Stratigraphic Section and Geochronological Studies of the Shoushan Basin, Fujian Province, South China, and Its Implications for the Mineralization of Shoushan Stone
Abstract
:1. Introduction
2. Geologic Setting
3. Sample Description
4. Analytical Methods
5. Results and Discussion
5.1. Stratigraphic Section Study of the Qishan Caldera and Its Significance for the Forming of Shoushan Stone
5.2. Zircon U-Pb Geochronology of Rhyolitic Tuff in the Qishan Caldera and Its Limitation for the Forming of Shoushan Stone
5.3. Stratigraphic Correlation of Xiaoxi Formation and Indication for Pyrophyllite Deposit Exploration
6. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Unit | Layer | Thickness (m) | Lithology Interpretation | Petrogenesis | Alteration |
---|---|---|---|---|---|
K1x3 | 28 | 6.7 | Rhyolitic ignimbrite with conglomerated breccia and crystal debris | Volcanic channel | - |
27 | 42.6 | Rhyolitic ignimbrite with breccia and crystal debris | Eruption | - | |
26 | 77.9 | Rhyolitic ignimbrite with crystal debris | Eruption | - | |
25 | 40.8 | Lithophysa rhyolite | Flood lava | - | |
24 | 20.1 | Rhyolitic ignimbrite with breccia and crystal debris | Eruption | - | |
23 | 66.3 | Rhyolitic ignimbrite with crystal debris | Eruption | - | |
K1x2 | 22 | 153.3 | Alterated rhyolitic tuff with crystal debris | Eruption | Diaspore and pyrophyllite alteration |
21 | 24.1 | The ore body of pyrophyllite (protolith: rhyolitic tuff with crystal debris) | Eruption | Silicification, diaspore, and pyrophyllite alteration | |
20 | 92.2 | Alterated rhyolitic tuff with crystal-rock-vitric debris | Eruption | Pyrophyllite alteration | |
19 | 107.3 | Alterated rhyolitic tuff with rock-crystal debris | Eruption | Pyrophyllite alteration | |
18 | 21.1 | Alterated rhyolitic tuff with vitric debris | Eruption | Pyrophyllite alteration | |
17 | 35.8 | Rhyolitic tuff with crystal debris | Eruption | - | |
16 | 37.7 | Tuffaceous sandstone | Sedimentary | - | |
15 | 309.7 | Rhyolitic ignimbrite with crystal debris | Eruption | - | |
14 | 53.2 | Tuffaceous mudstone | Sedimentary | - | |
13 | 84.9 | Rhyolitic tuff with crystal debris | Eruption | - | |
12 | 30.2 | Tuffaceous mudstone | Sedimentary | - | |
11 | 103.3 | Rhyolitic tuff with rock debris | Eruption | - | |
10 | 31.5 | Tuffaceous mudstone | Sedimentary | - | |
9 | 20.9 | Rhyolitic tuff with breccia and crystal debris | Eruption | - | |
8 | 5.6 | Rhyolitic tuff with vitric debris | Eruption | Silicification and pyritization | |
7 | 70.3 | Rhyolitic tuff with crystal debris | Eruption | - | |
6 | 62.4 | Rhyolitic ignimbrite with crystal debris | Eruption | - | |
5 | 18.1 | Lithophysa rhyolite | Flood lava | - | |
4 | 81 | Silicified rhyolitic tuff with crystal debris | Eruption | Silicification | |
K1x1 | 3 | 44 | Tuffaceous mudstone with banded silicalite | Sedimentary | Silicification |
J3n3 | 2 | 55.5 | Dacite | Flood lava | - |
1 | 279 | Dacitic ignimbrite with crystal debris | Eruption | - |
PM301-14 | Concordance | |||||||||||
Analysis | ppm | Ratios | Corrected Ratios | Corrected Ages/Ma | ||||||||
No. | Th | U | Th/U | 207Pb/235U | ±1σ | 206Pb/238U | ±1σ | 207Pb/235U | ±1σ | 206Pb/238U | ±1σ | |
1 | 11.33 | 181.51 | 0.06 | 0.14511 | 0.00495 | 0.02092 | 0.00026 | 137.6 | 4.39 | 133.5 | 1.63 | 0.97 |
2 | 410.9 | 609.31 | 0.67 | 0.14454 | 0.00978 | 0.02138 | 0.00038 | 137.1 | 8.67 | 136.4 | 2.37 | 0.99 |
3 | 93.33 | 77.58 | 1.2 | 0.14478 | 0.00882 | 0.02141 | 0.00034 | 137.3 | 7.83 | 136.5 | 2.13 | 0.99 |
4 | 73.19 | 89.23 | 0.82 | 0.14363 | 0.01465 | 0.02111 | 0.00046 | 136.3 | 13.01 | 134.6 | 2.89 | 0.99 |
5 | 127.91 | 110.98 | 1.15 | 0.14529 | 0.00788 | 0.02102 | 0.00031 | 137.7 | 6.98 | 134.1 | 1.98 | 0.97 |
6 | 24.47 | 68.83 | 0.36 | 0.14465 | 0.01709 | 0.02175 | 0.00058 | 137.2 | 15.16 | 138.7 | 3.68 | 1.01 |
7 | 214.95 | 180.46 | 1.19 | 0.14545 | 0.01083 | 0.02127 | 0.0004 | 137.9 | 9.6 | 135.7 | 2.51 | 0.98 |
8 | 153.84 | 177.83 | 0.87 | 0.14411 | 0.00968 | 0.02087 | 0.00036 | 136.7 | 8.59 | 133.1 | 2.3 | 0.97 |
9 | 452.5 | 458.37 | 0.99 | 0.14466 | 0.01827 | 0.02161 | 0.00053 | 137.2 | 16.2 | 137.9 | 3.33 | 1.01 |
10 | 24.93 | 71.07 | 0.35 | 0.14567 | 0.00895 | 0.02153 | 0.00035 | 138.1 | 7.93 | 137.3 | 2.2 | 0.99 |
11 | 11.76 | 186.93 | 0.06 | 0.14289 | 0.00708 | 0.02134 | 0.0003 | 135.6 | 6.29 | 136.1 | 1.88 | 1 |
12 | 196.89 | 197.47 | 1.00 | 0.14483 | 0.01081 | 0.02091 | 0.00039 | 137.3 | 9.59 | 133.4 | 2.46 | 0.97 |
13 | 127.74 | 128.38 | 1.00 | 0.1415 | 0.01777 | 0.02137 | 0.0006 | 134.4 | 15.81 | 136.3 | 3.78 | 1.01 |
14 | 23.98 | 69.14 | 0.35 | 0.14717 | 0.01517 | 0.02117 | 0.00049 | 139.4 | 13.43 | 135 | 3.09 | 0.97 |
15 | 59.94 | 73.84 | 0.81 | 0.14882 | 0.0134 | 0.02165 | 0.00046 | 140.9 | 11.85 | 138.1 | 2.92 | 0.98 |
16 | 94.21 | 110.4 | 0.85 | 0.15408 | 0.01836 | 0.02158 | 0.00058 | 145.5 | 16.15 | 137.6 | 3.65 | 0.95 |
17 | 99.64 | 110.65 | 0.9 | 0.14678 | 0.01342 | 0.02127 | 0.00046 | 139.1 | 11.88 | 135.7 | 2.89 | 0.98 |
18 | 27.28 | 77.71 | 0.35 | 0.14385 | 0.01178 | 0.02166 | 0.0004 | 136.5 | 10.46 | 138.1 | 2.51 | 1.01 |
19 | 12.17 | 191.66 | 0.06 | 0.14604 | 0.01065 | 0.02111 | 0.00038 | 138.4 | 9.43 | 134.6 | 2.43 | 0.97 |
20 | 218.96 | 185.35 | 1.18 | 0.14642 | 0.01103 | 0.02121 | 0.00041 | 138.7 | 9.77 | 135.3 | 2.6 | 0.98 |
21 | 173.75 | 184.65 | 0.94 | 0.14682 | 0.01087 | 0.02099 | 0.0004 | 139.1 | 9.63 | 133.9 | 2.51 | 0.96 |
22 | 134.27 | 128.24 | 1.05 | 0.14445 | 0.00691 | 0.02154 | 0.0003 | 137 | 6.13 | 137.4 | 1.91 | 1 |
23 | 153.34 | 223.17 | 0.69 | 0.14245 | 0.01605 | 0.02142 | 0.0005 | 135.2 | 14.27 | 136.6 | 3.14 | 1.01 |
PM301-32 | Concordance | |||||||||||
Analysis | ppm | Ratios | Corrected Ratios | Corrected Ages/Ma | ||||||||
No. | Th | U | Th/U | 207Pb/235U | ±1σ | 206Pb/238U | ±1σ | 207Pb/235U | ±1σ | 206Pb/238U | ±1σ | |
1 | 208.78 | 231.94 | 0.9 | 0.14509 | 0.00864 | 0.02041 | 0.00032 | 137.6 | 7.66 | 130.2 | 2.01 | 0.95 |
2 | 196.59 | 261.67 | 0.75 | 0.14997 | 0.01115 | 0.02064 | 0.0004 | 141.9 | 9.84 | 131.7 | 2.53 | 0.93 |
3 | 249.66 | 219.96 | 1.14 | 0.13626 | 0.00591 | 0.02063 | 0.00027 | 129.7 | 5.29 | 131.6 | 1.72 | 1.01 |
4 | 26.7 | 75.67 | 0.35 | 0.14096 | 0.00527 | 0.02066 | 0.00026 | 133.9 | 4.69 | 131.8 | 1.64 | 0.98 |
5 | 327.34 | 308.56 | 1.06 | 0.13703 | 0.00684 | 0.02062 | 0.0003 | 130.4 | 6.11 | 131.6 | 1.87 | 1.01 |
6 | 309.17 | 282.8 | 1.09 | 0.13576 | 0.01035 | 0.02082 | 0.00036 | 129.3 | 9.25 | 132.9 | 2.3 | 1.03 |
7 | 169.76 | 139.39 | 1.22 | 0.13809 | 0.00807 | 0.0208 | 0.00031 | 131.3 | 7.2 | 132.7 | 1.95 | 1.01 |
8 | 11.67 | 183.93 | 0.06 | 0.13746 | 0.01455 | 0.02059 | 0.00044 | 130.8 | 12.99 | 131.4 | 2.81 | 1 |
9 | 109.8 | 86.66 | 1.27 | 0.14167 | 0.00939 | 0.0206 | 0.00035 | 134.5 | 8.35 | 131.4 | 2.19 | 0.98 |
10 | 138.72 | 131.56 | 1.05 | 0.13459 | 0.00621 | 0.02034 | 0.00028 | 128.2 | 5.55 | 129.8 | 1.8 | 1.01 |
11 | 230.15 | 241.93 | 0.95 | 0.13602 | 0.01214 | 0.02059 | 0.0004 | 129.5 | 10.85 | 131.4 | 2.54 | 1.01 |
12 | 25.57 | 74.28 | 0.34 | 0.14469 | 0.00697 | 0.02038 | 0.0003 | 137.2 | 6.18 | 130.1 | 1.87 | 0.95 |
13 | 267.9 | 304.5 | 0.88 | 0.14137 | 0.00681 | 0.0206 | 0.0003 | 134.3 | 6.06 | 131.4 | 1.88 | 0.98 |
14 | 219.4 | 194.08 | 1.13 | 0.13885 | 0.00708 | 0.02064 | 0.0003 | 132 | 6.31 | 131.7 | 1.87 | 1 |
15 | 222.5 | 228.07 | 0.98 | 0.14301 | 0.00652 | 0.0207 | 0.00029 | 135.7 | 5.8 | 132.1 | 1.81 | 0.97 |
16 | 81.98 | 70.12 | 1.17 | 0.13888 | 0.00822 | 0.02096 | 0.00032 | 132 | 7.33 | 133.7 | 1.99 | 1.01 |
17 | 192.43 | 188.87 | 1.02 | 0.14215 | 0.00665 | 0.02077 | 0.00028 | 135 | 5.91 | 132.5 | 1.8 | 0.98 |
18 | 201.46 | 237.43 | 0.85 | 0.14487 | 0.0082 | 0.02068 | 0.00033 | 137.4 | 7.27 | 131.9 | 2.06 | 0.96 |
19 | 200.06 | 244.06 | 0.82 | 0.13548 | 0.00531 | 0.02071 | 0.00026 | 129 | 4.75 | 132.2 | 1.66 | 1.02 |
20 | 428.36 | 342.9 | 1.25 | 0.14865 | 0.00871 | 0.02073 | 0.00034 | 140.7 | 7.7 | 132.3 | 2.17 | 0.94 |
Sample | Shoushan Basin | Zhouling Basin | |||||||
---|---|---|---|---|---|---|---|---|---|
PM301-14 | PM301-32 | D3185 | D3683-2 | D3691 | D3713-2 | D3713-4 | D3714 | D3712 | |
SiO2 | 73.73 | 76.54 | 78.37 | 75.38 | 70.73 | 75.24 | 75.27 | 77.09 | 74.2 |
Al2O3 | 14 | 12.56 | 11.98 | 12.88 | 14.43 | 13.79 | 12.62 | 12.76 | 13.45 |
Ti2O | 0.31 | 0.13 | 0.16 | 0.18 | 0.26 | 0.12 | 0.23 | 0.11 | 0.19 |
Fe2O3 | 1.71 | 0.46 | 1.06 | 1.24 | 1.36 | 1.38 | 1.36 | 1.27 | 2.2 |
FeO | 0.27 | 0.58 | 0.3 | 0.33 | 0.74 | 0.28 | 0.24 | 0.2 | 0.56 |
CaO | 0.09 | 0.28 | 0.08 | 0.24 | 1.62 | 0.07 | 0.65 | 0.05 | 0.11 |
MgO | 0.37 | 0.16 | 0.14 | 0.26 | 0.4 | 0.07 | 0.24 | 0.06 | 0.1 |
K2O | 5.37 | 5.07 | 4.69 | 5.26 | 5.01 | 5.36 | 4.85 | 5.44 | 6.25 |
Na2O | 1.37 | 2.54 | 1.4 | 2.29 | 2.49 | 1.63 | 2.87 | 0.21 | 0.57 |
MnO | 0.02 | 0.08 | 0.03 | 0.07 | 0.05 | 0.03 | 0.08 | 0.03 | 0.06 |
P2O5 | 0.04 | 0.02 | 0.02 | 0.03 | 0.07 | 0.02 | 0.04 | 0.01 | 0.03 |
LOI | 2.29 | 1.12 | 1.39 | 1.35 | 2.42 | 1.65 | 1.22 | 2.39 | 1.89 |
Total | 99.6 | 99.6 | 99.7 | 99.5 | 99.6 | 99.7 | 99.7 | 99.6 | 99.7 |
Cr | 3.6 | 4.5 | 4.7 | 8.5 | 6.15 | 4 | 3.7 | 2.3 | 4.9 |
Co | 1.56 | 1.79 | 1.29 | 1.2 | 2.91 | 1.17 | 1.94 | 1.08 | 1.36 |
Ni | 1.18 | 1.51 | 1.82 | 0.54 | 2.09 | 1.86 | 2.31 | 2.91 | 2.53 |
V | 17.5 | 9.1 | 2.5 | 7.2 | 17.3 | 3.3 | 10.9 | 3.45 | 6.7 |
Cu | 2.72 | 1.72 | 8.12 | 3.63 | 5.57 | 5.85 | 6.63 | 5.4 | 6.35 |
Pb | 27.8 | 32.7 | 21.9 | 35.4 | 49.1 | 40.7 | 49.53 | 57.91 | 24.26 |
Zn | 55.3 | 50.5 | 161.1 | 40.1 | 82.6 | 151.2 | 78.1 | 115 | 124 |
Sn | 1.82 | 2.72 | 1.6 | 2.7 | 1.76 | 2.88 | 1.35 | 3.55 | 2.8 |
Mo | 1.48 | 1.37 | 0.83 | 0.6 | 0.69 | 1.39 | 1.23 | 1 | 0.7 |
Bi | 0.08 | 0.32 | 0.23 | 0.12 | 0.19 | 0.24 | 0.14 | 0.3 | 0.19 |
W | 2.75 | 1.61 | 2.75 | 1.21 | 2.22 | 2.71 | 2.43 | 2.17 | 2.79 |
Ag | 0.1 | 0.08 | 0.1 | 0.04 | 0.06 | 0.07 | 0.05 | 0.03 | 0.07 |
Au | 1.28 | 0.72 | 0.54 | 1.94 | 0.52 | 0.54 | 0.52 | 0.53 | 0.52 |
Li | 7.91 | 31.74 | 12.7 | 7.42 | 11.66 | 8.83 | 12.06 | 9.87 | 13.12 |
Hf | 8.06 | 3.61 | 9.2 | 5.37 | 6.33 | 8.84 | 6.01 | 8.58 | 9.2 |
Nb | 18.46 | 17.8 | 25.98 | 14.93 | 14.51 | 41.73 | 15.07 | 36.53 | 28.91 |
Rb | 236 | 189 | 202 | 185 | 209 | 254 | 195 | 252 | 313 |
Zr | 238 | 93.5 | 248 | 142 | 165 | 225 | 175 | 228 | 282 |
Ti | 1858 | 779 | 926 | 1042 | 1505 | 694 | 1331 | 636 | 1100 |
Ba | 1509 | 688 | 148 | 618 | 1018 | 257 | 972 | 248 | 300 |
U | 4.08 | 4.61 | 2.02 | 2.31 | 2.16 | 4.32 | 3.34 | 4.1 | 3.42 |
Th | 21.7 | 19.1 | 16.6 | 19.2 | 15.7 | 21.6 | 21.1 | 18.7 | 20.3 |
Sr | 70.2 | 57.69 | 19.14 | 101.3 | 193.7 | 57.7 | 146.9 | 26.5 | 39.9 |
La | 77.9 | 31.2 | 72.3 | 56.3 | 44.9 | 116 | 73.3 | 68.9 | 35.5 |
Ce | 131 | 57.8 | 138 | 93.4 | 76.8 | 191 | 133 | 133 | 82.1 |
Pr | 14.8 | 6.88 | 17.2 | 12.4 | 9.06 | 23.9 | 17.8 | 13.7 | 8.99 |
Nd | 50.9 | 23.4 | 55.3 | 39.3 | 27.86 | 75.3 | 58.6 | 42.1 | 30.8 |
Sm | 8.56 | 4.78 | 10.54 | 6.53 | 4.84 | 12.67 | 12.53 | 7.04 | 6.47 |
Eu | 2.42 | 0.96 | 0.53 | 1.09 | 1.14 | 0.62 | 0.51 | 1.23 | 0.23 |
Gd | 7.84 | 4.68 | 7.69 | 5.76 | 3.44 | 8.33 | 9.37 | 4.47 | 5 |
Tb | 0.91 | 0.7 | 1.3 | 0.86 | 0.57 | 1.31 | 1.63 | 0.79 | 1.1 |
Dy | 4.76 | 4.05 | 6.68 | 4.25 | 3.01 | 6.28 | 8.54 | 3.92 | 6.01 |
Ho | 0.89 | 0.85 | 1.34 | 0.78 | 0.62 | 1.25 | 1.72 | 0.78 | 1.32 |
Er | 2.64 | 2.65 | 4.36 | 2.35 | 2.1 | 4.16 | 5.62 | 2.6 | 4.1 |
Tm | 0.38 | 0.41 | 0.51 | 0.3 | 0.27 | 0.51 | 0.67 | 0.3 | 0.5 |
Yb | 2.61 | 2.91 | 4.04 | 2.28 | 2.05 | 3.96 | 5.36 | 2.46 | 3.97 |
Lu | 0.39 | 0.43 | 0.53 | 0.33 | 0.3 | 0.56 | 0.7 | 0.33 | 0.53 |
Y | 24.1 | 27.6 | 47.3 | 24.9 | 20.95 | 45.8 | 59.2 | 23.8 | 49.45 |
Eu*/Eu | 0.9 | 0.62 | 0.18 | 0.54 | 0.85 | 0.18 | 0.14 | 0.67 | 0.12 |
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Li, Y.-J.; Zhu, L.-Y.; Xu, W.; Meng, W.; Lin, M.; Yang, Z.; Chen, R.-S. Stratigraphic Section and Geochronological Studies of the Shoushan Basin, Fujian Province, South China, and Its Implications for the Mineralization of Shoushan Stone. Minerals 2022, 12, 1542. https://doi.org/10.3390/min12121542
Li Y-J, Zhu L-Y, Xu W, Meng W, Lin M, Yang Z, Chen R-S. Stratigraphic Section and Geochronological Studies of the Shoushan Basin, Fujian Province, South China, and Its Implications for the Mineralization of Shoushan Stone. Minerals. 2022; 12(12):1542. https://doi.org/10.3390/min12121542
Chicago/Turabian StyleLi, Yu-Juan, Lü-Yun Zhu, Wen Xu, Wei Meng, Min Lin, Zhong Yang, and Run-Sheng Chen. 2022. "Stratigraphic Section and Geochronological Studies of the Shoushan Basin, Fujian Province, South China, and Its Implications for the Mineralization of Shoushan Stone" Minerals 12, no. 12: 1542. https://doi.org/10.3390/min12121542