganovska, Virginija Vitola, Krisjanis Smits and Donats Millers

Coatings 2019, 9(12), 865; https://doi.org/10.3390/coatings9120865 - 16 Dec 2019

Cited by 7 | Viewed by 3455

Abstract

In this study, a new approach for producing phosphorescent aluminum coatings was studied. Using the plasma electrolytic oxidation (PEO) process, a porous oxide coating was produced on the Al6082 aluminum alloy substrate. Afterwards, activated strontium aluminate (SrAl₂O₄: Eu²⁺ [...] Read more.

In this study, a new approach for producing phosphorescent aluminum coatings was studied. Using the plasma electrolytic oxidation (PEO) process, a porous oxide coating was produced on the Al6082 aluminum alloy substrate. Afterwards, activated strontium aluminate (SrAl₂O₄: Eu²⁺, Dy³⁺) powder was filled into the cavities and pores of the PEO coating, which resulted in a surface that exhibits long-lasting luminescence. The structural and optical properties were studied using XRD, SEM, and photoluminescence measurements. It was found that the treatment time affects the morphology of the coating, which influences the amount of strontium aluminate powder that can be incorporated into the coating and the resulting afterglow intensity. Full article

(This article belongs to the Special Issue Plasma Electrolytic Oxidation (PEO) Coatings)

► Show Figures

Figure 1

15 pages, 11394 KiB

Open AccessArticle

Comparison of Exterior Coatings Applied to Oak Wood as a Function of Natural and Artificial Weathering Exposure

by Eliška Oberhofnerová, Kristýna Šimůnková, Ondřej Dvořák, Irena Štěrbová, Salim Hiziroglu, Přemysl Šedivka and Miloš Pánek

Coatings 2019, 9(12), 864; https://doi.org/10.3390/coatings9120864 - 16 Dec 2019

Cited by 11 | Viewed by 2935

Abstract

Artificial weathering can significantly reduce the testing time needed for proving coating durability, nevertheless its reliability is still not thoroughly proven. In this study, eight different transparent and pigmented coating systems, namely oil, acrylate, alkyd and urethane alkyd were evaluated through natural and [...] Read more.

Artificial weathering can significantly reduce the testing time needed for proving coating durability, nevertheless its reliability is still not thoroughly proven. In this study, eight different transparent and pigmented coating systems, namely oil, acrylate, alkyd and urethane alkyd were evaluated through natural and artificial weathering tests on oak samples by measuring colour, gloss and surface wettability and by macroscopic and microscopic evaluation. The oil coatings performed well in wood colour stability evaluations, while the best gloss and wettability change results were noted for acrylate coatings. Pigmented coatings were characterized by significantly lower colour changes than transparent ones. The gloss and wettability changes were more sensitive to coating disruption than to total colour changes of coated wood associated with chemical changes in wood. The findings in this work showed that values of gloss changes and surface wettability for all types of coatings exposed to artificial and natural weathering resulted in significant differences from each other. The data obtained by artificial weathering method provide basic results of coatings durability and, ideally, natural weathering should be performed at the same time to support the results from laboratory tests by exposing wood under real conditions. Full article

(This article belongs to the Special Issue Advances in Surface Modification and Treatment of Wood)

► Show Figures

Figure 1

12 pages, 7066 KiB

Open AccessArticle

Tunable Plasmonic Resonances in TiN Nanorod Arrays

by Yi-Jun Jen, Teh-Li Chan, Bo-Huei Liao, Zheng-Xing Li, Wei-Chen Liu and Ming-Yang Cong

Coatings 2019, 9(12), 863; https://doi.org/10.3390/coatings9120863 - 16 Dec 2019

Cited by 5 | Viewed by 3067

Abstract

In this work, titanium nitride (TiN) nanorod arrays were fabricated using glancing angle deposition in a magnetron sputtering system. The deposition parameters, including the bias on the substrate and the flow rate of nitrogen, were varied to deposit various TiN nanorod arrays. Before [...] Read more.

In this work, titanium nitride (TiN) nanorod arrays were fabricated using glancing angle deposition in a magnetron sputtering system. The deposition parameters, including the bias on the substrate and the flow rate of nitrogen, were varied to deposit various TiN nanorod arrays. Before glancing angle deposition was conducted, uniform TiN films were deposited and their permittivity spectra, for various deposition parameters, were obtained. The effect of the deposition parameters on the morphology of the nanorods is analyzed here. The polarization-dependent extinctance spectra of TiN nanorod arrays were measured and compared. Extinction, which corresponds to the longitudinal mode of localized surface plasmon resonance, can be significantly changed by tuning the N₂ flow rate and substrate bias voltage during deposition. Full article

(This article belongs to the Section Thin Films)

► Show Figures

Figure 1

15 pages, 12694 KiB

Open AccessArticle

Uptake of Pb(II) Ions from Simulated Aqueous Solution via Nanochitosan

by Camellia Zareie, Saeideh Kholghi Eshkalak, Ghasem Najafpour Darzi, Mazyar Sharifzadeh Baei, Habibollah Younesi and Seeram Ramakrishna

Coatings 2019, 9(12), 862; https://doi.org/10.3390/coatings9120862 - 15 Dec 2019

Cited by 11 | Viewed by 2879

Abstract

In this work, nanochitosan (NC) was prepared through ionic gelation using low molecular weight chitosan and maleic acid (MA). The synthesized NC was characterized by atomic force microscopy (AFM), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). During preparation, the particle [...] Read more.

In this work, nanochitosan (NC) was prepared through ionic gelation using low molecular weight chitosan and maleic acid (MA). The synthesized NC was characterized by atomic force microscopy (AFM), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). During preparation, the particle size of the material depended on parameters such as concentration of chitosan and pH of the aqueous solution. After controlling the mentioned parameters, NC smaller than 100 nm was prepared. The chitosan and prepared NC were employed for the adsorption of Pb(II) from an aqueous solution in the form of a batch system. Among the sorption parameters, pH showed the strongest effect on the sorption process and removal of the maximum number of Pb(II) ions was obtained at pH value of 6. Pseudo-first-order and pseudo-second-order models were used to track the kinetics of the adsorption process. Langmuir and Freundlich’s isotherms were subjected to the absorption data to evaluate absorption capacity. NC proved to be an excellent adsorbent with a remarkable capacity to eliminate Pb(II) ions from aqueous solutions at multiple concentrations. The NC also showed better performance with a comparatively easier preparation process than in other reported work. Full article

(This article belongs to the Special Issue Recent Advances in Bioactive Coatings)

► Show Figures

Figure 1

18 pages, 6697 KiB

Open AccessArticle

Preparation and Performance Test of the Super-Hydrophobic Polyurethane Coating Based on Waste Cooking Oil

by Yingmo Cheng, Dejun Miao, Lingxiao Kong, Jiachen Jiang and Zhenxing Guo

Coatings 2019, 9(12), 861; https://doi.org/10.3390/coatings9120861 - 15 Dec 2019

Cited by 19 | Viewed by 4572

Abstract

In order to solve the problem of dust accumulation on the fin surface of a mine air cooler, a method of preparing super-hydrophobic polyurethane (SPU) coating based on waste cooking oil (WCO) was proposed. Firstly, the polyurethane prepolymer was synthesized with WCO as [...] Read more.

In order to solve the problem of dust accumulation on the fin surface of a mine air cooler, a method of preparing super-hydrophobic polyurethane (SPU) coating based on waste cooking oil (WCO) was proposed. Firstly, the polyurethane prepolymer was synthesized with WCO as a raw material, and then the polyurethane prepolymer was modified with amino-terminated polydimethylsiloxane (ATP) to obtain SPU emulsion. The chemical structure and thermal stability of SPU were characterized by infrared spectrum and thermogravimetric analysis. A series of nanocomposites were prepared by combining modified silicon carbide (APT-SiC) particles and SPU emulsions. According to the parameters of pull-off strength, contact angle, sliding angle and thermal conductivity, the filler ratio of nanocomposites was optimized. The test results show that when the content of APT-SiC particles is 20 wt %, super-hydrophobic polyurethane coating can be obtained. The coating has good pull- off strength and thermal conductivity, and the contact angle and sliding angle are 161° and 3°, respectively. In addition, the practical application of the super-hydrophobic polyurethane coating was tested by related experiments. The experimental results show that the coating has good self-cleaning, wear resistance and anti-corrosion performance, can meet the requirements of air coolers in special environments, and has great application prospects. Full article

► Show Figures

Figure 1

10 pages, 5077 KiB

Open AccessArticle

Self-Cleaning Nanoscale Coating for the Separation of Oil–Water Mixture

by Suboohi Shervani, Jingjing Ling, Jiabin Liu and Tahir Husain

Coatings 2019, 9(12), 860; https://doi.org/10.3390/coatings9120860 - 15 Dec 2019

Cited by 4 | Viewed by 2738

Abstract

The current study pertains to the self-cleaning nanoscale coating of graphene/polymer nanohybrid system for the separation of oil–water mixture. Using a single nanohybrid system, we have developed a two-stage process for the selective removal of the hydrocarbons. Total petroleum hydrocarbons (TPHs) and separation [...] Read more.

The current study pertains to the self-cleaning nanoscale coating of graphene/polymer nanohybrid system for the separation of oil–water mixture. Using a single nanohybrid system, we have developed a two-stage process for the selective removal of the hydrocarbons. Total petroleum hydrocarbons (TPHs) and separation efficiency are determined by gas chromatography-flame ionization detector (GC-FID). Analysis of the polycyclic aromatic hydrocarbons (PAHs) in the two stage samples is carried out by using gas chromatography coupled to mass spectrometry (GC-MS). The analysis shows the reduction in TPHs from 290 ppm to less than 1 ppm and more than 99.5% separation efficiency (oil removal from oil–water mixture) is achieved. No polycyclic aromatic hydrocarbons (PAHs) were detected in the treated water. Full article

► Show Figures

Graphical abstract

9 pages, 3581 KiB

Open AccessArticle

Influence of Annealing Temperature on the Properties of ZnGa₂O₄ Thin Films by Magnetron Sputtering

by Wei-Kai Wang, Kuo-Feng Liu, Pi-Chuen Tsai, Yi-Jie Xu and Shih-Yung Huang

Coatings 2019, 9(12), 859; https://doi.org/10.3390/coatings9120859 - 14 Dec 2019

Cited by 29 | Viewed by 3892

Abstract

Zinc gallate (ZnGa₂O₄) thin films were grown on sapphire (0001) substrate using radio frequency (RF) magnetron sputtering. After the thin film deposition process, the grown ZnGa₂O₄ was annealed at a temperature ranging from 500 to 900 [...] Read more.

Zinc gallate (ZnGa₂O₄) thin films were grown on sapphire (0001) substrate using radio frequency (RF) magnetron sputtering. After the thin film deposition process, the grown ZnGa₂O₄ was annealed at a temperature ranging from 500 to 900 °C at atmospheric conditions. The average crystallite size of the grown ZnGa₂O₄ thin films increased from 11.94 to 27.05 nm as the annealing temperature rose from 500 to 900 °C. Excess Ga released from ZnGa₂O₄ during thermal annealing treatment resulted in the appearance of a Ga₂O₃ phase. High-resolution transmission electron microscope image analysis revealed that the preferential crystallographic orientation of the well-arranged, quasi-single-crystalline ZnGa₂O₄ (111) plane lattice fringes were formed after the thermal annealing process. The effect of crystallite sizes and lattice strain on the width of the X-ray diffraction peak of the annealed ZnGa₂O₄ thin films were investigated using Williamson-Hall analysis. The results indicate that the crystalline quality of the deposited ZnGa₂O₄ thin film improved at higher annealing temperatures. Full article

► Show Figures

Figure 1

12 pages, 7005 KiB

Open AccessArticle

Influence of Different Heat Treatment Temperatures on the Microstructure, Corrosion, and Mechanical Properties Behavior of Fe-Based Amorphous/Nanocrystalline Coatings

by Shenglin Liu, Yongsheng Zhu, Xinyue Lai, Xueping Zheng, Runnan Jia and Xiangsheng Yuan

Coatings 2019, 9(12), 858; https://doi.org/10.3390/coatings9120858 - 14 Dec 2019

Cited by 11 | Viewed by 2339

Abstract

Fe-based amorphous/nanocrystalline coatings with smooth, compact interior structure and low porosity were fabricated via supersonic plasma spraying (SPS). The coatings showed outstanding corrosion resistance in a 3.5% NaCl solution at room temperature. In order to analyze the effect of annealing treatment on the [...] Read more.

Fe-based amorphous/nanocrystalline coatings with smooth, compact interior structure and low porosity were fabricated via supersonic plasma spraying (SPS). The coatings showed outstanding corrosion resistance in a 3.5% NaCl solution at room temperature. In order to analyze the effect of annealing treatment on the microstructure, corrosion resistance and microhardness, the as-sprayed coating was annealed for 1 h under different temperatures such as 350, 450, 550 and 650 °C, respectively. The results showed that the number of oxides and cracks in the coatings presented an obvious increase with increasing annealing temperature, and the corrosion resistance of the coatings showed an obvious reduction. However, the microhardness of coatings showed an important increase. The microhardness of the coating could reach 1018 HV when the heat treatment temperature reached 650 °C. The X-ray diffraction (XRD) results showed that there appeared a number of crystalline phases in the coating when the heat treatment temperature was at 650 °C. The crystalline phases led to the increase of the microhardness. Full article

► Show Figures

Figure 1

9 pages, 1848 KiB

Open AccessFeature PaperArticle

The Excitation of Ultrasound by Laser Radiation in Water Using an Optical Fiber Laser Converter with a 2D Colloidal Crystalline Coating

by Vladimir I. Bredikhin and Viacheslav V. Kazakov

Coatings 2019, 9(12), 857; https://doi.org/10.3390/coatings9120857 - 14 Dec 2019

Cited by 1 | Viewed by 2456

Abstract

The technology of applying a colloidal single-layer coating of transparent polystyrene (PS) Ø 1 μm spheres at the tip face of a quartz fiber has been proposed and tested. Such a coating plays, in a light absorbing liquid, the role of a converter [...] Read more.

The technology of applying a colloidal single-layer coating of transparent polystyrene (PS) Ø 1 μm spheres at the tip face of a quartz fiber has been proposed and tested. Such a coating plays, in a light absorbing liquid, the role of a converter of pulsed laser radiation into acoustic radiation. The generation of ultrasound in water using a converter based on a quartz fiber 1 mm in diameter with a 2D colloidal crystalline coating consisted of polystyrene spheres with a diameter of ~1 μm at the fiber end was investigated. When excited by laser radiation (λ = 1.064 µm), coating of polystyrene spheres created in the liquid a laser thermal microstructure with a characteristic size of fractions of ~λ and a maximum temperature up to 10⁻² degree at an energy in a short laser pulse of ~0.005 J. This short-lived thermal microstructure generated sound pulses in the liquid in the approximately 0.2–4 MHz range. The results of the experimental study of this effect are reported. The proposed laser radiation converter with colloidal coating of the optical fiber distal tip by a single layer of transparent spheres can be used for the development of new laser microtools for studying, processing of various objects in microsurgery, microstructuring of the surface, spot cleaning and restoration of objects of art and history. Full article

(This article belongs to the Special Issue Design, Manufacturing and Measurement of Optical Film Coatings)

► Show Figures

Figure 1

14 pages, 5170 KiB

Open AccessArticle

Investigation on Microstructure, Hardness, and Corrosion Resistance of Mo–Ni–B Coatings Prepared by Laser Cladding Technique

by Xiaojie Ni, Shengze Wang, Yuantao Zhao, Wenge Li and Xiong Jiao

Coatings 2019, 9(12), 856; https://doi.org/10.3390/coatings9120856 - 13 Dec 2019

Cited by 7 | Viewed by 2526

Abstract

The hard and corrosion resistant coatings of Mo₂NiB₂ cermet were prepared by the laser cladding technique. The influences of the Mo:B ratio and the laser scanning speed on the microstructure and property of the Mo₂NiB₂ cermet coatings [...] Read more.

The hard and corrosion resistant coatings of Mo₂NiB₂ cermet were prepared by the laser cladding technique. The influences of the Mo:B ratio and the laser scanning speed on the microstructure and property of the Mo₂NiB₂ cermet coatings were investigated. The results showed that the laser scanning speed of 1.5 mm/s and the Mo:B ratio of 1 were more beneficial to the formation of Mo₂NiB₂ cermet than 2.0 mm/s and 0.8, 1.2, respectively. The amount of the Mo₂NiB₂ ceramic phases were decreased from the top layer to the bottom layer of the coating. The changes of microstructure and composition led to the changes of hardness and corrosion resistance of the Mo₂NiB₂ cermet coatings. The coating prepared at the Mo:B ratio of 1 and the scanning speed of 1.5 mm/s possessed the highest hardness, and the hardness gradually decreased from the top layer to the bottom layer of the coating. The formation of Mo₂NiB₂ and {FeM} phases led to the enhanced corrosion resistance of the Mo₂NiB₂ cermet coatings, and the coating prepared at the Mo:B ratio of 0.8 possessed the best corrosion resistance and the minimum corrosion current. Full article

► Show Figures

Figure 1

14 pages, 8246 KiB

Open AccessFeature PaperArticle

A FEA-Based Methodology to Predict the Osteotome Wear Status during Nasal Bone Surgical Operations

by G. Skordaris, F. Stergioudi, A. Boumpakis, D. Stergioudi and H. Behrbohm

Coatings 2019, 9(12), 855; https://doi.org/10.3390/coatings9120855 - 13 Dec 2019

Cited by 2 | Viewed by 7304

Abstract

A FEA-based methodology was developed in order to predict the wear status of an osteotome (surgical instrument) during its use in a lateral nasal bone osteotomy considering its fatigue strength. The latter parameter was determined by appropriate FEM-evaluation of the perpendicular impact test [...] Read more.

A FEA-based methodology was developed in order to predict the wear status of an osteotome (surgical instrument) during its use in a lateral nasal bone osteotomy considering its fatigue strength. The latter parameter was determined by appropriate FEM-evaluation of the perpendicular impact test results. For the simulation of the surgical procedure, two scenarios were examined: (i) when utilizing a brand new osteotome and (ii) when utilizing an already used osteotome characterized by decreased fatigue strength. The actual nasal bone geometry used in the FEA model was obtained from a high-resolution, maxillofacial, computed tomography (CT) scan of a single patient. In both cases examined, depiction of fracture patterns for the osteotome and the nasal bone were obtained. The wear of a new osteotome and an already used osteotome was also calculated and compared. The developed von Mises stresses in both the osteotome and nasal bone were depicted. The proposed methodology allowed an accurate prediction of the critical number of impacts that the osteotome can receive during the lateral nasal osteotomy which is followed in all rhinoplasties. Based on the developed methodology, a preventive replacement of the osteotome before its extensive fracture can be determined, thereby minimizing the risk of postoperative complications. Full article

(This article belongs to the Section Surface Characterization, Deposition and Modification)

► Show Figures

Figure 1

12 pages, 3412 KiB

Open AccessFeature PaperEditor’s ChoiceArticle

Laser-Assisted Surface Texturing of Ti/Zr Multilayers for Mesenchymal Stem Cell Response

by Suzana Petrović, Davor Peruško, Evangelos Skoulas, Janez Kovač, Miodrag Mitrić, Jelena Potočnik, Zlatko Rakočević and Emmanuel Stratakis

Coatings 2019, 9(12), 854; https://doi.org/10.3390/coatings9120854 - 13 Dec 2019

Cited by 6 | Viewed by 2822

Abstract

The formation of an ordered surface texture with micro and nanometer features on Ti/Zr multilayers is studied for better understanding and improvement of cell integration. Nanocomposite in form 30×(Ti/Zr)/Si thin films was deposited by ion sputtering on Si substrate for biocompatibility investigation. Surface [...] Read more.

The formation of an ordered surface texture with micro and nanometer features on Ti/Zr multilayers is studied for better understanding and improvement of cell integration. Nanocomposite in form 30×(Ti/Zr)/Si thin films was deposited by ion sputtering on Si substrate for biocompatibility investigation. Surface texturing by femtosecond laser processing made it possible to form the laser-induced periodic surface structure (LIPSS) in each laser-written line. At fluence slightly above the ablation threshold, beside the formation of low spatial frequency-LIPSS (LSFL) oriented perpendicular to the direction of the laser polarization, the laser-induced surface oxidation was achieved on the irradiated area. Intermixing between the Ti and Zr layers with the formation of alloy in the sub-surface region was attained during the laser processing. The surface of the Ti/Zr multilayer system with changed composition and topography was used to observe the effect of topography on the survival, adhesion and proliferation of the murine mesenchymal stem cells (MSCs). Confocal and SEM microscopy images showed that cell adhesion and their growth improve on these modified surfaces, with tendency of the cell orientation along of LIPSS in laser-written lines. Full article

(This article belongs to the Special Issue Surface Topography Effects on Functional Properties of PVD Coatings)

► Show Figures

Figure 1

14 pages, 2061 KiB

Open AccessArticle

Experimental and Simulation Study on Tool Life Models in Drilling of Forging Brass Using Uncoated-WC and AlCrN Coated-WC Tools

by Manit Timata and Charnnarong Saikaew

Coatings 2019, 9(12), 853; https://doi.org/10.3390/coatings9120853 - 13 Dec 2019

Cited by 5 | Viewed by 2731

Abstract

Burr is an undesirable phenomenon occurring in drilling operation which is one of the essential operations in the machining industry since it is directly influencing the operating costs. Exit burr height (EBH) values as the function of drilling time during drilling the specific [...] Read more.

Burr is an undesirable phenomenon occurring in drilling operation which is one of the essential operations in the machining industry since it is directly influencing the operating costs. Exit burr height (EBH) values as the function of drilling time during drilling the specific holes of the forging brass workpieces used for producing the water-valve components with the uncoated- tungsten carbide (WC) and the AlCrN coated-WC drills were discussed. The data sets of drilling time, corresponding to EBH values at the appropriate criterion were used to develop the tool life models in terms of cutting speed and feed rate using Taylor’s equation. Monte Carlo simulation was adopted to study the uncertainty of cutting speed and feed rate on tool life predictions for sensitivity analysis. The results showed that drilling with a low feed rate decreased the averages of EBH. The predicted tool life values of the AlCrN coated-WC drills were higher than those of the uncoated-WC ones based on the results of tool life predictions. The appropriate operating condition of the cutting speed of 60 m/min and the feed rate of 0.2 mm/rev was recommended for manufacturers in the drilling of the forging brass workpieces using the AlCrN coated-WC drills. Moreover, the predicted tool life values for the uncoated-WC and the AlCrN coated-WC drills were about 600 and 800 min, respectively. This indicated that the AlCrN coated-WC drill increased tool life by 30%. Full article

► Show Figures

Figure 1

13 pages, 4347 KiB

Open AccessArticle

Effect of Asymmetric Epoxy Coating/Metal Electrodes on the Electrochemical Noise Measurements Under Marine Alternating Hydrostatic Pressure

by Fandi Meng, Yushan Liu, Li Liu, Yu Cui and Fuhui Wang

Coatings 2019, 9(12), 852; https://doi.org/10.3390/coatings9120852 - 12 Dec 2019

Cited by 5 | Viewed by 2166

Abstract

Electrochemical noise (EN) is expected to be an in-situ evaluation method for coating performance in the real deep-ocean environment. The asymmetric factors of working electrodes (WEs) in EN configuration, including coating area, coating thickness, and coating impedance, were considered under marine alternating hydrostatic [...] Read more.

Electrochemical noise (EN) is expected to be an in-situ evaluation method for coating performance in the real deep-ocean environment. The asymmetric factors of working electrodes (WEs) in EN configuration, including coating area, coating thickness, and coating impedance, were considered under marine alternating hydrostatic pressure (AHP) condition. The effect of WE asymmetry was discussed mainly by EN time records, wavelet analysis and shot noise method. The results indicated that coating impedance is the most important factor, and the coating with higher impedance contributes more to current noise in a pair of electrodes. The reason of asymmetry influence on EN measurements is mainly by the variation of average charge of current sources but not the current source frequency during the initial period of coating failure process. When the obvious corrosion of metal substrate happens, the corresponding EN proportion relationship between coating/metal WEs may be not exist. Full article

► Show Figures

Figure 1

13 pages, 8125 KiB

Open AccessArticle

Improving Thickness Uniformity of Mo/Si Multilayers on Curved Spherical Substrates by a Masking Technique

by Zhe Zhang, Runze Qi, Yiyun Yao, Yingna Shi, Wenbin Li, Qiushi Huang, Shengzhen Yi, Zhong Zhang, Zhanshan Wang and Chun Xie

Coatings 2019, 9(12), 851; https://doi.org/10.3390/coatings9120851 - 12 Dec 2019

Cited by 9 | Viewed by 3601

Abstract

In this work, a masking technique was used to improve the thickness uniformity of a Mo/Si multilayer deposited on a curved spherical mirror by direct current (DC) magnetron sputtering with planetary rotation stages. The clear aperture of the mirror was 125 mm with [...] Read more.

In this work, a masking technique was used to improve the thickness uniformity of a Mo/Si multilayer deposited on a curved spherical mirror by direct current (DC) magnetron sputtering with planetary rotation stages. The clear aperture of the mirror was 125 mm with a radius of curvature equal to 143.82 mm. Two different shadow masks were prepared; one was flat and the other was oblique. When using the flat mask, the non-uniformity considerably increased owing to the relatively large gap between the mask and substrate. The deviation between the designed and measured layer thickness and non-uniformity gradually reduced with a smaller gap. The second mask was designed with an oblique profile. Using the oblique mask, the deviation from multilayer thickness uniformity was substantially reduced to a magnitude below 0.8% on the curved spherical substrate over the clear aperture of 125 mm. Multilayers still achieved a smooth growth when deposited with obliquely incident particles. The facile masking technique proposed in this study can be used for depositing uniform coatings on curved spherical substrates with large numerical apertures for high-resolution microscopes, telescopes, and other related optical systems. Full article

► Show Figures

Figure 1

13 pages, 4879 KiB

Open AccessArticle

Facile Preparation of Bilayer Titanium Silicate (TS-1) Zeolite Membranes by Periodical Secondary Growth

by Qi Zhang, Yong Liu, Xuguang Liu and Laibo Ma

Coatings 2019, 9(12), 850; https://doi.org/10.3390/coatings9120850 - 12 Dec 2019

Cited by 2 | Viewed by 2317

Abstract

A facile periodical secondary growth method, based on conventional secondary growth, is proposed to prepare bilayer TS-1 membranes. The novel periodical secondary growth consists of two or several periods, which involve three steps: the temperature is programmed to a desired crystallization temperature as [...] Read more.

A facile periodical secondary growth method, based on conventional secondary growth, is proposed to prepare bilayer TS-1 membranes. The novel periodical secondary growth consists of two or several periods, which involve three steps: the temperature is programmed to a desired crystallization temperature as the first stage, followed by holding for a certain duration, and finally cooling to room temperature. This periodical crystallization model enables a bilayer TS-1 membrane to be produced, while the conventional secondary growth method produces a monolayer TS-1 membrane. The bilayer TS-1 membrane exhibits a superior defect-free structure and hydrophobic properties, as illustrated by SEM, gas permeance, pore size distribution analysis, and water contact angle measurement. It displays an earlier desalination separation factor compared to the monolayer TS-1 membrane. This work demonstrates that the periodical secondary growth is an advanced approach for preparing a bilayer zeolite membrane with excellent properties. Full article

(This article belongs to the Section Thin Films)

► Show Figures

Graphical abstract

19 pages, 4808 KiB

Open AccessArticle

Impact of Second-Order Slip and Double Stratification Coatings on 3D MHD Williamson Nanofluid Flow with Cattaneo–Christov Heat Flux

by Muhammad Ramzan, Asma Liaquet, Seifedine Kadry, Sungil Yu, Yunyoung Nam and Dianchen Lu

Coatings 2019, 9(12), 849; https://doi.org/10.3390/coatings9120849 - 11 Dec 2019

Cited by 27 | Viewed by 2688

Abstract

The present research examines the impact of second-order slip with thermal and solutal stratification coatings on three-dimensional (3D) Williamson nanofluid flow past a bidirectional stretched surface and envisages it analytically. The novelty of the analysis is strengthened by Cattaneo–Christov (CC) heat flux accompanying [...] Read more.

The present research examines the impact of second-order slip with thermal and solutal stratification coatings on three-dimensional (3D) Williamson nanofluid flow past a bidirectional stretched surface and envisages it analytically. The novelty of the analysis is strengthened by Cattaneo–Christov (CC) heat flux accompanying varying thermal conductivity. The appropriate set of transformations is implemented to get a differential equation system with high nonlinearity. The structure is addressed via the homotopy analysis technique. The authenticity of the presented model is verified by creating a comparison with the limited published results and finding harmony between the two. The impacts of miscellaneous arising parameters are deliberated through graphical structures. Some useful tabulated values of arising parameters versus physical quantities are also discussed here. It is observed that velocity components exhibit an opposite trend with respect to the stretching ratio parameter. Moreover, the Brownian motion parameter shows the opposite behavior versus temperature and concentration distributions. Full article

(This article belongs to the Special Issue Recent Trends in Coatings and Thin Film–Modeling and Application)

► Show Figures

Figure 1

13 pages, 7501 KiB

Open AccessArticle

Effect of Trajectory Curvature on the Microstructure and Properties of Surfacing Wall Formed with the Process of Wire Arc Additive Manufacturing

by Tao Feng, Lishi Wang, Zhongmin Tang, Shanwen Yu, Zhixiang Bu, Xinbin Hu and Yihang Cheng

Coatings 2019, 9(12), 848; https://doi.org/10.3390/coatings9120848 - 11 Dec 2019

Cited by 3 | Viewed by 2335

Abstract

Curvature effects are typically present in the process of additive manufacturing (AM), particularly for wire arc additive manufacturing. In this paper, stainless-steel wire was adopted to deposit thin-walled samples with different curvatures. Optical microscopy, SEM, EDS and micro-hardness was used to analyse the [...] Read more.

Curvature effects are typically present in the process of additive manufacturing (AM), particularly for wire arc additive manufacturing. In this paper, stainless-steel wire was adopted to deposit thin-walled samples with different curvatures. Optical microscopy, SEM, EDS and micro-hardness was used to analyse the microstructure, composition and properties of the samples. The result shows that the bottom region of the thin-walled sample had a mainly planar and cellular crystal microstructure. For the middle region, the microstructure revealed mainly dendrites, and the top layer has equiaxed dendrite morphology. The microhardness value of the bottom was greater than that of the middle, and the microhardness value of the middle was greater than that of the top. Moreover, the grain size of the inner part (direct to curvature radius) was larger than that of the outer part, and the micro-hardness value exhibited an increasing tendency from the inner to the outer side. With enlarging curvature, the degree of grain size differences and micro-hardness variants decreased. Finally, an investigation with a low carbon steel wire showed that it had a similar curvature effect for its AM specimen. Full article

► Show Figures

Figure 1

16 pages, 5542 KiB

Open AccessArticle

Enhanced XRF Methods for Investigating the Erosion-Resistant Functional Coatings

by Mihail Lungu, Cosmin Dobrea and Ion Tiseanu

Coatings 2019, 9(12), 847; https://doi.org/10.3390/coatings9120847 - 10 Dec 2019

Cited by 2 | Viewed by 3467

Abstract

The development of erosion-resistant functional materials usable as plasma facing first wall components (PFC) is crucial for increasing the lifetime of future fusion reactors. Generally, PFCs have to be quality checked and characterized regarding their composition, before integrating them into the fusion reactor [...] Read more.

The development of erosion-resistant functional materials usable as plasma facing first wall components (PFC) is crucial for increasing the lifetime of future fusion reactors. Generally, PFCs have to be quality checked and characterized regarding their composition, before integrating them into the fusion reactor vessel. Enhanced X-ray fluorescence (XRF) methods represent an effective alternative to conventional analysis methods for the characterization of refractive metallic coatings on large areas of fusion materials. We have developed and applied XRF methods as fast and robust methods for the characterization of the thickness and composition uniformity of complex functional coatings. These coatings consist of tungsten included in multilayer configuration and deposited on low or high Z substrates. We have further developed customized calibration protocols for quantifying the element composition and layer thickness of each investigated sample. The calibration protocols are based on a combination of standard samples measurements, Monte Carlo simulations, and fundamental parameter theoretical calculations. The calibrated results are discussed considering a selection of relevant PFC samples. The deposition uniformity was successfully investigated for different PFC-relevant tiles and lamella shaped samples with W layers below and over the W L-line saturation thickness. Also, the 2D thickness mapping capability of the XRF method was demonstrated by studying the plasma post-erosion pattern. Full article

(This article belongs to the Section Surface Characterization, Deposition and Modification)

► Show Figures

Figure 1

9 pages, 1605 KiB

Open AccessArticle

A Note on the Surface Deterioration of Scrimber Composites Exposed to Artificial Ageing

by Minzhen Bao, Fei Rao, Sheng He, Yongjie Bao, Zaixing Wu, Neng Li and Yuhe Chen

Coatings 2019, 9(12), 846; https://doi.org/10.3390/coatings9120846 - 10 Dec 2019

Cited by 6 | Viewed by 1770

Abstract

The effect of ultraviolet radiation on the surface deterioration of scrimber composites with different densities and levels of resin content was investigated for this paper. The surface color, gloss, roughness, and wettability of the samples were investigated to determine the extent of surface [...] Read more.

The effect of ultraviolet radiation on the surface deterioration of scrimber composites with different densities and levels of resin content was investigated for this paper. The surface color, gloss, roughness, and wettability of the samples were investigated to determine the extent of surface changes due to accelerated ageing. The results indicated that all scrimber composites exhibited variation in the color of their surfaces during artificial xenon light exposure. After artificial accelerated ageing, the surface contact angle and roughness were found to increase, whereas the surface gloss and surface free energy decreased. Furthermore, it was observed that the density and resin content of the scrimber composites contributed to reductions in their color variation, wettability, and roughness during weathering, which suggested that the density and resin content played important roles in determining their surface photodegradation properties. Artificial ageing resulted in the degradation of lignin and hemicellulose, thus causing severe surface characteristics. Full article

► Show Figures

Figure 1

12 pages, 4387 KiB

Open AccessEditor’s ChoiceArticle

Structure Investigation of Titanium Metallization Coating Deposited onto AlN Ceramics Substrate by Means of Friction Surfacing Process

by Tomasz Chmielewski, Michał Hudycz, Arkadiusz Krajewski, Tadeusz Sałaciński, Beata Skowrońska and Rafał Świercz

Coatings 2019, 9(12), 845; https://doi.org/10.3390/coatings9120845 - 10 Dec 2019

Cited by 20 | Viewed by 3310

Abstract

The article presents selected properties of a titanium metallization coating deposited on aluminum nitride (AlN) ceramics surface by means of the friction surfacing method. Its mechanism is based on the formation of a joint between the surface of an AlN ceramics substrate and [...] Read more.

The article presents selected properties of a titanium metallization coating deposited on aluminum nitride (AlN) ceramics surface by means of the friction surfacing method. Its mechanism is based on the formation of a joint between the surface of an AlN ceramics substrate and a thin Ti coating, involving a kinetic energy of friction, which is directly converted into heat and delivered in a precisely defined quantity to the resulting joint. The largest effects on the final properties of the obtained coating include the high affinity of titanium for oxygen and nitrogen and a relatively high temperature for the deposition process. The titanium metallization coating was characterized in terms of surface stereometric structure, thickness, surface morphology, metallographic microstructural properties, and phase structure. The titanium coating has a thickness ranging from 3 to 7 μm. The phase structure of the coating surface (XPS investigated) is dominated by TiN_xO_y with the presence of TiO_x, TiN, metallic Ti, and AlN. The phase structure deeper below the surface (XRD investigated) is dominated by metallic Ti with additional AlN particles originating from the ceramic substrate due to friction by titanium tools. Full article

(This article belongs to the Special Issue Recent Advances in Friction Stir Processed Coatings)

► Show Figures

Figure 1

13 pages, 3299 KiB

Open AccessArticle

One-Step Preparation of Hyperbranched Polyether Functionalized Graphene Oxide for Improved Corrosion Resistance of Epoxy Coatings

by Xuepei Miao, An Xing, Lifan He, Yan Meng and Xiaoyu Li

Coatings 2019, 9(12), 844; https://doi.org/10.3390/coatings9120844 - 10 Dec 2019

Cited by 5 | Viewed by 2802

Abstract

In this paper, hyperbranched polyether functionalized graphene oxide (EHBPE-GO) was prepared by a facile one-step method. Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD), thermogravimetric analyzer (TGA), and trans-mission electron microscopy (TEM) results confirmed the formation of EHBPE-GO. Then, EHBPE-GO was cured with [...] Read more.

In this paper, hyperbranched polyether functionalized graphene oxide (EHBPE-GO) was prepared by a facile one-step method. Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD), thermogravimetric analyzer (TGA), and trans-mission electron microscopy (TEM) results confirmed the formation of EHBPE-GO. Then, EHBPE-GO was cured with phenolic amides at room temperature to prepare epoxy coatings. The corrosion resistance of epoxy coatings was investigated systematically by using electrochemical and traditional immersion methods. Results show that a small amount of EHBPE-GO (8 wt % of Diglycidyl ether of bisphenol A (DGEBA)) in epoxy coating achieves 50% higher improvement in acid-resistance than unmodified neat DGEBA resin. For the nanocomposite epoxy coating, the superior acid-resistance is attributed to the increased crosslink density and the impermeable 2D structure of EHBPE-GO. This work provides a facile strategy to develop the effective improved corrosion resistance nanofiller for epoxy coating. Full article

► Show Figures

Figure 1

16 pages, 9389 KiB

Open AccessFeature PaperArticle

On Friction Reduction by Surface Modifications in the TEHL Cam/Tappet-Contact-Experimental and Numerical Studies

by Max Marian, Tim Weikert and Stephan Tremmel

Coatings 2019, 9(12), 843; https://doi.org/10.3390/coatings9120843 - 09 Dec 2019

Cited by 26 | Viewed by 5158

Abstract

The overall energy efficiency of machine elements and engine components could be improved by using new technologies such as surface modifications. In the literature, surface engineering approaches like micro-texturing and the application of diamond-like carbon (DLC) coatings were frequently studied separately, with focus [...] Read more.

The overall energy efficiency of machine elements and engine components could be improved by using new technologies such as surface modifications. In the literature, surface engineering approaches like micro-texturing and the application of diamond-like carbon (DLC) coatings were frequently studied separately, with focus on a specific model contact and lubrication conditions. The contribution of the current study is to elucidate and compare the underlying friction reduction mechanisms of the aforementioned surface modifications in an application-orientated manner. The study applied the operating conditions of the thermo-elastohydrodynamically lubricated (TEHL) cam/tappet-contact of the valve train. Therefore, tribological cam/bucket tappet component Stribeck tests were used to determine the friction behavior of ultrashort pulse laser fabricated microtextures and PVD/PECVD deposited silicon-doped amorphous carbon coatings. Moreover, advanced surface characterization methods, as well as numerical TEHL tribo-simulations, were utilized to explore the mechanisms responsible for the observed tribological effects. The results showed that the DLC-coating could reduce the solid and fluid friction force in a wide range of lubrication regimes. Conversely, micro-texturing may reduce solid friction while increasing the fraction of fluid friction. Full article

(This article belongs to the Special Issue Tribological Behavior of Functional Surface: Models and Methods)

► Show Figures

Graphical abstract

22 pages, 1032 KiB

Open AccessArticle

Finite Element Simulation of Multi-Slip Effects on Unsteady MHD Bioconvective Micropolar Nanofluid Flow Over a Sheet with Solutal and Thermal Convective Boundary Conditions

by Liaqat Ali, Xiaomin Liu, Bagh Ali, Saima Mujeed and Sohaib Abdal

Coatings 2019, 9(12), 842; https://doi.org/10.3390/coatings9120842 - 09 Dec 2019

Cited by 101 | Viewed by 3473

Abstract

In this article, the intention is to explore the flow of a magneto-hydrodynamic (MHD) bioconvective micro-polar Nanofluid restraining microorganism. The numerical solution of 2-D laminar bioconvective boundary layer flow of micro-polar nanofluids are presented. The phenomena of multi-slip, convective thermal and Solutal boundary [...] Read more.

In this article, the intention is to explore the flow of a magneto-hydrodynamic (MHD) bioconvective micro-polar Nanofluid restraining microorganism. The numerical solution of 2-D laminar bioconvective boundary layer flow of micro-polar nanofluids are presented. The phenomena of multi-slip, convective thermal and Solutal boundary conditions have been integrated. A system of non-linear partial differential equations are transformed into the system of coupled nonlinear ordinary differential equations by applying appropriate transformations, the transformed equations are then solved by applying the variational finite element method (FEM). The fascinating features of assorted velocity parameter, microrotation, temperature, microorganism compactness, solutal and nanoparticles concentration have been inspected. The rate of heat transfer, the skin friction coefficient, couple stress and Sherwood number for microorganisms have also been discussed graphically and numerically. The investigations illustrated that increase in material parameters causes a reduction in microorganism compactness, concentration and temperature. As a result of enhancement in the unsteadiness parameter, the fluid velocity, concentration of microorganisms and the temperature are observed to be declines. Energy and microorganism compactness profile affected by the improvement in the buoyancy ratio parameter. As the improvement in results of buoyancy ratio parameter effects on improvement in the energy and the microorganism compactness profile while the velocity profile is condensed. In the end, rationalized convergence of the finite element solution has been inspected; the computations are found out via depreciating the mesh size. Full article

► Show Figures

Figure 1

16 pages, 3746 KiB

Open AccessArticle

Corrosion Resistant TiTaN and TiTaAlN Thin Films Grown by Hybrid HiPIMS/DCMS Using Synchronized Pulsed Substrate Bias with No External Substrate Heating

by Yuri Chipatecua Godoy, Olof Tengstrand, Jairo Olaya Florez, Ivan Petrov, Erika Bustos, Lars Hultman, Alberto Herrera-Gomez, J.E. Greene and Grzegorz Greczynski

Coatings 2019, 9(12), 841; https://doi.org/10.3390/coatings9120841 - 09 Dec 2019

Cited by 5 | Viewed by 3003

Abstract

Ti_0.92Ta_0.08N and Ti_0.41Al_0.51Ta_0.08N thin films grown on stainless-steel substrates, with no external heating, by hybrid high-power impulse and dc magnetron sputtering (HiPIMS/DCMS), were investigated for corrosion resistance. The Ta target was operated in [...] Read more.

Ti_0.92Ta_0.08N and Ti_0.41Al_0.51Ta_0.08N thin films grown on stainless-steel substrates, with no external heating, by hybrid high-power impulse and dc magnetron sputtering (HiPIMS/DCMS), were investigated for corrosion resistance. The Ta target was operated in HiPIMS mode to supply pulsed Ta-ion fluxes, while two Ti (or Ti and Al) targets were operated in DCSM mode in order to provide a high deposition rate. Corrosion resistance was investigated using potentiodynamic polarization and electrochemical impedance spectroscopy employing a 3.5% NaCl solution at room temperature. The 300-nm-thick transition-metal nitride coatings exhibited good corrosion resistance due to film densification resulting from pulsed heavy Ta-ion irradiation during film growth. Corrosion protective efficiencies were above 99.8% for both Ti_0.41Al_0.51Ta_0.08N and Ti_0.92Ta_0.08N, and pore resistance was apparently four orders of magnitude higher than for bare 304 stainless-steel substrates. Full article

(This article belongs to the Section Corrosion, Wear and Erosion)

► Show Figures

Figure 1

16 pages, 6585 KiB

Open AccessArticle

Microstructure, Mechanical Properties and Wear Behavior of High-Velocity Oxygen-Fuel (HVOF) Sprayed (Cr₃C₂-NiCr+Al) Composite Coating on Ductile Cast Iron

by Marzanna Ksiazek, Lukasz Boron and Adam Tchorz

Coatings 2019, 9(12), 840; https://doi.org/10.3390/coatings9120840 - 09 Dec 2019

Cited by 10 | Viewed by 3191

Abstract

In the present work Cr₃C₂-NiCr powder containing Al particles was deposited on ductile cast iron with high-velocity oxy-fuel (HVOF) thermal spray coating technique. An investigation was conducted to determine the role of Al particles in the Cr₃C [...] Read more.

In the present work Cr₃C₂-NiCr powder containing Al particles was deposited on ductile cast iron with high-velocity oxy-fuel (HVOF) thermal spray coating technique. An investigation was conducted to determine the role of Al particles in the Cr₃C₂-NiCr coating produced with HVOF technique on microstructure, mechanical and wear properties in a system Cr₂C₃-NiCr coating/ductile cast iron. The microstructure of the HVOF-sprayed Cr₃C₂-NiCr+Al coating was characterized by light microscopy, X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM) and energy dispersive X-ray spectroscopy (EDS). Microstructure analysis reveals the formation of coating with low porosity, good adhesion to the substrate and dense structure with irregularly shaped particles of Al arranged in strips and finely fragmented Cr₃C₂ particles embedded in a nanocrystalline Ni-Cr alloy matrix. In addition, the results were discussed in reference to examination of bending strength considering cracking and delamination in the system of (Cr₃C₂-NiCr+Al)/ductile cast iron as well as microhardness and wear resistance of the coating. It was found that the addition of Al particles significantly increased resistance to cracking and wear behaviour in the studied system. Full article

(This article belongs to the Section Plasma Coatings, Surfaces & Interfaces)

► Show Figures

Figure 1

15 pages, 7129 KiB

Open AccessArticle

Non-Evaporable Getter Ti-V-Hf-Zr Film Coating on Laser-Treated Aluminum Alloy Substrate for Electron Cloud Mitigation

by Jie Wang, Yong Gao, Zhiming You, Jiakun Fan, Jing Zhang, Zhaopeng Qiao, Sheng Wang and Zhanglian Xu

Coatings 2019, 9(12), 839; https://doi.org/10.3390/coatings9120839 - 09 Dec 2019

Cited by 4 | Viewed by 2784

Abstract

For improving the vacuum and mitigating the electron clouds in ultra-high vacuum chamber systems of high-energy accelerators, the deposition of Ti-V-Hf-Zr getter film on a laser-treated aluminum alloy substrate was proposed and exploited for the first time in this study. The laser-treated aluminum [...] Read more.

For improving the vacuum and mitigating the electron clouds in ultra-high vacuum chamber systems of high-energy accelerators, the deposition of Ti-V-Hf-Zr getter film on a laser-treated aluminum alloy substrate was proposed and exploited for the first time in this study. The laser-treated aluminum surface exhibits a low secondary electron yield (SEY), which is even lower than 1 for some selected laser parameters. Non-evaporable getter (NEG) Ti-V-Hf-Zr film coatings were prepared using the direct current (DC) sputtering method. The surface morphology, surface roughness and composition of Ti-V-Hf-Zr getter films were characterized and analyzed. The maximum SEY of unactivated Ti-V-Hf-Zr getter film on laser-treated aluminum alloy substrates ranged from 1.10 to 1.48. The X-ray photoelectron spectroscopy (XPS) spectra demonstrate that the Ti-V-Hf-Zr coated laser-treated aluminum alloy could be partially activated after being heated at 100 and 150 °C, respectively, for 1 h in a vacuum and also used as a pump. The results were demonstrated initially and the potential application should be considered in future particle accelerators. Full article

(This article belongs to the Section Surface Characterization, Deposition and Modification)

► Show Figures

Figure 1

Journal Menu

Journal Browser

Coatings, Volume 9, Issue 12 (December 2019) – 98 articles

Further Information

Guidelines

MDPI Initiatives

Follow MDPI