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Article

Cementitious Backfill with Partial Replacement of Cu-Rich Mine Tailings by Sand: Rheological, Mechanical and Microstructural Properties

1
Geotechnical, Waste Management and Backfill Laboratory, Recep Tayyip Erdogan University, Fener, Rize TR53100, Türkiye
2
Institute of Graduate Studies, Recep Tayyip Erdogan University, Fener, Rize TR53100, Türkiye
3
Department of Civil Engineering, Geotechnical Division, Recep Tayyip Erdogan University, Fener, Rize TR53100, Türkiye
*
Author to whom correspondence should be addressed.
Minerals 2023, 13(3), 437; https://doi.org/10.3390/min13030437
Submission received: 24 February 2023 / Revised: 10 March 2023 / Accepted: 17 March 2023 / Published: 18 March 2023
(This article belongs to the Special Issue Solid-Filling Technology in Coal Mining)

Abstract

:
The thinning of tailings gradation during ore processing leads to a sizeable fall in the strength of cementitious paste backfill (CPB), increases operational risks, and encourages researchers to use alternative economic products. This study aims to increase the strength performance by improving CPB’s gradation while cutting costs and reducing the sum of the binder employed per unit volume. An evolution of the slump/strength/structural properties of sand-substituted CPBs was explored experimentally. Samples were made with a fixed cement content (7 wt.%), diverse tailings/sand fractions (e.g., 100/0, 90/10, 80/20, 70/30, and 50/50), and diverse solid contents (e.g., 72 and 76 wt.%). After curing for 3–56 days, several experiments, such as slump, uniaxial compressive strength (UCS), mercury intrusion porosimetry (MIP), and scanning electron microscopy (SEM), were undertaken for the filling samples. The results demonstrate that adding sand to the backfill greatly increases CPB’s strength (up to 99%), but the replacement rate of sand was limited to 30% due to its segregation effect. Microstructural tests reveal that CPB’s void volume decreases as the added amount of sand increases. To sum up, it was concluded that calcareous sand made a major contribution to the filling strength, incorporating the effects of enhancing the fill gradation’s readjustment and reducing the sum of cement being used in the unit volume for CPB manufacturing.

1. Introduction

In recent years, huge tailings were generated while extracting ore from the mining industry to create major economic (e.g., high capital/operating costs), social (e.g., strict governmental rules and public awareness), and environmental (e.g., acid mine drainage AMD) problems [1,2,3]. Considering this situation, the research and development of effective tailings disposal methods or technologies have become inevitable today [4,5]. One of the most innovative tailings discarding ways is to employ a cementitious paste backfill (CPB) for modern mines [6,7,8]. CPB significantly reduces the environmental risks of AMD and heavy metals while eliminating the requirement for surface tailings disposal areas [9,10,11]. In addition, CPB economically helps to provide an efficient cost-ground support tool for underground structures [12,13,14]. It is a composite mixture of tailings (65–85 wt.% solids), cement (by a dosage of 2–8 wt.%), and mixing water (e.g., process, lake, and tap) [15,16]. Sometimes, different mineral (e.g., slag and fly ash) and chemical (e.g., plasticizer) additives can be added to CPB mixtures [17,18]. The physicochemical/mineralogical characteristics of tailings directly govern the quality/behavior of the manufactured CPB mixtures [19,20]. However, the reduction in particle size for the extraction of low-grade ores during milling adversely affects tailings’ physical properties (e.g., lower size of particles) [21,22,23]. CPB with finer tailings particles leads to lower uniaxial compressive strength values than that of coarser tailings particles [24,25,26]. As a creative solution to low aggregate material in the tailings, sand with relatively coarse particles can be the remedy for high backfill performance [27,28,29]. Inert materials such as sand can modify the gradation of finer tailings by bringing them to an appropriate grain size distribution [30,31].
The particle size of the sand gained by crushing/grinding operations greatly affects properties such as the void ratio and fluidity of cemented mixtures [32,33]. Well-graded sand has a lower void ratio which contributes positively to the final strength of cemented mixtures [34,35]. Similarly, the thinning of the particle size of sand increases its corresponding surface area and ensures that the grains gain a smooth structure [36]. In addition, coarser and angular sands increase the friction between particles, which has a remarkable factor in the development of the filling strength [37,38]. However, the excessive use of coarser sands in the mixture increases voids between particles (it needs high cement dosages to reach equal strengths for CPB) and can cause several operational problems (e.g., segregation, blockages, and failure) during pipeline transportation [39,40,41]. Hence, the amount of sand used in the mixture needs to be adjusted carefully to avoid these problems. In addition to the physical and rheological properties of sand, it’s chemical/mineralogical properties also affect the overall performance of CPB mixtures [42,43].
Many researchers have addressed this issue by investigating them from different aspects. Yang et al. [44] presented a flow experiment to guess the density drops in the pipeline of CPB prepared with cemented Gobi sand and tailings and found that their model could efficiently envisage the gravity drop in Bingham liquids exhibiting a laminar movement in the pipe. Zhou et al. [45] conducted an experimental study using OPC/fly ash as cement and sand as aggregate for backfilling in comparison to conventional CPB without fly ash and sand additives. They found that CPB specimens had a large bleeding rate and early (0.2–0.4 MPa) and that the late (7–9 MPa) compressive strengths of CPB were quite low. Sun et al. [46] explored the strength gaining of Aeolian sand-based filling mixes with different aspects (e.g., sand, fly ash, water, cement) at times that elapsed from 1 day to 28 days. They found that CPB samples prepared with Aeolian sand showed a rise in the strengths for the first 7-days of curing, but the strengths of CPB gradually decreased with increasing sand content (e.g., 70%) for 28 days of curing. They investigated the microstructural changes of 28-day cured fills consisting of tailings/sand mixtures and stated that adding a 5 wt.% cement to CPB mixture resulted in a significant reduction (five folds) in the pore size. Deng et al. [47] indicated that the strength of CPB consisting of waste rock/fly ash/lime/cement (as coarse aggregate/fine aggregate/activator/binder) improved with a large growth in solids of up to 75%, but a decrease in water content reduced workability clearly.
Although there are many studies on the use of diverse additives as a tailing’s replacement material for CPB, the use of sand as an alternative product is still a key issue that requires detailed research [48,49,50]. This paper aims to investigate the performance of sand when used as a substitute for tailings in CPB by considering different aspects: two different solid contents (72 and 76 wt.%), three different tailings/sand ratios (90/10, 70/30, and 50/50 wt.%), and CEM-I 42.5R (7 wt.%). Some rheological (slump), mechanical (uniaxial compressive strength UCS), and microstructural (scanning electron microscopy SEM, X-Ray fluorescence spectroscopy XRF and mercury intrusion porosimetry MIP) experiments were undertaken for the backfills prepared with crushed sand. This paper also includes some useful thoughts about the trials achieved and the key outcomes when sand was added CPBs.

2. Materials and Methods

2.1. Materials

2.1.1. Sieved Sand

The sand obtained from a quarry around the mine under the test was employed for making mine backfill specimens. Figure 1 indicates the sand’s particle size distribution (PSD) curve. It is apparent that the sand’s D50 value was found to be 1.12 mm while its maximum particle size was under 3.35 mm. This sieve size reflects the allowable maximum particle size within transportable paste backfill mixtures into underground stopes via a pipeline. The tested sand was well graded as the coefficient of curvature, Cc, varied from 1 to 3 (in this case, this value was computed as 1.35) while the coefficient of uniformity, Cu, was higher than 6 (in this case, this value was computed as 13.1). Table 1 also lists some physical properties of the sand used. The sand’s specific gravity GS and surface area SS values were found to be 2.63 and 0.71 m2/g, respectively.
The sand’s composition was chemically analyzed by the PANalytical/Epsilon 5 energy dispersion XRF spectrometry. Table 2 lists the sand’s chemical composition. One can see clearly that the major oxide within the sand was calcium oxide (CaO: 55.6%), while the minor phases within the sand were silicon dioxide (SiO2: 1.85%) and aluminum oxide (Al2O3: 1.51%). Note that the loss-on-ignition (LOI) was relatively high (41.28%).

2.1.2. Copper Tailings

The Cu-rich mine tailings were employed for paste backfill manufacturing. The PSD analysis of the studied tailings sample was measured by a Malvern Mastersizer 2000 laser granulometer (able to measure particles up to 2 mm). Figure 1 indicates the tailings’ particle size distribution (PSD) curve. One can infer that the tailings’ fines content (−20 µm) was 28.8% (it can be classified as coarse-sized tailings when compared to a standard material content ranging from 15% to 35%, based on Landriault’s tailings sorting method). GS and SS values for the tailings sample were found to be 3.55 and 2.89 m2/g, respectively. Table 1 also indicates some basic physical properties of the tailings.
The tailings’ chemistry was also analyzed by XRF spectrometry. Table 2 indicates the tailings’ oxide analysis result. One can visibly infer that iron oxide (Fe2O3: 41.8%) and silicon dioxide (SiO2: 26.5%) were redetected as major oxide phases. In addition, copper grades within processing tailings varied between 0.13 and 1.18 mg/L.

2.1.3. Cement and Mixing Water

In this study, CEM I 42.5R was adopted as the cement. Table 2 tabulates the oxide analysis results of cement. CaO and SiO2 contents were detected as 64.5% and 16.9%, respectively. Table 1 also indicates the cement’s key characteristics. The cement’s specific gravity and specific surface were 3.12 and 0.43 m2/g, respectively. To thoroughly blend the key ingredients (tailings/sand/cement), only tap water was used as mixing water.

2.2. CPB Manufacturing

CPBs were prepared in the lab, respecting the recipes that were pre-determined. Table 3 indicates the CPB recipe design. According to the selected cement content (7 wt.%), the addition of sand to CPB (72/76 wt.% solid contents) was adjusted to 0% (control), 10%, 20%, 30%, and 50% of the total tailings mass, respectively. The backfill amounts were first weighed with the help of precision scales. Tailings and water were blended in a 10-L capacity UTEST mixer for 3 min. Ordinary Portland Cement (OPC) and sand were then added and mixed for another 4 min.
To achieve the wanted slump for CPB samples, the total time required was determined as 7 min. Each mixture was then compressed 25 times with the aid of a steel rod and placed in the mini-slump cone in increments of one third to obtain the appropriate consistency. As in the slump tests, the mixture was placed in one-third volume increments into a cylindrical plastic mold (D × H: 5 × 10 cm) and compacted as indicated above. To denote underground mining conditions, a curing cabinet was maintained at a temperature of 20 °C and 85% humidity. The samples were placed in a cabinet and kept there until the pre-determined curing times. Figure 2 shows the sample preparation process.

2.3. Methods

2.3.1. Miniature Slump Cone Tests

The slump of backfill samples with or without sand was measured by a miniature slump cone (15 cm height; Figure 2) according to the ASTM C143 code. Instead of a standard slump cone (30 cm height) which was typically employed as a measure of concrete flowability, tests using a miniature slump cone required small volumes of backfill materials [51,52]. Experience displays that standard and miniature slump cones represent a strong relationship. Overall, the miniature slump cone provided half of the slump measured by a standard slump cone. The slump determined by a miniature slump cone was measured as 50 mm, while the slump value determined by a standard slump cone was measured as 100 mm. The target slump values of the paste backfill mixtures were determined as 250 mm and 210 mm for a given solid content of 72 wt.% and 76 wt.%, respectively.

2.3.2. Mechanical Strength Tests

For UCS tests, an auto-controlled UTEST Multiplex Universal device (capacity: 50 kN; displacement: 1 mm/min) was employed on cylinder-shaped specimens (D × H: 5 × 10 cm). Before starting the test, the upper and lower surfaces of CPB specimens to be positioned between low and top metal circles were leveled. The strength value of backfilling was acquired by averaging three UCS test results.

2.3.3. SEM Observations

After UCS testing, the effect of inert sand on microstructural changes in CPB was explored by JEOL JSM-6510 type scanning electron microscopy. The microscope’s key parameters were 10–30 kV acceleration voltage, 2000 times magnification, and 3 nm resolution. Before the SEM analyses, CPB pieces were put in alcohol first and were then furnace dehydrated at 50 °C for 5 days to wholly stop the backfill’s cement hydration process. Note that SEM analyses were conducted at an acceleration voltage of 25 keV with 0.9 nA current emission.

2.3.4. MIP Measurements

After the UCS test, the effect of sand on the fill’s microstructure was explored by a Quantachrome PoreMaster PM60-type mercury intrusion porosimetry. The porosimeter’s key parameters were 3–210 kPa low pressure, 0.21–410 MPa high pressure, and 0.003 µm pore diameter. Before MIP tests, 2–5 g cylindrical samples were oven-dried first and then subjected to low/high pressures sequentially. Note that MIP tests were conducted at a Hg body volume of 70%, a 130° contact angle, and 0.485 N/m surface tension. CPB’s porosities were acquired by averaging three MIP test results.

3. Results and Discussion

3.1. Sand Effect on CPB’s Strength Property

Figure 3 demonstrates the strength evolution of CPB samples when prepared with diverse tailings/sand ratios. The average strengths of the backfill samples generally increased depending on the sand replacement rates.
The average strengths of the reference samples (CT100-72 and CT100-76) for different curing times were found to be 0.35, 0.58, 0.78, and 0.88 MPa, as well as 0.43, 0.80, 1.00, and 1.15 MPa, respectively. The mean strengths of the CT90-S10-72 (25 cm slump) and CT90-S10-76 (21 cm slump) samples varied in the range of 0.50–1.07 MPa and 0.64–1.28 MPa, respectively. In cases of CT50-S50-72 and CT50-S50-76, where the amount of sand used instead of tailings was the highest, the strength ranges reached 0.65–1.17 MPa, and 0.83–1.42 MPa, respectively. When CPB mixtures prepared with different tailings/sand ratios at a 72 wt.% solid content were considered, backfill strengths increased in the ranges of 42.5%–89.0%, 38.9%–60.9%, 20.6%–38.5%, and 21.9%–40.4% for 3, 14, 28, and 56 days, respectively. For the 76 wt.% solid content, backfill strengths at these curing times increased in the range of 47.7%–99.2%, 21.4%–54.1%, 11.4%–32.8%, and 11.6%–33.4%, respectively.
The main reason behind these increases in strengths is that sand improved the particle size distribution of tailings [53]. In addition, sand samples containing high amounts of CaO can interact with cement and contribute to the creation of a suitable pH environment for hydration, increasing the pH to ideal levels [54,55]. Considering both the increase in strength and the rheological properties, the ideal tailings/sand ratio was determined as 70/30. It has been observed that if the amount of sand used was more than this ratio, it caused segregation, which reduced CPB’s workability. The grain structure, shape, and size of the sand to be selected for CPB manufacturing should be well explored, as this may cause extra friction losses during the delivery of CPB via a pipeline, including the wear on the elbows and the slowing down or even stopping of operations.

3.2. Influence of Tailings-To-Sand Rate on Backfill Failure

The stress–strain curves of 56-day cured filling specimens with different tailings/sand ratios are given in Figure 4. Stress–strain curves can be evaluated in four steps: (i) pore solidity step, (ii) elastic distortion step, (iii) plastic yield step, and (iv) rupture-breakage step [56,57].
Cementitious filling specimens that were tested at the first stage demonstrated many voids due to grains of sand. Therefore, from the first stress implemented, the micro-voids of cementitious paste backfill began to close, and a concave stress–strain curve was shaped. In the second step, cementitious paste backfill specimens entered the elastic deformation stage, and the strain was augmented with increasing stress. Therefore, the curve developed a traditional line, and micro-cracks began to form in the backfilling. The modulus of elasticity of backfill with diverse sand replacement ranks was acquired. As can be seen from Figure 4, in 76 wt.%, solid content as the sand substitution rank was augmented from 0% to 50%, the rupture-breakage values for the filling specimens were higher than the 72 wt.% solid content. This meant that the addition of sand improved the confrontation of backfilling to distortion.
In the third step, elastic distortion rotated into plastic distortion. The inner pores/cracks of the filling samples progressively extended, stress–strain curves became convex, and gradually reached their highest mechanical strength values. Significant differences occurred in the peak stresses, with reductions in the strains corresponding to the maximum stresses that occurred as the sand substitution increased. It was determined that the unit deformation values corresponding to the peak stress at 72 wt.% and 76 wt.% solid contents were between 0.78% and 1.11% and between 0.77% and 1.08%.
In the last step, after the specimens extended the peak, as the stress amplified, the micro-cracks of the samples merged, and fracture planes were formed. As the loading continued, the pressure progressively reduced, and all specimens had a residual strength once breaking. The residual strength of cementitious paste backfills with sand appeared to be slightly higher than that of CPB without sand. Almost all the samples tested showed strong brittleness after reaching the peak stress. Since filling specimens reinforced with sand still had a high bearing capacity even after collapse compared to filling specimens reinforced with no sand, this demonstrates that sand can be used as an additive material to increase the safety of underground operations.

3.3. MIP Analysis of Filling Specimens

Figure 5 and Figure 6 indicate the cumulative MIP results of filling specimens on different curing days. It is quite apparent that for a certain mix recipe, CPB’s total porosity decreased with an increased curing time. For all curing times at 72–76 wt.% solid contents, the total porosity values of the backfill control samples were found to be in the ranges of 50.4%–52.2% and 47.2%–49.2%, respectively. Similarly, for different tailings/sand ratios, these values were found to be in the ranges of 49.0%–51.9% and 44.0%–48.3%, respectively. The well-graded sand used in filling specimen mixtures provided lower porosity compared to the reference samples.
In addition to the particle size distribution, CaO (55.6%) within sand encourages the hydration products (C-S-H) to appear, contributing to the filling of pores. The hydration products resulted in a significant reduction in pore size and porosity [58,59,60]. Accordingly, the strength of CPB improved significantly. For example, CT70-S30-72 and CT70-S30-76 samples had lower porosity values (2.84% and 6.72%, respectively) when compared to the control samples. However, one could interpret that CPB’s pore size augmented at a 50% sand addition. Note that sand exceeding the threshold limit (30%) caused segregation in CPB. Segregation disrupts the uniformity of backfill mixtures by causing friction and breaking of bonds between the particles [61,62,63]. This results in an increase in the voids of CPB and the formation of different strength values in different parts of CPB samples.

3.4. SEM Observations of CPB Samples

Figure 7 and Figure 8 indicate the SEM-EDS results of 56-day cured filling specimens (C70-S30-72 and C70-S30-76) at different solid contents. The circulation of sand, pores, bonds, and cracks on the outside of the filling specimens studied could be observed easily. In addition, the compact structure that was formed due to the fill’s high solid content made CPBs denser. It has been observed that different hydration products are formed as a result of the interaction of sand with tailings. In addition, it has been found that the grains in tailings are glued with hydration materials. However, there are few voids between the grains. It can be interpreted that these gaps are eliminated by well-graded sand.
In addition, different quantities of CSH gels and ettringite bonds were observed in both solid contents. This could be clarified by the amount of Ca contained in the sand [64,65,66]. According to EDS results, the key features in hydration products of CT70-S30-72 are O, Fe, C, Ca, S, Si, Mo, Al, and Mg with a mass fraction of 41.1%, 16.1%, 14.9%, 12.4%, 9.3%, 6.2%, 2.2%, 1.0%, and 2.3%, respectively. Similarly, the same main elements of CT70-S30-76 are 36.1%, 15.9%, 11.8%, 14.2%, 8.7%, 5.5%, 1.3%, 3.7%, and 1.3%, respectively. The circulation of O, Fe, C, Ca, S, Si, and Al elements is strictly linked to the fill’s mineral composition, and it appears to have clear limits in the delivery area. Between these elements, Ca is dispersed in cement and sand hydration products. Si and Al elements occupy a large place on the surface of cement and are usually found in small amounts in CPB [67,68,69]. The excess content of Ca, Si, O, and Al elements in the hydration materials supports the formation of SiO2 and Al2O3 in the content of sand and cement and makes a positive contribution to the strengths.

4. Conclusions

The usability of sand in backfill manufacturing was explored experimentally. The mini-slump, UCS, and microstructural (SEM-EDX and MIP) properties of CPB, when produced with different solid contents and tailings/sand ratios, were investigated experimentally. As a result of this lab-scale study, the optimum sand replacement ratio for backfilling was determined in terms of rheology and strength, considering the operational conditions. The key consequences of this research are below:
  • Since the totaling of sand to the backfill increased the mixture gradation, the compressive strengths were found to be greater at up to 89.0% and 99.2% of the solid contents of 72% and 76%, respectively, compared to samples without sand.
  • Increasing the replacement ratio of the sand used within CPB increases the corresponding strength but reduces strength after a threshold limit of 30%, causing segregation.
  • Inert sand with a high CaO ratio can be used as a cement material as well as being used as an aggregate in CPB samples, providing high strengths even at low cement amounts. This shows the importance of using sand to reduce cement costs.
The results of the research show that the use of sand in mixtures improves the mechanical properties of CPB and can reduce cement-related costs depending on the distance of the quarry to the mine. However, using a high amount of sand adversely affects CPB’s rheological properties. In addition to the backfill strengths, rheological properties should be also taken into consideration. The gradation of sand should be determined accurately, together with the suitable replacement ratio. In upcoming studies, the writers will ruminate further on the optimization of sand when used as aggregate in CPB with different mineral/chemical additives, as well as some other reinforcement agents. All these works are currently underway.

Author Contributions

Conceptualization, N.U.G. and E.Y.; methodology, M.S. and T.K.; writing—original draft preparation, N.U.G.; writing—review and editing, N.U.G., E.Y., M.S. and T.K.; and supervision, E.Y. All authors have read and agreed to the published version of the manuscript.

Funding

This research received no external funding.

Data Availability Statement

No new data were created or analyzed in this study. Data sharing is not applicable to this article.

Conflicts of Interest

The authors declare no conflict of interest.

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Figure 1. Cumulative PSD curves of Cu-rich tailings and sand.
Figure 1. Cumulative PSD curves of Cu-rich tailings and sand.
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Figure 2. Specimen preparation steps.
Figure 2. Specimen preparation steps.
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Figure 3. The compressive strengths of CPB with different sand ratios: (a) 72 wt.% and (b) 76 wt.%.
Figure 3. The compressive strengths of CPB with different sand ratios: (a) 72 wt.% and (b) 76 wt.%.
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Figure 4. Stress–strain curves of 56-day cured fills with (a) 72 wt.% and (b) 76 wt.% solids.
Figure 4. Stress–strain curves of 56-day cured fills with (a) 72 wt.% and (b) 76 wt.% solids.
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Figure 5. MIP results of 72 wt.% solid fill specimens: (a) cumulative; (b) incremental curves.
Figure 5. MIP results of 72 wt.% solid fill specimens: (a) cumulative; (b) incremental curves.
Minerals 13 00437 g005aMinerals 13 00437 g005b
Figure 6. MIP results of 76 wt.% solid fill specimens: (a) cumulative; (b) incremental curves.
Figure 6. MIP results of 76 wt.% solid fill specimens: (a) cumulative; (b) incremental curves.
Minerals 13 00437 g006aMinerals 13 00437 g006b
Figure 7. SEM (a) and EDS (b) results of 56-day cured CPB samples with 72 wt.% solid contents.
Figure 7. SEM (a) and EDS (b) results of 56-day cured CPB samples with 72 wt.% solid contents.
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Figure 8. SEM (a) and EDS (b) results of 56-day cured CPB samples with 76 wt.% solid contents.
Figure 8. SEM (a) and EDS (b) results of 56-day cured CPB samples with 76 wt.% solid contents.
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Table 1. A summary of basic physical features of tailings, sand, and cement.
Table 1. A summary of basic physical features of tailings, sand, and cement.
Physical ParametersTailingsSandCement
Specific gravity, GS3.552.633.12
Specific surface area, SS, m2/g2.890.710.43
D10, μm5.961134.62
D30, μm24.147612.8
D50, μm43.6112223.1
D60, μm60148332.3
D90, μm132254169
Cu, Coefficient of uniformity (D60/D10)10.113.16.99
Cc, Coefficient of curvature (D302)/(D60 × D10)1.621.351.10
Table 2. Oxide analyses of tailings/sand/cement materials.
Table 2. Oxide analyses of tailings/sand/cement materials.
Oxide AnalysisTailings (%)Sand (%)Cement (%)
Fe2O341.80.443.13
Mn3O40.930.020.03
BaO0.020.010.09
TiO20.340.030.20
CaO4.2555.664.5
K2O0.290.090.79
SO30.390.753.53
P2O50.050.010.03
SrO0.010.010.08
SiO226.51.8516.9
Al2O37.111.515.81
MgO1.650.591.22
Na2O0.040.020.39
LOI20.141.283.90
Table 3. CPB recipe design (CT: copper tailings).
Table 3. CPB recipe design (CT: copper tailings).
NotationCuring Time (Days)Solid
Content
(wt.%)
Slump
(cm)
OPC
(wt.%)
Tailings
(wt.%)
Sand
(wt.%)
CT100-723, 14, 28, 5672257100-
CT100-763, 14, 28, 5676217100-
CT90-S10-723, 14, 28, 56722579010
CT90-S10-763, 14, 28, 56762179010
CT80-S20-723, 14, 28, 56722578020
CT80-S20-763, 14, 28, 56762178020
CT70-S30-763, 14, 28, 56722577030
CT70-S30-763, 14, 28, 56762177030
CT50-S50-A3, 14, 28, 56722575050
CT50-S50-B3, 14, 28, 56762175050
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Guner, N.U.; Yilmaz, E.; Sari, M.; Kasap, T. Cementitious Backfill with Partial Replacement of Cu-Rich Mine Tailings by Sand: Rheological, Mechanical and Microstructural Properties. Minerals 2023, 13, 437. https://doi.org/10.3390/min13030437

AMA Style

Guner NU, Yilmaz E, Sari M, Kasap T. Cementitious Backfill with Partial Replacement of Cu-Rich Mine Tailings by Sand: Rheological, Mechanical and Microstructural Properties. Minerals. 2023; 13(3):437. https://doi.org/10.3390/min13030437

Chicago/Turabian Style

Guner, Nihat Utku, Erol Yilmaz, Muhammet Sari, and Tugrul Kasap. 2023. "Cementitious Backfill with Partial Replacement of Cu-Rich Mine Tailings by Sand: Rheological, Mechanical and Microstructural Properties" Minerals 13, no. 3: 437. https://doi.org/10.3390/min13030437

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