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Molecules, Volume 5, Issue 9 (September 2000) – 3 articles , Pages 1055-1079

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Review
Recent Advances in the Substitution Reactions of Triorganylstannyl Ions with Aromatic Compounds by the SRN1 Mechanism. Synthetic Applications
by Eduardo F. Córsico, Al Postigo and Roberto A. Rossi
Molecules 2000, 5(9), 1068-1079; https://doi.org/10.3390/50901068 - 11 Sep 2000
Cited by 3 | Viewed by 10032
Abstract
A review on the reactions of triorganyl stannyl ions with haloarenes is presented. Emphasis on the synthetic applications of the resulting triorganyl stannyl aryl compounds is made, with their inherent potential to build large molecules through the SRN1 sequence, i.e. ArX→ArSnR [...] Read more.
A review on the reactions of triorganyl stannyl ions with haloarenes is presented. Emphasis on the synthetic applications of the resulting triorganyl stannyl aryl compounds is made, with their inherent potential to build large molecules through the SRN1 sequence, i.e. ArX→ArSnR3→ArAr, which can be iteratively repeated when appropriately substituted substrates are chosen. Full article
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35 KiB  
Article
Swern Oxidation of Bicyclo[2.2.1]hept-5-ene-2,3-diol and Its Pyrazine-fused Derivatives: An Improved Synthesis of Bicyclo[2.2.1]hept-5-ene-2,3-dione and An Unexpected Ring-Opening Reaction
by Tomoshige Kobayashi and Sayuri Kobayashi
Molecules 2000, 5(9), 1062-1067; https://doi.org/10.3390/50901062 - 9 Sep 2000
Cited by 14 | Viewed by 8869
Abstract
An improved synthesis of bicyclo[2.2.1]hept-5-ene-2,3-dione by Swern oxidation of bicyclo[2.2.1]hept-5-ene-2,3-diol, and an unexpected ring-opening reaction by the Swern oxidation of pyrazine-fused congeners are described. Full article
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32 KiB  
Article
Synthesis and Fungicidal Activity of 2-Imino-3-(4-arylthiazol-2-yl)-thiazolidin-4-ones and Their 5-Arylidene Derivatives
by Hui-Ling Liu, Zongcheng Lieberzeit and Thorleif Anthonsen
Molecules 2000, 5(9), 1055-1061; https://doi.org/10.3390/50901055 - 5 Sep 2000
Cited by 145 | Viewed by 12003
Abstract
Five derivatives of 2-imino-3-(4-arylthiazol-2-yl)-thiazolidin-4-ones and a series of their 5-arylidene derivatives have been synthesized and tested for antifungal activity against seven agricultural fungi. 2-Imino-3-(2,4-dichloro-5-fluorophenylthiazol-2-yl)-4-thiazolidi-none and 2-imino-3-(2,4-dichlorophenylthiazol-2-yl)-4-thiazolidione, both of them new compounds, exhibited higher fungicidal effects than the other compounds prepared. Full article
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